Perovskite

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Perovskite
Perovskite-155026.jpg
General
Category Oxide minerals
Formula
(repeating unit)
CaTiO3
Strunz classification 4.CC.30
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Pnma
Identification
Formula mass 135.96 g/mol
ColorBlack, reddish brown, pale yellow, yellowish orange
Crystal habit Pseudo cubic – crystals show a cubic outline
Twinning complex penetration twins
Cleavage [100] good, [010] good, [001] good
Fracture Conchoidal
Mohs scale hardness5–5.5
Luster Adamantine to metallic; may be dull
Streak grayish white
Diaphaneity Transparent to opaque
Specific gravity 3.98–4.26
Optical propertiesBiaxial (+)
Refractive index nα = 2.3, nβ = 2.34, nγ = 2.38
Other characteristicsnon-radioactive, non-magnetic
References [1] [2] [3] [4]

Perovskite (pronunciation: /pəˈrɒvskt/ ) is a calcium titanium oxide mineral composed of calcium titanate (Ca Ti O 3). It lends its name to the class of compounds which have the same type of crystal structure as CaTiO3 (XIIA2+VIB4+X2−3), known as the perovskite structure. [5] Many different cations can be embedded in this structure, allowing the development of diverse engineered materials. [6]

Calcium Chemical element with atomic number 20

Calcium is a chemical element with symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to its heavier homologues strontium and barium. It is the fifth most abundant element in Earth's crust and the third most abundant metal, after iron and aluminium. The most common calcium compound on Earth is calcium carbonate, found in limestone and the fossilised remnants of early sea life; gypsum, anhydrite, fluorite, and apatite are also sources of calcium. The name derives from Latin calx "lime", which was obtained from heating limestone.

Titanium Chemical element with atomic number 22

Titanium is a chemical element with symbol Ti and atomic number 22. It is a lustrous transition metal with a silver color, low density, and high strength. Titanium is resistant to corrosion in sea water, aqua regia, and chlorine.

Calcium titanate chemical compound

Calcium titanate is an inorganic compound with the chemical formula CaTiO3. As a mineral, it is called perovskite, named after Russian mineralogist, L. A. Perovski (1792-1856). It is a colourless, diamagnetic solid, although the mineral is often coloured owing to impurities.

Contents

History

The mineral was discovered in the Ural Mountains of Russia by Gustav Rose in 1839 and is named after Russian mineralogist Lev Perovski (1792–1856). [2] Perovskite's notable crystal structure was first described by Victor Goldschmidt in 1926, in his work on tolerance factors. [7] The crystal structure was later published in 1945 from X-ray diffraction data on barium titanate by Helen Dick Megaw. [8]

Ural Mountains mountain range in Russia

The Ural Mountains, or simply the Urals, are a mountain range that runs approximately from north to south through western Russia, from the coast of the Arctic Ocean to the Ural River and northwestern Kazakhstan. The mountain range forms part of the conventional boundary between the continents of Europe and Asia. Vaygach Island and the islands of Novaya Zemlya form a further continuation of the chain to the north into the Arctic Ocean.

Russia transcontinental country in Eastern Europe and Northern Asia

Russia, officially the Russian Federation, is a transcontinental country in Eastern Europe and North Asia. At 17,125,200 square kilometres (6,612,100 sq mi), Russia is the largest country in the world by area, covering more than one-eighth of the Earth's inhabited land area, and the ninth most populous, with about 146.77 million people as of 2019, excluding Crimea. About 77% of the population live in the western, European part of the country. Russia's capital, Moscow, is the largest metropolitan area in Europe proper and one of the largest cities in the world; other major cities include Saint Petersburg, Novosibirsk, Yekaterinburg and Nizhny Novgorod. Extending across the entirety of Northern Asia and much of Eastern Europe, Russia spans eleven time zones and incorporates a wide range of environments and landforms. From northwest to southeast, Russia shares land borders with Norway, Finland, Estonia, Latvia, Lithuania and Poland, Belarus, Ukraine, Georgia, Azerbaijan, Kazakhstan, China, Mongolia and North Korea. It shares maritime borders with Japan by the Sea of Okhotsk and the U.S. state of Alaska across the Bering Strait. However, Russia recognises two more countries that border it, Abkhazia and South Ossetia, both of which are internationally recognized as parts of Georgia.

Gustav Rose mineralogist


Prof Gustavus ("Gustav") Rose FRSFor HFRSE was a German mineralogist who was a native of Berlin. He was President of the German Geological Society from 1863 to 1873.

Occurrence

Found in the Earth’s mantle, perovskite’s occurrence at Khibina Massif is restricted to the under-saturated ultramafic rocks and foidolites, due to the instability in a paragenesis with feldspar. Perovskite occurs as small anhedral to subhedral crystals filling interstices between the rock-forming silicates. [9]

A mantle is a layer inside a planetary body bounded below by a core and above by a crust. Mantles are made of rock or ices, and are generally the largest and most massive layer of the planetary body. Mantles are characteristic of planetary bodies that have undergone differentiation by density. All terrestrial planets, a number of asteroids, and some planetary moons have mantles.

Khibiny Mountains mountain range

The Khibiny Massif, Khibiny Mountains, Khibinsky Mountains or Khibins, Khibinsky tundras, Khibiny is one of the two main mountain ranges of the Kola Peninsula, Russia, within the Arctic Circle, located between Imandra and Umbozero lakes.

Foidolite A rare coarse-grained intrusive igneous rock in which more than 60% of light-coloured minerals are feldspathoids

Foidolite is a rare coarse-grained intrusive igneous rock in which more than 60% of light-coloured minerals are feldspathoids. Crystals of alkali feldspar, plagioclase, biotite, amphibole, pyroxene, and/or olivine may be present within the rock. The volcanic equivalents are termed foidite and phonolitic or tephritic foidites.

Perovskite is found in contact carbonate skarns at Magnet Cove, Arkansas, in altered blocks of limestone ejected from Mount Vesuvius, in chlorite and talc schist in the Urals and Switzerland, [10] and as an accessory mineral in alkaline and mafic igneous rocks, nepheline syenite, melilitite, kimberlites and rare carbonatites. Perovskite is a common mineral in the Ca-Al-rich inclusions found in some chondritic meteorites. [3]

Carbonate rock

Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3) and dolostone, which is composed of the mineral dolomite (CaMg(CO3)2).

Skarn Hard, coarse-grained, hydrothermally altered metamorphic rocks

Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals. These minerals form as a result of alteration which occurs when hydrothermal fluids interact with a protolith of either igneous or sedimentary origin. In many cases, skarns are associated with the intrusion of a granitic pluton found in and around faults or Shear zones that intrude into a carbonate layer such as a dolomite or limestone. Skarns can form by regional, or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from either magmatic, metamorphic, meteoric, marine, or even a mix of these. The resulting skarn may consist of a variety of different minerals which are highly dependent on the original composition of both the hydrothermal fluid and the original composition of the protolith.

The Magnet Cove igneous complex is a small alkalic ring complex lying to the west of the town of Magnet Cove in Hot Spring County, Arkansas. It and the adjacent town are so named due to the existence of magnetite and the terrain being a cove, a basin-shaped valley.

A rare-earth-bearing variety knopite (Ca,Ce,Na)(Ti,Fe)O3) is found in alkali intrusive rocks in the Kola Peninsula and near Alnö, Sweden. A niobium-bearing variety dysanalyte occurs in carbonatite near Schelingen, Kaiserstuhl, Germany. [10] [11]

Kola Peninsula peninsula in the northwest of Russia

The Kola Peninsula is a peninsula in the far northwest of Russia. Constituting the bulk of the territory of Murmansk Oblast, it lies almost completely inside the Arctic Circle and is bordered by the Barents Sea in the north and the White Sea in the east and southeast. The city of Murmansk is the most populous human settlement on the peninsula, with a population of over 300,000 as of the 2010 Census.

Sweden constitutional monarchy in Northern Europe

Sweden, officially the Kingdom of Sweden, is a Scandinavian Nordic country in Northern Europe. It borders Norway to the west and north and Finland to the east, and is connected to Denmark in the southwest by a bridge-tunnel across the Öresund, a strait at the Swedish-Danish border. At 450,295 square kilometres (173,860 sq mi), Sweden is the largest country in Northern Europe, the third-largest country in the European Union and the fifth largest country in Europe by area. Sweden has a total population of 10.2 million of which 2.4 million has a foreign background. It has a low population density of 22 inhabitants per square kilometre (57/sq mi). The highest concentration is in the southern half of the country.

Niobium Chemical element with atomic number 41

Niobium, formerly known as columbium, is a chemical element with symbol Nb and atomic number 41. It is a soft, grey, crystalline, ductile transition metal, often found in the minerals pyrochlore and columbite, hence the former name "columbium". Its name comes from Greek mythology, specifically Niobe, who was the daughter of Tantalus, the namesake of tantalum. The name reflects the great similarity between the two elements in their physical and chemical properties, making them difficult to distinguish.

Special characteristics

The stability of perovskite in igneous rocks is limited by its reaction relation with sphene. In volcanic rocks perovskite and sphene are not found together, the only exception being in an etindite from Cameroon. [12]

Cameroon republic in West Africa

Cameroon, officially the Republic of Cameroon, is a country in Central Africa. It is bordered by Nigeria to the west and north; Chad to the northeast; the Central African Republic to the east; and Equatorial Guinea, Gabon and the Republic of the Congo to the south. Cameroon's coastline lies on the Bight of Biafra, part of the Gulf of Guinea and the Atlantic Ocean. Although Cameroon is not an ECOWAS member state, it geographically and historically is in West Africa with the Southern Cameroons which now form her Northwest and Southwest Regions having a strong West African history. The country is sometimes identified as West African and other times as Central African due to its strategic position at the crossroads between West and Central Africa.

Physical properties

Perovskites have a cubic structure with general formula of ABO
3
. In this structure, an A-site ion, on the corners of the lattice, is usually an alkaline earth or rare-earth element. B-site ions, on the center of the lattice, could be 3d, 4d, and 5d transition metal elements. A large number of metallic elements are stable in the perovskite structure, if the tolerance factor t is in the range of 0.75–1.0. [13]

where RA, RB and RO are the ionic radii of A and B site elements and oxygen, respectively.

Perovskites have sub-metallic to metallic luster, colorless streak, cube like structure along with imperfect cleavage and brittle tenacity. Colors include black, brown, gray, orange to yellow. Crystals of perovskite appear as cubes, but are pseudocubic and crystallize in the orthorhombic system. Perovskite crystals have been mistaken for galena; however, galena has a better metallic luster, greater density, perfect cleavage and true cubic symmetry. [14]

See also

Related Research Articles

Titanite nesosilicate mineral

Titanite, or sphene (from the Greek sphenos (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, CaTiSiO5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals including cerium and yttrium; calcium may be partly replaced by thorium.

Alkaline earth metal group of chemical elements

The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra). The elements have very similar properties: they are all shiny, silvery-white, somewhat reactive metals at standard temperature and pressure.

Zircon Zirconium silicate, a mineral belonging to the group of nesosilicates

Zircon ( or ) is a mineral belonging to the group of nesosilicates. Its chemical name is zirconium silicate, and its corresponding chemical formula is ZrSiO4. A common empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon forms in silicate melts with large proportions of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue and green. Colorless specimens that show gem quality are a popular substitute for diamond and are also known as "Matura diamond".

Pyrochlore mineral group, pyrochlore supergroup

Pyrochlore (Na,Ca)2Nb2O6(OH,F) is a mineral group of the niobium end member of the pyrochlore supergroup. The general formula, A2B2O7 (A and B are metals), represent a family of phases isostructural to the mineral pyrochlore. Pyrochlores are important class of materials from the point of view of diverse technological applications like in luminescence, ionic conductivity, nuclear waste immobilization, high temperature thermal barrier coatings, automobile exhaust gas control, catalysts, solid oxide fuel cell, ionic/electric conductors etc.

Baddeleyite oxide mineral

Baddeleyite is a rare zirconium oxide mineral (ZrO2 or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown. See etymology below.

Perovskite (structure)

A perovskite is any material with the same type of crystal structure as calcium titanium oxide (CaTiO3), known as the perovskite structure, or XIIA2+VIB4+X2−3 with the oxygen in the edge centers. Perovskites take their name from the mineral, which was first discovered in the Ural mountains of Russia by Gustav Rose in 1839 and is named after Russian mineralogist L. A. Perovski (1792–1856). The general chemical formula for perovskite compounds is ABX3, where 'A' and 'B' are two cations of very different sizes, and X is an anion that bonds to both. The 'A' atoms are larger than the 'B' atoms. The ideal cubic structure has the B cation in 6-fold coordination, surrounded by an octahedron of anions, and the A cation in 12-fold cuboctahedral coordination. The relative ion size requirements for stability of the cubic structure are quite stringent, so slight buckling and distortion can produce several lower-symmetry distorted versions, in which the coordination numbers of A cations, B cations or both are reduced.

In chemistry, titanate usually refers to inorganic compounds composed of titanium oxides. In some cases, the term is used more generally for any titanium-containing anion, e.g. [TiCl6]2− and [Ti(CO)7]2−. This article focuses on the oxides.

Strontium titanate chemical compound

Strontium titanate is an oxide of strontium and titanium with the chemical formula SrTiO3. At room temperature, it is a centrosymmetric paraelectric material with a perovskite structure. At low temperatures it approaches a ferroelectric phase transition with a very large dielectric constant ~104 but remains paraelectric down to the lowest temperatures measured as a result of quantum fluctuations, making it a quantum paraelectric. It was long thought to be a wholly artificial material, until 1982 when its natural counterpart—discovered in Siberia and named tausonite—was recognised by the IMA. Tausonite remains an extremely rare mineral in nature, occurring as very tiny crystals. Its most important application has been in its synthesized form wherein it is occasionally encountered as a diamond simulant, in precision optics, in varistors, and in advanced ceramics.

Carbonatite Igneous rock with more than 50% carbonate minerals

Carbonatite is a type of intrusive or extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geochemical verification.

Tausonite perovskite, oxide mineral

Tausonite is the rare naturally occurring mineral form of strontium titanate: chemical formula: SrTiO3. It occurs as red to orange brown cubic crystals and crystal masses.

Celsian feldspar, mineral

Celsian is an uncommon feldspar mineral, barium aluminosilicate, BaAl2Si2O8. The mineral occurs in contact metamorphic rocks with significant barium content. Its crystal system is monoclinic, and it is white, yellow, or transparent in appearance. In pure form, it is transparent. Synthetic barium aluminosilicate is used as a ceramic in dental fillings and other applications.

Barium titanate chemical compound

Barium titanate is an inorganic compound with chemical formula BaTiO3. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a ferroelectric ceramic material that exhibits the photorefractive effect and piezoelectric properties. It is used in capacitors, electromechanical transducers and nonlinear optics.

Nyerereite is a very rare sodium calcium carbonate mineral with formula Na2Ca(CO3)2. It forms colorless, platey pseudohexagonal orthorhombic crystals that are typically twinned. It has a specific gravity of 2.54 and indices of refraction of nα=1.511, nβ=1.533 and nγ=1.535. Nyerereite is not stable in contact with the atmosphere and rapidly breaks down. Collection specimens must be kept in a sealed argon environment.

Baotite cyclosilicate mineral

Baotite Ba4Ti4(Ti, Nb, Fe)4(Si4O12)O16Cl is a rare mineral recognized as having a unique four-fold silicate ring. Crystals are tetragonal, though commonly deformed to the extent of appearing monoclinic. Named for the locality of first discovery, Baotou, China, baotite has been found in hydrothermal veins and alkalic rocks in various locations around the world.

Geikielite oxide mineral

Geikielite is a magnesium titanium oxide mineral with formula: MgTiO3. It is a member of the ilmenite group. It crystallizes in the trigonal system forming typically opaque, black to reddish black crystals.

Silicate perovskite is either (Mg,Fe)SiO3 (the magnesian end-member is called bridgmanite) or CaSiO3 (calcium silicate) when arranged in a perovskite structure. Silicate perovskites are not stable at Earth's surface, and are mainly found in the lower part of Earth's mantle, between about 670 and 2,700 km (420 and 1,680 mi) depth. They are thought to form the main mineral phases, together with ferropericlase.

Helen Megaw Irish X-ray crystallographer, Cambridge University and Cavendish Laboratory

Helen Dick Megaw was an Irish crystallographer who was a pioneer in X-ray crystallography. She made measurements of the cell dimensions of ice and established the Perovskite crystal structure.

Anzaite-(Ce) is a rare-earth element (REE) oxide mineral with the formula Ce4Fe2+Ti6O18(OH)2. An example of chemically related mineral is lucasite-(Ce), although it contains no iron. Cerium in anzaite-(Ce) is mainly substituted by neodymium, lanthanum, calcium and praseodymium. Titanium is substituted by niobium. Trace elements include thorium. The mineral is monoclinic, space group C2/m. Anzaite-(Ce) is hydrothermal mineral found in a carbonatite from the mineralogically-prolific Kola Peninsula. The mineral name honors Anatoly N. Zaitsev, who is known for studies of carbonatites and REE.

Jinshajiangite is a rare silicate mineral named after the Jinshajiang river in China. Its currently accepted formula is BaNaFe4Ti2(Si2O7)2O2(OH)2F. It gives a name of the jinshajiangite group. The mineral is associated with alkaline rocks. In jinshajiangite, there is a potassium-to-barium, calcium-to-sodium, manganese-to-iron and iron-to-titanium diadochy substitution. Jinshajiangite is the iron-analogue of surkhobite and perraultite. It is chemically related to bafertisite, cámaraite and emmerichite. Its structure is related to that of bafertisite. Jinshajiangite is a titanosilicate with heteropolyhedral HOH layers, where the H-layer is a mixed tetrahedral-octahedral layer, and the O-layer is simply octahedral.

References

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