| Åkermanite | |
|---|---|
| Åkermanite (yellowish brown), calcite (blue), foshagite (hillebrandite variety, fibrous), tilleyite (creamy) | |
| General | |
| Category | Sorosilicates |
| Formula (repeating unit) | Ca2Mg(Si2O7) |
| IMA symbol | Åk [1] |
| Strunz classification | 9.BB.10 |
| Dana classification | 55.4.1.1 (8 ed) |
| Crystal system | Tetragonal |
| Crystal class | Scalenohedral (42m) H-M symbol: (4 2m) |
| Space group | P421m |
| Unit cell | a = 7.8288(8) c = 5.0052(2) [Å]; Z = 2 |
| Identification | |
| Color | Colorless, yellowish gray, green, brown |
| Cleavage | Distinct on {001}, poor on {110} |
| Fracture | Irregular/ uneven, conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 5–6 |
| Luster | Vitreous, resinous |
| Streak | White |
| Diaphaneity | Transparent, translucent |
| Specific gravity | 2.944 |
| Optical properties | Uniaxial (+) |
| Refractive index | nω = 1.632 nε = 1.640 |
| Birefringence | δ = 0.008 |
| Pleochroism | none |
| References | [2] [3] |
Åkermanite (Ca2Mg[Si2O7]) is a melilite mineral of the sorosilicate group, containing calcium, magnesium, silicon, and oxygen. It is a product of contact metamorphism of siliceous limestones and dolomites, and rocks of sanidinite facies. Sanidinite facies represent the highest conditions of temperature of contact metamorphism and are characterized by the absence of hydrous minerals. It has a density of 2.944 g/cm3. [4] [3] Åkermanite ranks a 5 or 6 on the Mohs scale of mineral hardness, and can be found gray, green, brown, or colorless. It has a white streak and a vitreous or resinous luster. It has a tetragonal crystal system and a good, or distinct, cleavage. It is the end member in a solid solution series beginning with gehlenite (Ca2Al[AlSiO7]). [2]
The mineral is named for Anders Richard Åkerman (Swedish page) (1837–1922), a Swedish metallurgist. It has been found at Monte Somma and Vesuvius, and Monte Cavalluccio near Rome. It was "grandfathered" in as a species of mineral because it was described prior to 1959, before the founding of the International Mineralogical Association. [3]
Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the Earth's crust. Kyanite is also known as disthene or cyanite.
Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than 150 to 200 °C and, often, elevated pressure of 100 megapascals (1,000 bar) or more, causing profound physical or chemical changes. During this process, the rock remains mostly in the solid state, but gradually recrystallizes to a new texture or mineral composition. The protolith may be an igneous, sedimentary, or existing metamorphic rock.
Metamorphism is the transformation of existing rock to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of 150 °C (300 °F), and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface.
Amphibolite is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky) structure. The small flakes of black and white in the rock often give it a salt-and-pepper appearance.
Periclase is a magnesium mineral that occurs naturally in contact metamorphic rocks and is a major component of most basic refractory bricks. It is a cubic form of magnesium oxide (MgO). In nature it usually forms a solid solution with wüstite (FeO) and is then referred to as ferropericlase or magnesiowüstite.
Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and ferro-actinolite. Pure magnesium tremolite is creamy white, but the color grades to dark green with increasing iron content. It has a hardness on Mohs scale of 5 to 6. Nephrite, one of the two minerals known as the gemstone jade, is a green variety of tremolite.
Glaucophane is the name of a mineral and a mineral group belonging to the sodic amphibole supergroup of the double chain inosilicates, with the chemical formula ☐Na2(Mg3Al2)Si8O22(OH)2.
Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are caused by fine grained non-aligned crystals with platy or prismatic habits, characteristic of metamorphism at high temperature but without accompanying deformation. The term is derived from the German word Hornfels, meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern England as whetstones.
The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.
Blueschist, also called glaucophane schist, is a metavolcanic rock that forms by the metamorphism of basalt and rocks with similar composition at high pressures and low temperatures, approximately corresponding to a depth of 15–30 km (9.3–18.6 mi). The blue color of the rock comes from the presence of the predominant minerals glaucophane and lawsonite.
Cummingtonite is a metamorphic amphibole with the chemical composition (Mg,Fe2+
)
2(Mg,Fe2+
)
5Si
8O
22(OH)
2, magnesium iron silicate hydroxide.
Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. It was first discovered within included blocks or adjacent to lavas on Mount Vesuvius, hence its name. Attractive-looking crystals are sometimes cut as gemstones. Localities which have yielded fine crystallized specimens include Mount Vesuvius and the Ala Valley near Turin, Piedmont.
Afwillite is a calcium hydroxide nesosilicate mineral with formula Ca3(SiO3OH)2·2H2O. It occurs as glassy, colorless to white prismatic monoclinic crystals. Its Mohs scale hardness is between 3 and 4. It occurs as an alteration mineral in contact metamorphism of limestone. It occurs in association with apophyllite, natrolite, thaumasite, merwinite, spurrite, gehlenite, ettringite, portlandite, hillebrandite, foshagite, brucite and calcite.
Zussmanite is a hydrated iron-rich silicate mineral with the chemical formula K(Fe2+,Mg,Mn)13[AlSi17O42](OH)14. It occurs as pale green crystals with perfect cleavage.
A metamorphic facies is a set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures. The assemblage is typical of what is formed in conditions corresponding to an area on the two dimensional graph of temperature vs. pressure. Rocks which contain certain minerals can therefore be linked to certain tectonic settings, times and places in the geological history of the area. The boundaries between facies are wide because they are gradational and approximate. The area on the graph corresponding to rock formation at the lowest values of temperature and pressure is the range of formation of sedimentary rocks, as opposed to metamorphic rocks, in a process called diagenesis.
In geology, a metamorphic zone is an area where, as a result of metamorphism, the same combination of minerals occur in the bedrock. These zones occur because most metamorphic minerals are only stable in certain intervals of temperature and pressure.
Manganosite is a rare mineral composed of manganese(II) oxide MnO. It was first described in 1817 for an occurrence in the Harz Mountains, Saxony-Anhalt, Germany. It has also been reported from Langban and Nordmark, Sweden and at Franklin Furnace, New Jersey. It also occurs in Japan, Kyrgyzstan and Burkina Faso.
Kampfite is a rare barium silicate–carbonate–halide mineral with the chemical formula Ba12(Si11Al5)O31(CO3)8Cl5. Discovered in 1964 and described in 2001, it is named after Anthony R. Kampf. The mineral is known only from Fresno County, California.
Gabrielite is an extremely rare thallium sulfosalt mineral with a chemical formula of Tl6Ag3Cu6(As,Sb)9S21 or Tl2AgCu2As3S7.
A petrogenetic grid is a geological phase diagram that connects the stability ranges or metastability ranges of metamorphic minerals or mineral assemblages to the conditions of metamorphism. Experimentally determined mineral or mineral-assemblage stability ranges are plotted as metamorphic reaction boundaries in a pressure–temperature cartesian coordinate system to produce a petrogenetic grid for a particular rock composition. The regions of overlap of the stability fields of minerals form equilibrium mineral assemblages used to determine the pressure–temperature conditions of metamorphism. This is particularly useful in geothermobarometry.