Gelatin silver process

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The gelatin silver process is the most commonly used chemical process in black-and-white photography, and is the fundamental chemical process for modern analog color photography. As such, films and printing papers available for analog photography rarely rely on any other chemical process to record an image. A suspension of silver salts in gelatin is coated onto a support such as glass, flexible plastic or film, baryta paper, or resin-coated paper. These light-sensitive materials are stable under normal keeping conditions and are able to be exposed and processed even many years after their manufacture. The "dry plate" gelatin process was an improvement on the collodion wet-plate process dominant from the 1850s–1880s, which had to be exposed and developed immediately after coating.

Contents

A gelatin silver print of a Hawaiian girl Portrait of Young Hawaiian Girl, toned gelatin silver print, 1909, signed in pencil on lower right.jpg
A gelatin silver print of a Hawaiian girl

History

Gelatine was used to copy the images of Daguerreotypes by 1845 [1] and Alphonse Louis Poitevin wrote about positive proofs of negatives on dry gelatine plates in 1850. [2] [3]

In the 1860s, the dry plate collodion process (with gelatin or albumen) was described as advantageous for outdoor photography, especially when a large amount of shots in different places were required, or when there was little time. Negatives taken during summer outings could wait until the long winter evenings to be developed, fixed and printed. Exposure times were long compared to the wet process, but that required much more time to prepare a plate before exposure, to develop, fix and wash the negative soon after, with chemicals and a portable dark room that had to be dragged around and installed. [4]

The introduction of the gelatin silver process is commonly attributed to Richard Leach Maddox, author of the 1871 article An Experiment with Gelatino-Bromide. [5]

In 1873, Charles Harper Bennett discovered a method of hardening the emulsion, making it more resistant to friction.[ citation needed ] In 1878, Bennett discovered that by prolonged heating, the sensitivity of the emulsion could be greatly increased. While dry plate processes could previous only be used with long exposures, Bennett's plates attributed much to instantaneous photography turning into a very common practice.

George Eastman developed a machine to coat glass plates in 1879 and founded the Eastman Film and Dry Plate Company in 1881.

William de Wiveleslie Abney and Josef Maria Eder improved the formula with silver chloride.

Gelatin silver print paper was made as early as 1874 on a commercial basis, but it was poor quality because the dry-plate emulsion was coated onto the paper only as an afterthought. Coating machines for the production of continuous rolls of sensitized paper were in use by the mid-1880s, though widespread adoption of gelatin silver print materials did not occur until the 1890s. The earliest papers had no baryta layer, and it was not until the 1890s that baryta coating became a commercial operation, first in Germany, in 1894, and then taken up by Kodak by 1900.[ citation needed ]

Although the baryta layer plays an important part in the manufacture of smooth and glossy prints, the baryta paper of the 1890s did not produce the lustrous or glossy print surface that became the standard for fine art photography in the twentieth century. Matting agents, textured papers, and thin baryta layers that were not heavily calendering produced a low-gloss and textured appearance. The higher gloss papers first became popular in the 1920s and 30s as photography transitioned from pictorialism into modernism, photojournalism, and "straight" photography.[ citation needed ]

Research over the last 125 years has led to current materials that exhibit low grain and high sensitivity to light.

Childe Hassam by James W. Porter, 1913, silver print Childe Hassam by James W. Porter.jpg
Childe Hassam by James W. Porter, 1913, silver print

Timeline

Technology

Overview

The gelatin silver print or gelatin developing out paper (DOP) is a monochrome imaging process based on the light sensitivity of silver halides. They have been made for both contact printing and enlarging purposes by modifying the paper's light sensitivity. A brief exposure to a negative produces a latent image, which is then made visible by a developing agent. The image is then made permanent by treatment in a photographic fixer, which removes the remaining light sensitive silver halides. And finally, a water bath clears the fixer from the print. The final image consists of small particles of silver bound in a layer of gelatin. This gelatin image layer is only one of the four layers found in a typical gelatin silver print, which typically include the overcoat, image layer, baryta, and paper support.

Layer structure

A gelatin silver print is composed of four layers: paper base, baryta, gelatin binder, and a protective gelatin layer or overcoat. The multi-layer structure of the gelatin silver print and the sensitivity of the silver imaging salts require specialized coating equipment and fastidious manufacturing technique to produce a consistent product that is free of impurities harmful to the image.

The paper base or support serves as the substrate onto which the subsequent layers are attached. Paper is in many ways an ideal support: it is lightweight, flexible, and strong enough to withstand both wet processing and regular handling. The photographic paper base must be free of photoactive impurities such as iron and lignins. In order to obtain this purity, the paper was originally made from cotton rags, though after World War I there was a transition to purified wood pulp, which has been used ever since.

The second layer is the baryta, a white opaque coating made primarily from gelatin and barium sulfate. Its purpose is to cover the paper fibers and form a smooth surface upon which to coat the gelatin. Surface textures are created by a variety of textured felts used in the drying of the paper, calendaring, and embossing before or after application of the baryta layer depending on the desired effect.

The third layer is the gelatin binder that holds the silver grains of the photographic image. Gelatin has many qualities that make it an ideal photographic binder. Among these are toughness and abrasion resistance when dry and its ability to swell and allow the penetration of processing solutions. The fourth layer, called the overcoat, supercoat, or topcoat, is a very thin layer of hardened gelatin that is applied on top of the gelatin binder. It acts as a protective layer, providing superior abrasion resistance to the print surface.

Image and processing

Before a paper is exposed, the image layer is a clear gelatin matrix holding the light-sensitive silver halides. For gelatin silver prints, these silver halides are typically combinations of silver bromide and silver chloride. Exposure to a negative is typically done with an enlarger, although contact printing was also popular, particularly among amateurs in the early twentieth century and among users of large format cameras. Wherever the light strikes the paper the silver halides form small specks of silver metal on their surface by the chemical process of reduction. The exposure is the greatest in areas of the print corresponding to clear parts of the negatives, which become the shadows or high density areas of the print.

This process is the formation of the latent image, as it forms an invisible image in the paper that is subsequently made visible by development. The paper is placed in the developer, which transforms the silver halide particles that have a latent image speck on them into metallic silver. Now the image is visible, but the remaining unexposed silver halide must still be removed to make the image permanent. But first the print is placed into the stop bath, which stops development and prevents the developer from contaminating the next bath: the fixer.

The fixer, typically sodium thiosulfate, is able to remove the unexposed silver halide by forming a water-soluble complex with it. And finally, a water wash sometimes preceded by a washing aid removes the fixer from the print, leaving an image composed of silver particles held in the clear gelatin image layer. Toning is sometimes used for permanence or aesthetic purposes and follows the fixing step. Selenium, gold, and sulfur toners are the most common and act by either partially converting the silver to another compound (such as silver selenide or silver sulfide) or partially replacing the silver with another metal (such as gold). [6]

When small crystals (called grains) of silver salts such as silver bromide and silver chloride are exposed to light, a few atoms of free metallic silver are liberated. These free silver atoms form the latent image. This latent image is relatively stable and will persist for some months without degradation provided the film is kept dark and cool. Films are developed using solutions that reduce silver halides in the presence of free silver atoms. An 'amplification' of the latent image occurs as the silver halides near the free silver atom are reduced to metallic silver. The strength, temperature and time for which the developer is allowed to act allow the photographer to control the contrast of the final image. The development is then stopped by neutralizing the developer in a second bath.

Once development is complete, the undeveloped silver salts must be removed by fixing in sodium thiosulphate or ammonium thiosulphate, and then the negative or print must be washed in clean water. The final image consists of metallic silver embedded in the gelatin coating.

All gelatin silver photographic materials are subject to deterioration. The silver particles that comprise the image are susceptible to oxidation, leading to yellowing and fading of the image. Poor processing can also result in various forms of image degradation, due to residual silver-thiosulfate complexes. Toning increases the stability of the silver image by coating the silver image with a less easily oxidized metal such as gold, or by converting portions of the silver image particles into more stable compounds, such as silver selenide or silver sulfide. [6]

Digital silver gelatin printing

Also known as digital bromides, black and white silver gelatin prints imaged via digital output devices such as the Durst Lambda and the Océ LightJet, have been developed for the art market by Ilford Imaging.

By adapting a large format paper processor in conjunction with the manufacturers, McLeod's innovation led the way for the possibility of producing large resin coated (RC) and fibre based (FB) black and white prints.

Ilford, in collaboration with Metro Imaging, London adapted their FB Galerie emulsion paper and its light sensitivity so that it would be receptive to full spectrum RGB laser channels.

In molecular biology

An essentially identical procedure called "silver staining" is utilized in molecular biology to visualize DNA or proteins after gel electrophoresis, usually SDS-PAGE. The latent image is formed by the DNA or RNA or protein molecules (i.e. the reduced silver selectively precipitates onto those molecules). It is known for being nearly as sensitive as autoradiography, the "gold standard" technique, but one not widely used due to the use of radioactive materials. [7]

Related Research Articles

<span class="mw-page-title-main">Film stock</span> Medium used for recording motion pictures

Film stock is an analog medium that is used for recording motion pictures or animation. It is recorded on by a movie camera, developed, edited, and projected onto a screen using a movie projector. It is a strip or sheet of transparent plastic film base coated on one side with a gelatin emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the crystals determine the sensitivity, contrast and resolution of the film. The emulsion will gradually darken if left exposed to light, but the process is too slow and incomplete to be of any practical use. Instead, a very short exposure to the image formed by a camera lens is used to produce only a very slight chemical change, proportional to the amount of light absorbed by each crystal. This creates an invisible latent image in the emulsion, which can be chemically developed into a visible photograph. In addition to visible light, all films are sensitive to X-rays and high-energy particles. Most are at least slightly sensitive to invisible ultraviolet (UV) light. Some special-purpose films are sensitive into the infrared (IR) region of the spectrum.

<span class="mw-page-title-main">Collodion process</span> Early photographic technique

The collodion process is an early photographic process. The collodion process, mostly synonymous with the "collodion wet plate process", requires the photographic material to be coated, sensitized, exposed, and developed within the span of about fifteen minutes, necessitating a portable darkroom for use in the field. Collodion is normally used in its wet form, but it can also be used in its dry form, at the cost of greatly increased exposure time. The increased exposure time made the dry form unsuitable for the usual portraiture work of most professional photographers of the 19th century. The use of the dry form was mostly confined to landscape photography and other special applications where minutes-long exposure times were tolerable.

Photographic processing or photographic development is the chemical means by which photographic film or paper is treated after photographic exposure to produce a negative or positive image. Photographic processing transforms the latent image into a visible image, makes this permanent and renders it insensitive to light.

<span class="mw-page-title-main">Photographic paper</span> Light-sensitive paper used to make photographic prints

Photographic paper is a paper coated with a light-sensitive chemical formula, like photographic film, used for making photographic prints. When photographic paper is exposed to light, it captures a latent image that is then developed to form a visible image; with most papers the image density from exposure can be sufficient to not require further development, aside from fixing and clearing, though latent exposure is also usually present. The light-sensitive layer of the paper is called the emulsion. The most common chemistry was based on silver halide but other alternatives have also been used.

<span class="mw-page-title-main">Photographic developer</span> Chemical(s) which convert a latent image on photographic film to a visible image

In the processing of photographic films, plates or papers, the photographic developer is one or more chemicals that convert the latent image to a visible image. Developing agents achieve this conversion by reducing the silver halides, which are pale-colored, into silver metal, which is black when in the form of fine particles. The conversion occurs within the gelatine matrix. The special feature of photography is that the developer acts more quickly on those particles of silver halide that have been exposed to light. When left in developer, all the silver halides will eventually be reduced and turn black. Generally, the longer a developer is allowed to work, the darker the image.

<span class="mw-page-title-main">Albumen print</span> Photographic process

The albumen print, also called albumen silver print, was published in January 1847 by Louis Désiré Blanquart-Evrard, and was the first commercially exploitable method of producing a photographic print on a paper base from a negative. It used the albumen found in egg whites to bind the photographic chemicals to the paper and became the dominant form of photographic positives from 1855 to the start of the 20th century, with a peak in the 1860–90 period. During the mid-19th century, the carte de visite became one of the more popular uses of the albumen method. In the 19th century, E. & H. T. Anthony & Company were the largest makers and distributors of albumen photographic prints and paper in the United States.

Photographic printing is the process of producing a final image on paper for viewing, using chemically sensitized paper. The paper is exposed to a photographic negative, a positive transparency , or a digital image file projected using an enlarger or digital exposure unit such as a LightJet or Minilab printer. Alternatively, the negative or transparency may be placed atop the paper and directly exposed, creating a contact print. Digital photographs are commonly printed on plain paper, for example by a color printer, but this is not considered "photographic printing".

C-41 is a chromogenic color print film developing process introduced by Kodak in 1972, superseding the C-22 process. C-41, also known as CN-16 by Fuji, CNK-4 by Konica, and AP-70 by AGFA, is the most popular film process in use, with most, if not all photofinishing labs devoting at least one machine to this development process.

<span class="mw-page-title-main">Platinum print</span>

Platinum prints, also called platinotypes, are photographic prints made by a monochrome printing process involving platinum.

<span class="mw-page-title-main">Silver bromide</span> Chemical compound

Silver bromide (AgBr) is a soft, pale-yellow, water-insoluble salt well known for its unusual sensitivity to light. This property has allowed silver halides to become the basis of modern photographic materials. AgBr is widely used in photographic films and is believed by some to have been used for making the Shroud of Turin. The salt can be found naturally as the mineral bromargyrite.

A silver halide is one of the chemical compounds that can form between the element silver (Ag) and one of the halogens. In particular, bromine (Br), chlorine (Cl), iodine (I) and fluorine (F) may each combine with silver to produce silver bromide (AgBr), silver chloride (AgCl), silver iodide (AgI), and four forms of silver fluoride, respectively.

<span class="mw-page-title-main">Latent image</span> An invisible image produced by the exposure of a photosensitive material to light.

A latent image is an invisible image produced by the exposure to light of a photosensitive material such as photographic film. When photographic film is developed, the area that was exposed darkens and forms a visible image. In the early days of photography, the nature of the invisible change in the silver halide crystals of the film's emulsion coating was unknown, so the image was said to be "latent" until the film was treated with photographic developer.

The conservation and restoration of photographs is the study of the physical care and treatment of photographic materials. It covers both efforts undertaken by photograph conservators, librarians, archivists, and museum curators who manage photograph collections at a variety of cultural heritage institutions, as well as steps taken to preserve collections of personal and family photographs. It is an umbrella term that includes both preventative preservation activities such as environmental control and conservation techniques that involve treating individual items. Both preservation and conservation require an in-depth understanding of how photographs are made, and the causes and prevention of deterioration. Conservator-restorers use this knowledge to treat photographic materials, stabilizing them from further deterioration, and sometimes restoring them for aesthetic purposes.

A chromogenic print, also known as a C-print or C-type print, a silver halide print, or a dye coupler print, is a photographic print made from a color negative, transparency or digital image, and developed using a chromogenic process. They are composed of three layers of gelatin, each containing an emulsion of silver halide, which is used as a light-sensitive material, and a different dye coupler of subtractive color which together, when developed, form a full-color image.

Photographic emulsion is a light-sensitive colloid used in film-based photography. Most commonly, in silver-gelatin photography, it consists of silver halide crystals dispersed in gelatin. The emulsion is usually coated onto a substrate of glass, films, paper, or fabric. The substrate is often flexible and known as a film base.

Dye transfer is a continuous-tone color photographic printing process. It was used to print Technicolor films, as well as to produce paper colour prints used in advertising, or large transparencies for display.

<span class="mw-page-title-main">Photographic film</span> Film used by film (analog) cameras

Photographic film is a strip or sheet of transparent film base coated on one side with a gelatin emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the crystals determine the sensitivity, contrast, and resolution of the film. Film is typically segmented in frames, that give rise to separate photographs.

Photographic hypersensitization refers to a set of processes that can be applied to photographic film or plates before exposing. One or more of these processes is often needed to make photographic materials work better in long exposures.

<span class="mw-page-title-main">Oil print process</span>

The oil print process is a photographic printmaking process that dates to the mid-19th century. Oil prints are made on paper on which a thick gelatin layer has been sensitized to light using dichromate salts. After the paper is exposed to light through a negative, the gelatin emulsion is treated in such a way that highly exposed areas take up an oil-based paint, forming the photographic image.

<span class="mw-page-title-main">Conservation and restoration of photographic plates</span>

The conservation and restoration of photographic plates is caring for and maintaining photographic plates to preserve their materials and content. It covers the necessary measures that can be taken by conservators, curators, collection managers, and other professionals to conserve the material unique to photographic plate processes. This practice includes understanding the composition and agents of deterioration of photographic plates, as well as the preventive conservation and interventive conservation measures that can be taken to increase their longevity.

References

  1. THORNTHWAITE, William Henry (1845). A guide to photography; containing simple and practical details of the latest and most improved processes for the production of pictures by the chemical action of light, including photogenic drawing, calotype, Daguerreotype, ... illustrated with drawings on stone. Horne, Thornthwaite, and Wood; R. Groombridge and Sons.
  2. The Chemist: A Monthly Journal of Chemical Philosophy. 1850.
  3. The Civil engineer & [and] architect's journal. Kent. 1850.
  4. Towler, John (1865). Dry Plate Photography: Or, The Tannin Process, Made Simple and Practical for Operators and Amateurs. J.H. Ladd.
  5. "An Experiment With Gelatino Bromide - [PDF Document]". vdocuments.mx. Retrieved 2023-02-21.
  6. 1 2 Weaver, Gawain (2008). "A Guide to Fiber-Base Gelatin Silver Print Condition and Deterioration" (PDF). George Eastman House, International Museum of Photography and Film. Retrieved 30 October 2009.
  7. Bassam, Brant J (25 October 2007). "Silver staining DNA in polyacrylamide gels". Nature Protocols. 2 (11): 2649–2654. doi:10.1038/nprot.2007.330. PMID   18007600. S2CID   22136479.

Further reading