Pyrochlore2Nb2O6(OH,F) is a mineral group of the niobium end member of the pyrochlore supergroup. The general formula, A2B2O7, represent a family of phases isostructural to the mineral pyrochlore. Pyrochlores are an important class of materials in diverse technological applications such as luminescence, ionic conductivity, nuclear waste immobilization, high temperature thermal barrier coatings, automobile exhaust gas control, catalysts, solid oxide fuel cell, ionic/electrical conductors etc.
Euxenite, or euxenite-(Y), is a brownish black mineral with a metallic luster.
Samarskite is a radioactive rare earth mineral series which includes samarskite-(Y), with the chemical formula (YFe3+Fe2+U,Th,Ca)2(Nb,Ta)2O8 and samarskite-(Yb), with the chemical formula (YbFe3+)2(Nb,Ta)2O8. The formula for samarskite-(Y) is also given as (Y,Fe3+,U)(Nb,Ta)O4.
The mineral group tantalite [(Fe, Mn)Ta2O6] is the primary source of the chemical element tantalum, a corrosion (heat and acid) resistant metal. It is chemically similar to columbite, and the two are often grouped together as a semi-singular mineral called coltan or "columbite-tantalite" in many mineral guides. However, tantalite has a much greater specific gravity than columbite (8.0+ compared to columbite's 5.2). Iron-rich tantalite is the mineral tantalite-(Fe) or ferrotantalite and manganese-rich is tantalite-(Mn) or manganotantalite.
Tusionite is a rare colorless to transparent to translucent yellow brown trigonal borate mineral with chemical formula: MnSn(BO3)2. The mineral is composed of 18.86% manganese, 40.76% tin, 7.42% boron, and 32.96% oxygen. It is a late stage hydrothermal mineral and occurs rarely in granite pegmatites in miarolitic cavities.
Polycrase or polycrase-(Y) is a black or brown metallic complex uranium yttrium oxide mineral with the chemical formula (Y,Ca,Ce,U,Th)(Ti,Nb,Ta)2O6. It is amorphous. It has a Mohs hardness of 5 to 6 and a specific gravity of 5. It is radioactive due to its uranium content. It occurs in granitic pegmatites.
Zimbabweite is a mineral; formula (Na,K)2PbAs4(Nb,Ta,Ti)4O18. It is generally classed as an arsenite but is notable for also containing niobium and tantalum. A yellow brown mineral with orthorhombic crystal habit and a hardness of 5. It was discovered in 1986 in kaolinized pegmatite, i.e. weathered to clay, in Zimbabwe.
Microlite was once known as a pale-yellow, reddish-brown, or black isometric mineral composed of sodium calcium tantalum oxide with a small amount of fluorine. Its chemical formula is(Na,Ca)2Ta2O6(O,OH,F). Today it is a name of a group of oxide minerals of a similar stoichiometry having tantalum prevailing over titanium and niobium. The microlite group belongs to a large pyrochlore supergroup that occurs in pegmatites and constitutes an ore of tantalum. It has a Mohs hardness of 5.5 and a variable specific gravity of 4.2 to 6.4. It occurs as disseminated microscopic subtranslucent to opaque octahedral crystals with a refractive index of 2.0 to 2.2. Microlite is also called djalmaite, but both names are now obsolete.
Fluor-liddicoatite is a rare member of the tourmaline group of minerals, elbaite subgroup, and the theoretical calcium endmember of the elbaite-fluor-liddicoatite series; the pure end-member has not yet been found in nature. Fluor-liddicoatite is indistinguishable from elbaite by X-ray diffraction techniques. It forms a series with elbaite and probably also with olenite. Liddiocoatite is currently a non-approved mineral name, but Aurisicchio et al. (1999) and Breaks et al. (2008) found OH-dominant species. Formulae are
Hambergite (Be2BO3OH) is a beryllium borate mineral named after Swedish explorer and mineralogist Axel Hamberg (1863–1933). The mineral occurs as white or colorless orthorhombic crystals.
Ixiolite is an accessory oxide mineral found in granitic pegmatites. It is an oxide with the general chemical formula (Ta,Nb,Sn,Mn,Fe)4O8 or (Ta,Mn,Nb)O2.
Billwiseite is a very rare oxide mineral found at the pegmatite commonly referred to as "Stak Nala" located within a few hundred yards from the village of Toghla in the Stak Nala, Gilgit-Baltistan Pakistan. It has only been found as a coating on a single crystal of lepidolite. The sole rock containing Billwiseite is kept at the Royal Ontario Museum, catalogue number M5595.
Kentbrooksite is a moderately rare mineral of the eudialyte group, with chemical formula (Na,REE)15(Ca,REE)6Mn3Zr3NbSi[(Si9O27)2(Si3O9)2O2]F2·2H2O. This extended formula shows the presence of cyclic silicate groups and dominance of Si at the M4 site, according to the nomenclature of the eudialyte group. The characteristic features of kentbrooksite, that make it different from eudialyte are: (1) dominancy of fluorine (the only currently known example among the whole group), (2) dominancy of manganese, and (3) dominancy of niobium. Trace hafnium and magnesium are also reported. Kentbrooksite is relatively common when compared to most other species of the group.
Mogovidite is a very rare mineral of the eudialyte group, with formula Na9(Ca,Na)6Ca6(Fe3+,Fe2+)2Zr3[]Si(Si9O27)2(Si3O9)2(CO3)(OH,H2O)4. The formula given is based on the original one but extended to show the presence of cyclic silicate groups. It is similar to feklichevite, differing from it in the presence of essential vacancies and carbonate group. Another specific feature is the dominance of ferric iron - a feature shared with other eudialyte-group members, including feklichevite, fengchengite, golyshevite and ikranite. Similarly to golyshevite, it is calcium-dominant, however on three sites: M(1), N(3) and N(4). It has a molecular mass of 3,066.24 gm.
Béhierite is a very rare mineral, a natural tantalum borate of the formula (Ta,Nb)BO4. Béhierite is also one of the most simple tantalum minerals. It contains simple tetrahedral borate anions, instead of more common among minerals, planar BO3 groups. It forms a solid solution with its niobium-analogue, schiavinatoite. Both have zircon-type structure (tetragonal, space group I41/amd) and are found in pegmatites. Béhierite and holtite are minerals with essential tantalum and boron.
Nioboholtite is an extremely rare mineral with the formula (Nb0.6[]0.4)Al6BSi3O18. It is the niobium-rich member of the dumortierite supergroup, and the niobium analogue of holtite of the holtite group. It is one of three quite recently found minerals of this group, the other two being titanoholtite and szklaryite, all coming from the Szklary village near Ząbkowice Śląskie in Poland. They occur in a unique pegmatite. Nioboholtite and schiavinatoite are both minerals with essential niobium and boron.
Titanoholtite is an extremely rare mineral with the formula (Ti0.75[]0.25)Al6BSi3O18. It is titanium-rich member of dumortierite supergroup, and titanium-analogue of holtite of the holtite group. It is one of three quite recently found minerals of this group, the other two being nioboholtite and szklaryite, all coming from the Szklary village near Ząbkowice Śląskie in Poland. They occur in a unique pegmatite of probable anatectic origin.
Peterandresenite is a very rare mineral, the first known natural hexaniobate. Its chemical formula is Mn4Nb6O19•14H2O. Its structure contains a special type of octahedron: Lindqvist ion. Peterandresenite was found in a pegmatite of the Larvik complex in Norway. It is somewhat similar to other unique niobium minerals, aspedamite and menezesite.
Ekplexite is a unique sulfide-hydroxide niobium-rich mineral with the formula (Nb,Mo)S2•(Mg1-xAlx)(OH)2+x. It is unique because niobium is usually found in oxide or, eventually, silicate minerals. Ekplexite is a case in which chalcophile behaviour of niobium is shown, which means niobium present in a sulfide mineral. The unique combination of elements in ekplexite has to do with its name, which comes from a Greek world on "surprise". The other example of chalcophile behaviour of niobium is edgarite, FeNb3S6, and both minerals were found in the same environment, which is a fenitic rock of Mt. Kaskasnyunchorr, Khibiny Massif, Kola Peninsula, Russia. Analysis of the same rock has revealed the presence of two analogues of ekplexite, kaskasite (molybdenum-analogue) and manganokaskasite (molybdenum- and manganese-analogue). All three minerals belong to the valleriite group, and crystallize in the trigonal system with similar possible space groups.
Vigezzite is a variant of the mineral aeschynite containing calcium, cerium, niobium, tantalum, and titanium. It was first discovered near Orcesco, Valle Vigezzo, Provo Novara, Northern Italy, in cavities of an albitic rock. The crystals of Vigezzite are flat prismatic crystals up to 2-3 mm length of an orange-yellow color.The name Vigezzite was chosen to draw attention to the locality that has produced the first occurrence of a Ca-Nb-Ta-mineral with Nb dominance over Ta, crystallizing with the aeschynite structure. The ideal chemical formula for vigezzite is (Ca,Ce),(Nb,Ta,Ti)2O6
