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Martempering is also known as stepped quenching or interrupted quenching. In this process, steel is heated above the upper critical point (above the transformation range) and then quenched in a salt, oil, or lead bath kept at a temperature of 150-300 °C. The workpiece is held at this temperature above martensite start (Ms) point until the temperature becomes uniform throughout the cross-section of workpiece. After that it is cooled in air or oil to room temperature. The steel is then tempered. In this process, Austenite is transformed to martensite by step quenching, at a rate fast enough to avoid the formation of ferrite, pearlite or bainite. [1] [2]

Phase transition transitions between solid, liquid and gaseous states of matter, and, in rare cases, plasma

The term phase transition is most commonly used to describe transitions between solid, liquid, and gaseous states of matter, as well as plasma in rare cases. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change, often discontinuously, as a result of the change of external conditions, such as temperature, pressure, or others. For example, a liquid may become gas upon heating to the boiling point, resulting in an abrupt change in volume. The measurement of the external conditions at which the transformation occurs is termed the phase transition. Phase transitions commonly occur in nature and are used today in many technologies.

Salt mineral used as ingredient, composed primarily of sodium chloride (NaCl)

Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in its natural form as a crystalline mineral is known as rock salt or halite. Salt is present in vast quantities in seawater, where it is the main mineral constituent. The open ocean has about 35 grams (1.2 oz) of solids per liter of sea water, a salinity of 3.5%.

An oil is any nonpolar chemical substance that is a viscous liquid at ambient temperatures and is both hydrophobic and lipophilic. Oils have a high carbon and hydrogen content and are usually flammable and surface active.


In the martempering process, austenitized metal part is immersed in a bath at a temperature just above the martensite start temperature (Ms). By using interrupted quenching, the cooling is stopped at a point above the martensite transformation region to ensure sufficient time for the center to cool to the same temperature as the surface. The metal part is then removed from the bath and cooled in air to room temperature to permit the austenite to transform to martensite. Martempering is a method by which the stresses and strains generated during the quenching of a steel component can be controlled. In Martempering steel is heated to above the critical range to make it all austenite.

The drawback of this process is that the large section cannot be heat treated by this process.

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Steel alloy made by combining iron and other elements

Steel is an alloy of iron and carbon, and sometimes other elements. Because of its high tensile strength and low cost, it is a major component used in buildings, infrastructure, tools, ships, automobiles, machines, appliances, and weapons.

Differential heat treatment

Differential heat treatment is a technique used during heat treating to harden or soften certain areas of a steel object, creating a difference in hardness between these areas. There are many techniques for creating a difference in properties, but most can be defined as either differential hardening or differential tempering. These were common heat treating techniques used historically in Europe and Asia, with possibly the most widely known example being from Japanese swordsmithing. Some modern varieties were developed in the twentieth century as metallurgical knowledge and technology rapidly increased.

Heat treating process of heating something to alter it

Heat treating is a group of industrial and metalworking processes used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgical. Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, to achieve a desired result such as hardening or softening of a material. Heat treatment techniques include annealing, case hardening, precipitation strengthening, tempering, carburizing, normalizing and quenching. It is noteworthy that while the term heat treatment applies only to processes where the heating and cooling are done for the specific purpose of altering properties intentionally, heating and cooling often occur incidentally during other manufacturing processes such as hot forming or welding.

Martensite most commonly refers to a very hard form of steel crystalline structure, but it can also refer to any crystal structure that is formed by diffusionless transformation.

Martensite is named after the German metallurgist Adolf Martens (1850–1914). The term most commonly refers to a very hard form of steel crystalline structure, but can also refer to any crystal structure that is formed by diffusionless transformation. Martensite includes a class of hard minerals that occur as lath- or plate-shaped crystal grains.

Austenite metallic, non-magnetic allotrope of iron or a solid solution of iron, with an alloying element

Austenite, also known as gamma-phase iron (γ-Fe), is a metallic, non-magnetic allotrope of iron or a solid solution of iron, with an alloying element. In plain-carbon steel, austenite exists above the critical eutectoid temperature of 1000 K (727 °C); other alloys of steel have different eutectoid temperatures. The austenite allotrope is named after Sir William Chandler Roberts-Austen (1843–1902); it exists at room temperature in stainless steel.


Bainite is a plate-like microstructure that forms in steels at temperatures of 125–550 °C. First described by E. S. Davenport and Edgar Bain, it is one of the products that may form when austenite is cooled past a temperature where it no longer is thermodynamically stable with respect to ferrite, cementite, or ferrite and cementite. Davenport and Bain originally described the microstructure as being similar in appearance to tempered martensite.

Carbon steel steel in which the main interstitial alloying constituent is carbon

Carbon steel is a steel with carbon content up to 2.1% by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states:

Quenching rapid cooling of a workpiece to obtain certain material properties

In materials science, quenching is the rapid cooling of a workpiece in water, oil or air to obtain certain material properties. A type of heat treating, quenching prevents undesired low-temperature processes, such as phase transformations, from occurring. It does this by reducing the window of time during which these undesired reactions are both thermodynamically favorable, and kinetically accessible; for instance, quenching can reduce the crystal grain size of both metallic and plastic materials, increasing their hardness.

Carburizing Heat treatment process in which a metal absorbs carbon while the metal is heated in the presence of a carbon-bearing material, such as charcoal or carbon monoxide

Carburizing, carburising, or carburization is a heat treatment process in which iron or steel absorbs carbon while the metal is heated in the presence of a carbon-bearing material, such as charcoal or carbon monoxide. The intent is to make the metal harder. Depending on the amount of time and temperature, the affected area can vary in carbon content. Longer carburizing times and higher temperatures typically increase the depth of carbon diffusion. When the iron or steel is cooled rapidly by quenching, the higher carbon content on the outer surface becomes hard due to the transformation from austenite to martensite, while the core remains soft and tough as a ferritic and/or pearlite microstructure.

Maraging steel steel

Maraging steels are steels that are known for possessing superior strength and toughness without losing ductility. Aging refers to the extended heat-treatment process. These steels are a special class of low-carbon ultra-high-strength steels that derive their strength not from carbon, but from precipitation of intermetallic compounds. The principal alloying element is 15 to 25 wt.% nickel. Secondary alloying elements, which include cobalt, molybdenum and titanium, are added to produce intermetallic precipitates. Original development was carried out on 20 and 25 wt.% Ni steels to which small additions of Al, Ti, and Nb were made; a rise in the price of cobalt in the late 1970s led to the development of cobalt-free maraging steels.


Case-hardening or surface hardening is the process of hardening the surface of a metal object while allowing the metal deeper underneath to remain soft, thus forming a thin layer of harder metal at the surface. For iron or steel with low carbon content, which has poor to no hardenability of its own, the case-hardening process involves infusing additional carbon or nitrogen into the surface layer. Case-hardening is usually done after the part has been formed into its final shape, but can also be done to increase the hardening element content of bars to be used in a pattern welding or similar process. The term face hardening is also used to describe this technique, when discussing modern armour.

Tempering (metallurgy) metallurgy

Tempering is a process of heat treating, which is used to increase the toughness of iron-based alloys. Tempering is usually performed after hardening, to reduce some of the excess hardness, and is done by heating the metal to some temperature below the critical point for a certain period of time, then allowing it to cool in still air. The exact temperature determines the amount of hardness removed, and depends on both the specific composition of the alloy and on the desired properties in the finished product. For instance, very hard tools are often tempered at low temperatures, while springs are tempered to much higher temperatures.


The hardenability of a metal alloy is the depth to which a material is hardened after putting it through a heat treatment process. The unit of hardenability is length. It is an indication of how deep into the material a certain hardness can be achieved. It should not be confused with hardness, which is a measure of a sample's resistance to indentation or scratching. It is an important property for welding, since it is inversely proportional to weldability, that is, the ease of welding a material.

Cryogenic hardening is a cryogenic treatment process where the material is cooled to approximately −185 °C (−301 °F), usually using liquid nitrogen. It can have a profound effect on the mechanical properties of certain steels, provided their composition and prior heat treatment are such that they retain some austenite at room temperature. It is designed to increase the amount of martensite in the steel's crystal structure, increasing its strength and hardness, sometimes at the cost of toughness. Presently this treatment is being practiced over tool steels, high-carbon, and high-chromium steels to obtain excellent wear resistance. Recent research shows that there is precipitation of fine carbides in the matrix during this treatment which imparts very high wear resistance to the steels.

Hardening is a metallurgical metalworking process used to increase the hardness of a metal. The hardness of a metal is directly proportional to the uniaxial yield stress at the location of the imposed strain. A harder metal will have a higher resistance to plastic deformation than a less hard metal.

Annealing, in metallurgy and materials science, is a heat treatment that alters the physical and sometimes chemical properties of a material to increase its ductility and reduce its hardness, making it more workable. It involves heating a material above its recrystallization temperature, maintaining a suitable temperature for a suitable amount of time, and then cooling.

Hardened steel

The term hardened steel is often used for a medium or high carbon steel that has been given heat treatment and then quenching followed by tempering. The quenching results in the formation of metastable martensite, the fraction of which is reduced to the desired amount during tempering. This is the most common state for finished articles such as tools and machine parts. In contrast, the same steel composition in annealed state is softer, as required for forming and machining.

Isothermal transformation diagram

Isothermal transformation diagrams are plots of temperature versus time. They are generated from percentage transformation-vs time measurements, and are useful for understanding the transformations of an alloy steel at elevated temperatures.

Methods have been devised to modify the yield strength, ductility, and toughness of both crystalline and amorphous materials. These strengthening mechanisms give engineers the ability to tailor the mechanical properties of materials to suit a variety of different applications. For example, the favorable properties of steel result from interstitial incorporation of carbon into the iron lattice. Brass, a binary alloy of copper and zinc, has superior mechanical properties compared to its constituent metals due to solution strengthening. Work hardening has also been used for centuries by blacksmiths to introduce dislocations into materials, increasing their yield strengths.


Austempering is heat treatment that is applied to ferrous metals, most notably steel and ductile iron. In steel it produces a bainite microstructure whereas in cast irons it produces a structure of acicular ferrite and high carbon, stabilized austenite known as ausferrite. It is primarily used to improve mechanical properties or reduce / eliminate distortion. Austempering is defined by both the process and the resultant microstructure. Typical austempering process parameters applied to an unsuitable material will not result in the formation of bainite or ausferrite and thus the final product will not be called austempered. Both microstructures may also be produced via other methods. For example, they may be produced as-cast or air cooled with the proper alloy content. These materials are also not referred to as austempered.


  1. Abbasi, F.; Fletcher, A.J.; Soomro, A.B. (1987). "A critical assessment of the hardening of steel by martempering". International Journal of Production Research. 25 (7): 1069. doi:10.1080/00207548708919896.
  2. Yazıcı, A (2012). "Investigation of the Wear Behavior of Martempered 30MnB5 Steel for Soil Tillage". Transactions of the ASABE. 55 (1): 15–20. doi:10.13031/2013.41243.