Spinel

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Spinel
Calcite-Spinel-dtn37a.jpg
Small spinel crystal on top of a white calcite from Mogok, Myanmar, measuring 1.5 × 1.1 × 1 cm in size
General
Category
Formula
(repeating unit)
MgAl
2
O
4
IMA symbol Spl [1]
Strunz classification 4.BB.05
Crystal system Cubic
Crystal class Hextetrahedral (43m)
H–M symbol: (43m) [2] [3] [4]
Space group F4 3 m (No. 216)
Unit cell a = 8.0898(9) Å; Z = 8
Identification
ColorVarious; red, pink, blue, lavender/violet, dark green, brown, black, colourless
Crystal habit Octahedral or flat triangular plates caused by twinning
Twinning common
Cleavage None
Fracture Conchoidal
Mohs scale hardness7.5–8.0
Luster Vitreous
Streak White
Diaphaneity Transparent to opaque
Specific gravity (Depending on the composition) The rare Zn-rich spinel can be as high as 4.40, otherwise it averages from 3.58 to 3.61.
Optical propertiesIsotropic
Refractive index 1.719
Pleochroism Absent
Solubility None
Other characteristicsWeak to medium magnetic, sometimes fluorescent (red synthetic yes, natural red sometimes)
References [5] [6]
Polyhedral representation of spinel MgAl2O4 MgAl2O4.png
Polyhedral representation of spinel MgAl2O4

Spinel ( /spɪˈnɛl,ˈspɪnəl/ [7] ) is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl
2
O
4
in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals. [5]

Contents

Properties

Cut spinel Spinelgem.JPG
Cut spinel

Spinel crystallizes in the isometric system; common crystal forms are octahedra, usually twinned. It has no true cleavage, but shows an octahedral parting and a conchoidal fracture. [8] Its hardness is 8, its specific gravity is 3.5–4.1, and it is transparent to opaque with a vitreous to dull luster. It may be colorless, but is usually various shades of red, lavender, blue, green, brown, black, or yellow. [9] Chromium(III) causes the red color in spinel from Burma. [10] Some spinels are among the most famous gemstones; among them are the Black Prince's Ruby and the "Timur ruby" in the British Crown Jewels, [11] and the "Côte de Bretagne", formerly from the French Crown jewels. [12] The Samarian Spinel is the largest known spinel in the world, weighing 500 carats (100 g). [13]

The transparent red spinels were called spinel-rubies [14] or balas rubies. [15] In the past, before the arrival of modern science, spinels and rubies were equally known as rubies. After the 18th century, the word ruby was only used for the red gem variety of the mineral corundum, and the word spinel came to be used. [16] "Balas" is derived from Balascia, the ancient name for Badakhshan, a region in central Asia situated in the upper valley of the Panj River, one of the principal tributaries of the Oxus River. However, "Balascia" itself may be derived from Sanskrit bālasūryaka, which translates as "crimson-coloured morning sun". [17] Mines in the Gorno Badakhshan region of Tajikistan constituted for centuries the main source for red and pink spinels. [16]

Occurrence

Geologic occurrence

Spinel is found as a metamorphic mineral in metamorphosed limestones and silica-poor mudstones. [9] It also occurs as a primary mineral in rare mafic igneous rocks; in these igneous rocks, the magmas are relatively deficient in alkalis relative to aluminium, and aluminium oxide may form as the mineral corundum or may combine with magnesia to form spinel. This is why spinel and ruby are often found together. The spinel petrogenesis in mafic magmatic rocks is strongly debated, but certainly results from mafic magma interaction with more evolved magma [18] or rock (e.g. gabbro, troctolite). [19] [20]

Spinel, (Mg,Fe)(Al,Cr)2O4, is common in peridotite in the uppermost Earth's mantle, between approximately 20 km to approximately 120 km, possibly to lower depths depending on the chromium content. [21] At significantly shallower depths, above the Moho, calcic plagioclase is the more stable aluminous mineral in peridotite while garnet is the stable phase deeper in the mantle below the spinel stability region. [22]

Spinel, (Mg,Fe)Al2O4, is a common mineral in the Ca-Al-rich inclusions (CAIs) in some chondritic meteorites. [23]

Geographical occurrence

Spinel has long been found in the gemstone-bearing gravel of Sri Lanka and in limestones of the Badakshan Province in modern-day Afghanistan and Tajikistan; and of Mogok in Myanmar. Over the last decades gem quality spinels are found in the marbles of Lục Yên District (Vietnam), Mahenge and Matombo (Tanzania), Tsavo (Kenya) and in the gravels of Tunduru (Tanzania) and Ilakaka (Madagascar). [16] [24]

Since 2000, in several locations around the world, spinels have been discovered with unusual vivid pink or blue colors. Such "glowing" spinels are known from Mogok (Myanmar), [25] Mahenge plateau (Tanzania), Lục Yên District (Vietnam) [26] and some more localities. In 2018 bright blue spinels have been reported also in the southern part of Baffin Island (Canada). [27] The pure blue coloration of spinel is caused by small additions of cobalt. [28]

Synthetic spinel

Synthetic spinel can be produced by similar means to synthetic corundum, including the Verneuil method and the flux method pioneered by Edmond Frémy. It is widely used as an inexpensive cut gem in birthstone jewelry for the month of August. Light blue synthetic spinel is a good imitation of aquamarine beryl, and green synthetic spinel is used as an emerald or tourmaline simulant. [29] By 2015, transparent spinel was being made in sheets and other shapes through sintering. [30] Synthetic spinel, which looks like glass but has notably higher strength against pressure, can also have applications in military and commercial use. [31]

See also

Related Research Articles

<span class="mw-page-title-main">Corundum</span> Oxide mineral

Corundum is a crystalline form of aluminium oxide typically containing traces of iron, titanium, vanadium, and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. Corundum has two primary gem varieties: ruby and sapphire. Rubies are red due to the presence of chromium, and sapphires exhibit a range of colors depending on what transition metal is present. A rare type of sapphire, padparadscha sapphire, is pink-orange.

<span class="mw-page-title-main">Gemstone</span> Piece of mineral crystal used to make jewelry

A gemstone is a piece of mineral crystal which, when cut or polished, is used to make jewelry or other adornments. Certain rocks and occasionally organic materials that are not minerals may also be used for jewelry and are therefore often considered to be gemstones as well. Most gemstones are hard, but some softer minerals such as brazilianite may be used in jewelry because of their color or luster or other physical properties that have aesthetic value. However, generally speaking, soft minerals are not typically used as gemstones by virtue of their brittleness and lack of durability.

<span class="mw-page-title-main">Gabbro</span> Coarse-grained mafic intrusive rock

Gabbro is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is chemically equivalent to rapid-cooling, fine-grained basalt. Much of the Earth's oceanic crust is made of gabbro, formed at mid-ocean ridges. Gabbro is also found as plutons associated with continental volcanism. Due to its variant nature, the term gabbro may be applied loosely to a wide range of intrusive rocks, many of which are merely "gabbroic". By rough analogy, gabbro is to basalt as granite is to rhyolite.

<span class="mw-page-title-main">Sapphire</span> Gem variety of corundum

Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide (α-Al2O3) with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon. The name sapphire is derived from the Latin word sapphirus, itself from the Greek word sappheiros (σάπφειρος), which referred to lapis lazuli. It is typically blue, but natural "fancy" sapphires also occur in yellow, purple, orange, and green colors; "parti sapphires" show two or more colors. Red corundum stones also occur, but are called rubies rather than sapphires. Pink-colored corundum may be classified either as ruby or sapphire depending on locale. Commonly, natural sapphires are cut and polished into gemstones and worn in jewelry. They also may be created synthetically in laboratories for industrial or decorative purposes in large crystal boules. Because of the remarkable hardness of sapphires – 9 on the Mohs scale (the third hardest mineral, after diamond at 10 and moissanite at 9.5) – sapphires are also used in some non-ornamental applications, such as infrared optical components, high-durability windows, wristwatch crystals and movement bearings, and very thin electronic wafers, which are used as the insulating substrates of special-purpose solid-state electronics such as integrated circuits and GaN-based blue LEDs. Sapphire is the birthstone for September and the gem of the 45th anniversary. A sapphire jubilee occurs after 65 years.

<span class="mw-page-title-main">Garnet</span> Mineral, semi-precious stone

Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.

<span class="mw-page-title-main">Ruby</span> Variety of corundum, mineral, gemstone

A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum. Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sapphires. Ruby is one of the traditional cardinal gems, alongside amethyst, sapphire, emerald, and diamond. The word ruby comes from ruber, Latin for red. The color of a ruby is due to the element chromium.

<span class="mw-page-title-main">Chrysoberyl</span> Mineral or gemstone of beryllium aluminate

The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula BeAl2O4. The name chrysoberyl is derived from the Greek words χρυσός chrysos and βήρυλλος beryllos, meaning "a gold-white spar". Despite the similarity of their names, chrysoberyl and beryl are two completely different gemstones, although they both contain beryllium. Chrysoberyl is the third-hardest frequently encountered natural gemstone and lies at 8.5 on the Mohs scale of mineral hardness, between corundum (9) and topaz (8).

Lustre or luster is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the Latin lux, meaning "light", and generally implies radiance, gloss, or brilliance.

<span class="mw-page-title-main">Gemology</span> Science dealing with natural and artificial gemstone materials

Gemology or gemmology is the science dealing with natural and artificial gemstone materials. It is a geoscience and a branch of mineralogy. Some jewelers are academically trained gemologists and are qualified to identify and evaluate gems.

<span class="mw-page-title-main">Kimberlite</span> Igneous rock which sometimes contains diamonds

Kimberlite, an igneous rock and a rare variant of peridotite, is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an 83.5-carat diamond called the Star of South Africa in 1869 spawned a diamond rush and led to the excavation of the open-pit mine called the Big Hole. Previously, the term kimberlite has been applied to olivine lamproites as Kimberlite II, however this has been in error.

<span class="mw-page-title-main">Phonolite</span> Uncommon extrusive rock

Phonolite is an uncommon shallow intrusive or extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous rock trachyte that contains nepheline or leucite rather than quartz. It has an unusually high (12% or more) Na2O + K2O content, defining its position in the TAS classification of igneous rocks. Its coarse grained (phaneritic) intrusive equivalent is nepheline syenite. Phonolite is typically fine grained and compact. The name phonolite comes from the Ancient Greek meaning "sounding stone" due to the metallic sound it produces if an unfractured plate is hit; hence, the English name clinkstone is given as a synonym.

<span class="mw-page-title-main">Chromite</span> Crystalline mineral

Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging to the spinel group. The element magnesium can substitute for iron in variable amounts as it forms a solid solution with magnesiochromite (MgCr2O4). A substitution of the element aluminium can also occur, leading to hercynite (FeAl2O4). Chromite today is mined particularly to make stainless steel through the production of ferrochrome (FeCr), which is an iron-chromium alloy.

<span class="mw-page-title-main">Peridotite</span> Coarse-grained ultramafic igneous rock type

Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.

<span class="mw-page-title-main">Cordierite</span> Mg, Fe, Al cyclosilicate mineral

Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present, and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18). A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings. Cordierite is also synthesized and used in high temperature applications such as catalytic converters and pizza stones.

<span class="mw-page-title-main">Sapphirine</span> Rare mineral, a silicate of magnesium and aluminium

Sapphirine is a rare mineral, a silicate of magnesium and aluminium, with the chemical formula 8(Al,Si)6O20. Named for its sapphire-like colour, sapphirine is primarily of interest to researchers and collectors: well-formed crystals are treasured and occasionally cut into gemstones. Sapphirine has also been synthesized for experimental purposes via a hydrothermal process.

<span class="mw-page-title-main">Lamprophyre</span> Ultrapotassic igneous rocks

Lamprophyres are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.

<span class="mw-page-title-main">Painite</span> Borate mineral

Painite is a very rare borate mineral. It was first found in Myanmar by British mineralogist and gem dealer Arthur C.D. Pain who misidentified it as ruby, until it was discovered as a new gemstone in the 1950s. When it was confirmed as a new mineral species, the mineral was named after him. Due to its rarity, painite can cost between US$50,000 to $60,000 per carat.

<span class="mw-page-title-main">Komatiite</span> Magnesium-rich igneous rock

Komatiite is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% magnesium oxide (MgO). It is classified as a 'picritic rock'. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite was named for its type locality along the Komati River in South Africa, and frequently displays "spinifex" texture composed of large dendritic plates of olivine and pyroxene.

<span class="mw-page-title-main">Cumulate rock</span> Igneous rocks formed by the accumulation of crystals from a magma either by settling or floating.

Cumulate rocks are igneous rocks formed by the accumulation of crystals from a magma either by settling or floating. Cumulate rocks are named according to their texture; cumulate texture is diagnostic of the conditions of formation of this group of igneous rocks. Cumulates can be deposited on top of other older cumulates of different composition and colour, typically giving the cumulate rock a layered or banded appearance.

<span class="mw-page-title-main">Igneous intrusion</span> Body of intrusive igneous rocks

In geology, an igneous intrusion is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and compositions, illustrated by examples like the Palisades Sill of New York and New Jersey; the Henry Mountains of Utah; the Bushveld Igneous Complex of South Africa; Shiprock in New Mexico; the Ardnamurchan intrusion in Scotland; and the Sierra Nevada Batholith of California.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Robert John Lancashire. "Normal Spinels". CHEM2101 (C 21J) Inorganic Chemistry – Chemistry of Transition Metal Complexes. University of the West Indies. Archived from the original on 2018-08-08.
  3. N. W. Grimes; et al. (Apr 8, 1983). "New Symmetry and Structure for Spinel". Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences. 386 (1791): 333–345. Bibcode:1983RSPSA.386..333G. doi:10.1098/rspa.1983.0039. JSTOR   2397417. S2CID   96560029.
  4. L. Hwang; et al. (Jul 1973). "On the space group of MgAl
    2
    O
    4
    spinel"
    . Philosophical Magazine . doi:10.1080/14786437308217448.
  5. 1 2 Spinel, Mindat.org
  6. Spinel Mineral Data, WebMineral.com
  7. "spinel". The Chambers Dictionary (9th ed.). Chambers. 2003. ISBN   0-550-10105-5.
  8. Nesse, William D. (2000). Introduction to mineralogy. New York: Oxford University Press. pp. 362–363. ISBN   9780195106916.
  9. 1 2 Klein, Cornelis; Hurlbut, Cornelius S. Jr. (1993). Manual of mineralogy : (after James D. Dana) (21st ed.). New York: Wiley. ISBN   047157452X.
  10. "Minerals Colored by Metal Ions". minerals.gps.caltech.edu. Retrieved 2023-03-01.
  11. Sir Thomas Butler (1989). The Crown Jewels and Coronation Ceremony. Pitkin. p. 6. ISBN   978-0-85372-467-4.
  12. Pardieu, V.; Farkhodova, T. (Summer 2019). "Spinel from Tajikistan". InColor: 30–33. Retrieved 28 April 2021.
  13. "Samarian spinel". Dictionary of Gems and Gemology: 657–737. 2005. doi:10.1007/3-540-27269-0_19.
  14. Lytvynov, L.A. (2011). "On the words used as names for ruby and sapphire" (PDF). Functional Materials. 18 (2): 275. Retrieved 29 April 2021.
  15. Hughes, R.W. (1994). "The rubies and spinels of Afghanistan: A brief history" (PDF). Journal of Gemmology. 24 (4): 256–267. doi:10.15506/JoG.1994.24.4.256 . Retrieved 29 April 2021.
  16. 1 2 3 Pardieu & Farkhodova 2019.
  17. Biswas, A.K. (2001). "Minerals and their Exploitation in Ancient and Pre-modern India". In Ramachandra Rao, P.; Goswami, N.G. (eds.). Metallurgy in India : a retrospective. New Delhi: India International Publisher. pp. 1–22. ASIN   B002A9M6QU.
  18. Irvine TN (1977). "Origin of chromite layers in the Muskox intrusion and other stratiform intrusions: a new perspective". Geology. 5 (5): 273. doi:10.1130/0091-7613(1977)5<273:ooclit>2.0.co;2.
  19. Leuthold J, Blundy JD, Brooker RA (2015). "Experimental petrology constraints on the recycling of mafic cumulate: A focus on Cr-spinel from the Rum Eastern Layered Intrusion, Scotland". Contributions to Mineralogy and Petrology. 170 (2): 12. Bibcode:2015CoMP..170...12L. doi:10.1007/s00410-015-1165-0. hdl: 1983/43578f76-07c8-4676-84d1-d763d5228efb . S2CID   129562202.
  20. O Driscoll B, Emeleus CH, Donaldson CH, Daly JS (2009). "The roles of melt infiltration and cumulate assimilation in the formation of anorthosite and a Cr-spinel seam in the Rum Eastern Layered Intrusion, NW Scotland". Lithos. 111 (1–2): 6–20. Bibcode:2009Litho.111....6O. doi:10.1016/j.lithos.2008.11.011.
  21. Klemme, Stephan (2004). "The influence of Cr on the garnet–spinel transition in the Earth's mantle: Experiments in the system MgO—Cr2O3—SiO2 and thermodynamic modelling" (PDF). Lithos. 77 (1–4): 639–646. Bibcode:2004Litho..77..639K. doi:10.1016/j.lithos.2004.03.017.
  22. Philpotts, Anthony R.; Ague, Jay J. (2009). Principles of igneous and metamorphic petrology (2nd ed.). Cambridge, UK: Cambridge University Press. p. 17. ISBN   9780521880060.
  23. MacPherson, G.J. (2007). "Calcium–Aluminum-Rich Inclusions in Chondritic Meteorites". Treatise on Geochemistry: 1–47. doi:10.1016/B0-08-043751-6/01065-3. ISBN   9780080437514.
  24. Pardieu, Vincent; Hughes, R. W.; Boehm, E. (2008). "Spinel: Resurrection of a classic". InColor Magazine: 10–18. Retrieved 29 April 2021.
  25. Pardieu, Vincent (2014). "Hunting for "Jedi" Spinels in Mogok". Gems & Gemology. 50 (1): 46–57. doi: 10.5741/GEMS.50.1.46 .
  26. Wondermondo (16 June 2019). "Finds of cobalt blue spinel in Lục Yên, Vietnam".
  27. Mining.Com (5 April 2019). "Scientists figure out origin of cobalt-blue spinel in Canada's Arctic".
  28. Boris Chauviré, Benjamin Rondeau, Emmanuel Fritsch, Phillipe Ressigeac, and Jean-Luc Devidal (Spring 2015). "Blue Spinel From the Luc Yen District of Vietnam". Gems & Gemology.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  29. Simon & Schuster's Guide to Gems and Precious Stones, K. Lyman, 1996
  30. "Researchers finding applications for tough spinel ceramic". Phys.org. 24 April 2015.
  31. "Transparent Armor from NRL; Spinel Could Also Ruggedize Your Smart Phone". Naval Research Laboratory. 23 April 2015. Archived from the original on 4 August 2023. Retrieved 4 August 2023.

Bibliography