Lead-tin-yellow is a yellow pigment, of historical importance in oil painting,also known as the "Yellow of the Old Masters".
Lead-tin-yellow historically occurred in two varieties. The first and more common one, today known as "Type I", was a lead stannate, an oxide of lead and tin with the chemical formula Pb2SnO4. The second, "Type II", was a silicate with the formula Pb(Sn,Si)O3. °C. In "Type II" the mixture also contained quartz. Its hue is a rather saturated yellow. The pigment is opaque and lightfast. It is also highly poisonous, through either prolonged ingestion, inhalation or skin contact, due to the lead component.Lead-tin-yellow was produced by heating a powder mixture of lead oxide and tin oxide to about 900
The origin of lead-tin-yellow can be dated back to at least the thirteenth century when Type II was applied in frescos, perhaps having been discovered as a by-product of crystal glass production. Until the eighteenth century Type I was the standard yellow used in oil painting. It was then almost completely replaced in use by Naples yellow. After 1750, no paintings seem to have been made containing the pigment.In the nineteenth century its existence had been forgotten and its application was only in 1941 rediscovered by the German scientist Richard Jakobi, the director of the Doerner Institute. That it faded from collective memory has been explained by a confusion with massicot, the name of which was also applied to lead-tin-yellow. The term "lead-tin-yellow", a literal translation of German Blei-Zinn-Gelb, is therefore a modern designation, not the historical name of the pigment. In English it used to be called "general" after the Italian giallorino. After 1967, Hermann Kühn in a series of studies proved its general use in the traditional oil technique of earlier centuries, coining the distinction between the Type I and Type II varieties.
Lead-tin-yellow was employed in the Renaissanceby painters such as Titian (Bacchus and Ariadne), Bellini (The Feast of the Gods) and Raphael (Sistine Madonna), and during the Baroque period by Rembrandt (Belshazzar's Feast), Vermeer (The Milkmaid), and Velázquez (Apollo in the Forge of Vulcan).
Lead-tin-yellow was displaced in use by Naples Yellow, which is less opaque. During the nineteenth century, newer inorganic yellow pigments came into use, such as chrome yellow (lead chromate), cadmium sulfide, and cobalt yellow.