Wave–particle duality

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Wave–particle duality is the concept in quantum mechanics that every particle or quantum entity may be described as either a particle or a wave. It expresses the inability of the classical concepts "particle" or "wave" to fully describe the behaviour of quantum-scale objects. As Albert Einstein wrote: [1]

Quantum mechanics Branch of physics that acts as an abstract framework formulating all the laws of nature

Quantum mechanics, including quantum field theory, is a fundamental theory in physics which describes nature at the smallest scales of atoms and subatomic particles.

Particle small localized object in physical sciences

In the physical sciences, a particle is a small localized object to which can be ascribed several physical or chemical properties such as volume, density or mass. They vary greatly in size or quantity, from subatomic particles like the electron, to microscopic particles like atoms and molecules, to macroscopic particles like powders and other granular materials. Particles can also be used to create scientific models of even larger objects depending on their density, such as humans moving in a crowd or celestial bodies in motion.

Wave oscillation that travels through space and matter

In physics, mathematics, and related fields, a wave is a disturbance of one or more fields such that the field values oscillate repeatedly about a stable equilibrium (resting) value. If the relative amplitude of oscillation at different points in the field remains constant, the wave is said to be a standing wave. If the relative amplitude at different points in the field changes, the wave is said to be a traveling wave. Waves can only exist in fields when there is a force that tends to restore the field to equilibrium.

Contents

It seems as though we must use sometimes the one theory and sometimes the other, while at times we may use either. We are faced with a new kind of difficulty. We have two contradictory pictures of reality; separately neither of them fully explains the phenomena of light, but together they do.

Through the work of Max Planck, Albert Einstein, Louis de Broglie, Arthur Compton, Niels Bohr, and many others, current scientific theory holds that all particles exhibit a wave nature and vice versa. [2] This phenomenon has been verified not only for elementary particles, but also for compound particles like atoms and even molecules. For macroscopic particles, because of their extremely short wavelengths, wave properties usually cannot be detected. [3]

Max Planck German theoretical physicist

Max Karl Ernst Ludwig Planck, ForMemRS was a German theoretical physicist whose discovery of energy quanta won him the Nobel Prize in Physics in 1918.

Albert Einstein German-born physicist and developer of the theory of relativity

Albert Einstein was a German-born theoretical physicist who developed the theory of relativity, one of the two pillars of modern physics. His work is also known for its influence on the philosophy of science. He is best known to the general public for his mass–energy equivalence formula , which has been dubbed "the world's most famous equation". He received the 1921 Nobel Prize in Physics "for his services to theoretical physics, and especially for his discovery of the law of the photoelectric effect", a pivotal step in the development of quantum theory.

Louis de Broglie French physicist

Louis Victor Pierre Raymond de Broglie, 7th duc de Broglie was a French physicist who made groundbreaking contributions to quantum theory. In his 1924 PhD thesis, he postulated the wave nature of electrons and suggested that all matter has wave properties. This concept is known as the de Broglie hypothesis, an example of wave–particle duality, and forms a central part of the theory of quantum mechanics.

Although the use of the wave-particle duality has worked well in physics, the meaning or interpretation has not been satisfactorily resolved; see Interpretations of quantum mechanics.

An interpretation of quantum mechanics is an attempt to explain how the mathematical theory of quantum mechanics "corresponds" to reality. Although quantum mechanics has held up to rigorous and extremely precise tests in an extraordinarily broad range of experiments, there exist a number of contending schools of thought over their interpretation. These views on interpretation differ on such fundamental questions as whether quantum mechanics is deterministic or random, which elements of quantum mechanics can be considered "real", and what is the nature of measurement, among other matters.

Bohr regarded the "duality paradox" as a fundamental or metaphysical fact of nature. A given kind of quantum object will exhibit sometimes wave, sometimes particle, character, in respectively different physical settings. He saw such duality as one aspect of the concept of complementarity. [4] Bohr regarded renunciation of the cause-effect relation, or complementarity, of the space-time picture, as essential to the quantum mechanical account. [5]

Paradox Statement that apparently contradicts itself

A paradox is a logical statement that seems to contradict itself. It is a statement that, despite apparently valid reasoning from true premises, leads to an apparently-self-contradictory or logically unacceptable conclusion. A paradox involves contradictory-yet-interrelated elements that exist simultaneously and persist over time.

In physics, complementarity is both a theoretical and an experimental result of quantum mechanics, also referred to as principle of complementarity. Formulated by Niels Bohr, a leading founder of quantum mechanics, the complementarity principle holds that objects have certain pairs of complementary properties which cannot all be observed or measured simultaneously.

Werner Heisenberg considered the question further. He saw the duality as present for all quantic entities, but not quite in the usual quantum mechanical account considered by Bohr. He saw it in what is called second quantization, which generates an entirely new concept of fields that exist in ordinary space-time, causality still being visualizable. Classical field values (e.g. the electric and magnetic field strengths of Maxwell) are replaced by an entirely new kind of field value, as considered in quantum field theory. Turning the reasoning around, ordinary quantum mechanics can be deduced as a specialized consequence of quantum field theory. [6] [7]

Werner Heisenberg German theoretical physicist

Werner Karl Heisenberg was a German theoretical physicist and one of the key pioneers of quantum mechanics. He published his work in 1925 in a breakthrough paper. In the subsequent series of papers with Max Born and Pascual Jordan, during the same year, this matrix formulation of quantum mechanics was substantially elaborated. He is known for the Heisenberg uncertainty principle, which he published in 1927. Heisenberg was awarded the 1932 Nobel Prize in Physics "for the creation of quantum mechanics".

Second quantization Formulation of the quantum many-body problem

Second quantization, also referred to as occupation number representation, is a formalism used to describe and analyze quantum many-body systems. In quantum field theory, it is known as canonical quantization, in which the fields are thought of as field operators, in a manner similar to how the physical quantities are thought of as operators in first quantization. The key ideas of this method were introduced in 1927 by Paul Dirac, and were developed, most notably, by Vladimir Fock and Pascual Jordan later.

James Clerk Maxwell Scottish physicist

James Clerk Maxwell was a Scottish scientist in the field of mathematical physics. His most notable achievement was to formulate the classical theory of electromagnetic radiation, bringing together for the first time electricity, magnetism, and light as different manifestations of the same phenomenon. Maxwell's equations for electromagnetism have been called the "second great unification in physics" after the first one realised by Isaac Newton.

History

Classical particle and wave theories of light

Thomas Young's sketch of two-slit diffraction of waves, 1803 Young Diffraction.png
Thomas Young's sketch of two-slit diffraction of waves, 1803

Democritus argued that all things in the universe, including light, are composed of indivisible sub-components. [8] At the beginning of the 11th century, the Arabic scientist Ibn al-Haytham wrote the first comprehensive Book of optics describing reflection, refraction, and the operation of a pinhole lens via rays of light traveling from the point of emission to the eye. He asserted that these rays were composed of particles of light. In 1630, René Descartes popularized and accredited the opposing wave description in his treatise on light, The World (Descartes) , showing that the behavior of light could be re-created by modeling wave-like disturbances in a universal medium i.e. luminiferous aether. Beginning in 1670 and progressing over three decades, Isaac Newton developed and championed his corpuscular theory, arguing that the perfectly straight lines of reflection demonstrated light's particle nature, only particles could travel in such straight lines. He explained refraction by positing that particles of light accelerated laterally upon entering a denser medium. Around the same time, Newton's contemporaries Robert Hooke and Christiaan Huygens, and later Augustin-Jean Fresnel, mathematically refined the wave viewpoint, showing that if light traveled at different speeds in different media, refraction could be easily explained as the medium-dependent propagation of light waves. The resulting Huygens–Fresnel principle was extremely successful at reproducing light's behavior and was subsequently supported by Thomas Young's discovery of wave interference of light by his double-slit experiment in 1801. [9] [10] The wave view did not immediately displace the ray and particle view, but began to dominate scientific thinking about light in the mid 19th century, since it could explain polarization phenomena that the alternatives could not. [11]

Democritus Ancient Greek philosopher, pupil of Leucippus, founder of the atomic theory

Democritus was an Ancient Greek pre-Socratic philosopher primarily remembered today for his formulation of an atomic theory of the universe.

Light electromagnetic radiation in or near visible spectrum

Light is electromagnetic radiation within a certain portion of the electromagnetic spectrum. The word usually refers to visible light, which is the portion of the spectrum that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometers (nm), or 4.00 × 10−7 to 7.00 × 10−7 m, between the infrared and the ultraviolet. This wavelength means a frequency range of roughly 430–750 terahertz (THz).

Ibn al-Haytham Arab physicist, mathematician and astronomer

Ḥasan Ibn al-Haytham was an Arab mathematician, astronomer, and physicist of the Islamic Golden Age. Also sometimes referred to as "the father of modern optics", he made significant contributions to the principles of optics and visual perception in particular, his most influential work being his Kitāb al-Manāẓir, written during 1011–1021, which survived in the Latin edition. A polymath, he also wrote on philosophy, theology and medicine.

James Clerk Maxwell discovered that he could apply his previously discovered Maxwell's equations, along with a slight modification to describe self-propagating waves of oscillating electric and magnetic fields. It quickly became apparent that visible light, ultraviolet light, and infrared light were all electromagnetic waves of differing frequency.

Black-body radiation and Planck's law

In 1901, Max Planck published an analysis that succeeded in reproducing the observed spectrum of light emitted by a glowing object. To accomplish this, Planck had to make a mathematical assumption of quantized energy of the oscillators i.e. atoms of the black body that emit radiation. Einstein later proposed that electromagnetic radiation itself is quantized, not the energy of radiating atoms.

Black-body radiation, the emission of electromagnetic energy due to an object's heat, could not be explained from classical arguments alone. The equipartition theorem of classical mechanics, the basis of all classical thermodynamic theories, stated that an object's energy is partitioned equally among the object's vibrational modes. But applying the same reasoning to the electromagnetic emission of such a thermal object was not so successful. That thermal objects emit light had been long known. Since light was known to be waves of electromagnetism, physicists hoped to describe this emission via classical laws. This became known as the black body problem. Since the equipartition theorem worked so well in describing the vibrational modes of the thermal object itself, it was natural to assume that it would perform equally well in describing the radiative emission of such objects. But a problem quickly arose if each mode received an equal partition of energy, the short wavelength modes would consume all the energy. This became clear when plotting the Rayleigh–Jeans law, which, while correctly predicting the intensity of long wavelength emissions, predicted infinite total energy as the intensity diverges to infinity for short wavelengths. This became known as the ultraviolet catastrophe.

In 1900, Max Planck hypothesized that the frequency of light emitted by the black body depended on the frequency of the oscillator that emitted it, and the energy of these oscillators increased linearly with frequency (according E = hf where h is Planck's constant and f is the frequency). This was not an unsound proposal considering that macroscopic oscillators operate similarly when studying five simple harmonic oscillators of equal amplitude but different frequency, the oscillator with the highest frequency possesses the highest energy (though this relationship is not linear like Planck's). By demanding that high-frequency light must be emitted by an oscillator of equal frequency, and further requiring that this oscillator occupy higher energy than one of a lesser frequency, Planck avoided any catastrophe, giving an equal partition to high-frequency oscillators produced successively fewer oscillators and less emitted light. And as in the Maxwell–Boltzmann distribution, the low-frequency, low-energy oscillators were suppressed by the onslaught of thermal jiggling from higher energy oscillators, which necessarily increased their energy and frequency.

The most revolutionary aspect of Planck's treatment of the black body is that it inherently relies on an integer number of oscillators in thermal equilibrium with the electromagnetic field. These oscillators give their entire energy to the electromagnetic field, creating a quantum of light, as often as they are excited by the electromagnetic field, absorbing a quantum of light and beginning to oscillate at the corresponding frequency. Planck had intentionally created an atomic theory of the black body, but had unintentionally generated an atomic theory of light, where the black body never generates quanta of light at a given frequency with an energy less than hf. However, once realizing that he had quantized the electromagnetic field, he denounced particles of light as a limitation of his approximation, not a property of reality.

Photoelectric effect

The photoelectric effect. Incoming photons on the left strike a metal plate (bottom), and eject electrons, depicted as flying off to the right. Photoelectric effect.svg
The photoelectric effect. Incoming photons on the left strike a metal plate (bottom), and eject electrons, depicted as flying off to the right.

While Planck had solved the ultraviolet catastrophe by using atoms and a quantized electromagnetic field, most contemporary physicists agreed that Planck's "light quanta" represented only flaws in his model. A more-complete derivation of black-body radiation would yield a fully continuous and "wave-like" electromagnetic field with no quantization. However, in 1905 Albert Einstein took Planck's black body model to produce his solution to another outstanding problem of the day: the photoelectric effect, wherein electrons are emitted from atoms when they absorb energy from light. Since their existence was theorized eight years previously, phenomena had been studied with the electron model in mind in physics laboratories worldwide.

In 1902 Philipp Lenard discovered that the energy of these ejected electrons did not depend on the intensity of the incoming light, but instead on its frequency. So if one shines a little low-frequency light upon a metal, a few low energy electrons are ejected. If one now shines a very intense beam of low-frequency light upon the same metal, a whole slew of electrons are ejected; however they possess the same low energy, there are merely more of them. The more light there is, the more electrons are ejected. Whereas in order to get high energy electrons, one must illuminate the metal with high-frequency light. Like blackbody radiation, this was at odds with a theory invoking continuous transfer of energy between radiation and matter. However, it can still be explained using a fully classical description of light, as long as matter is quantum mechanical in nature. [12]

If one used Planck's energy quanta, and demanded that electromagnetic radiation at a given frequency could only transfer energy to matter in integer multiples of an energy quantum hf, then the photoelectric effect could be explained very simply. Low-frequency light only ejects low-energy electrons because each electron is excited by the absorption of a single photon. Increasing the intensity of the low-frequency light (increasing the number of photons) only increases the number of excited electrons, not their energy, because the energy of each photon remains low. Only by increasing the frequency of the light, and thus increasing the energy of the photons, can one eject electrons with higher energy. Thus, using Planck's constant h to determine the energy of the photons based upon their frequency, the energy of ejected electrons should also increase linearly with frequency, the gradient of the line being Planck's constant. These results were not confirmed until 1915, when Robert Andrews Millikan produced experimental results in perfect accord with Einstein's predictions.

While energy of ejected electrons reflected Planck's constant, the existence of photons was not explicitly proven until the discovery of the photon antibunching effect, of which a modern experiment can be performed in undergraduate-level labs. [13] This phenomenon could only be explained via photons. Einstein's "light quanta" would not be called photons until 1925, but even in 1905 they represented the quintessential example of wave-particle duality. Electromagnetic radiation propagates following linear wave equations, but can only be emitted or absorbed as discrete elements, thus acting as a wave and a particle simultaneously.

Einstein's explanation of photoelectric effect

In 1905, Albert Einstein provided an explanation of the photoelectric effect, an experiment that the wave theory of light failed to explain. He did so by postulating the existence of photons, quanta of light energy with particulate qualities.

In the photoelectric effect, it was observed that shining a light on certain metals would lead to an electric current in a circuit. Presumably, the light was knocking electrons out of the metal, causing current to flow. However, using the case of potassium as an example, it was also observed that while a dim blue light was enough to cause a current, even the strongest, brightest red light available with the technology of the time caused no current at all. According to the classical theory of light and matter, the strength or amplitude of a light wave was in proportion to its brightness: a bright light should have been easily strong enough to create a large current. Yet, oddly, this was not so.

Einstein explained this enigma by postulating that the electrons can receive energy from electromagnetic field only in discrete units (quanta or photons): an amount of energy E that was related to the frequency f of the light by

where h is Planck's constant (6.626 × 10−34 Js). Only photons of a high enough frequency (above a certain threshold value) could knock an electron free. For example, photons of blue light had sufficient energy to free an electron from the metal, but photons of red light did not. One photon of light above the threshold frequency could release only one electron; the higher the frequency of a photon, the higher the kinetic energy of the emitted electron, but no amount of light below the threshold frequency could release an electron. To violate this law would require extremely high-intensity lasers that had not yet been invented. Intensity-dependent phenomena have now been studied in detail with such lasers. [14]

Einstein was awarded the Nobel Prize in Physics in 1921 for his discovery of the law of the photoelectric effect.

de Broglie's hypothesis

Propagation of de Broglie waves in 1d--real part of the complex amplitude is blue, imaginary part is green. The probability (shown as the colour opacity) of finding the particle at a given point x is spread out like a waveform; there is no definite position of the particle. As the amplitude increases above zero the curvature decreases, so the amplitude decreases again, and vice versa--the result is an alternating amplitude: a wave. Top: Plane wave. Bottom: Wave packet. Propagation of a de broglie wave.svg
Propagation of de Broglie waves in 1d—real part of the complex amplitude is blue, imaginary part is green. The probability (shown as the colour opacity) of finding the particle at a given point x is spread out like a waveform; there is no definite position of the particle. As the amplitude increases above zero the curvature decreases, so the amplitude decreases again, and vice versa—the result is an alternating amplitude: a wave. Top: Plane wave. Bottom: Wave packet.

In 1924, Louis-Victor de Broglie formulated the de Broglie hypothesis, claiming that all matter [15] [16] has a wave-like nature, he related wavelength and momentum:

This is a generalization of Einstein's equation above, since the momentum of a photon is given by p = and the wavelength (in a vacuum) by λ = , where c is the speed of light in vacuum.

De Broglie's formula was confirmed three years later for electrons with the observation of electron diffraction in two independent experiments. At the University of Aberdeen, George Paget Thomson passed a beam of electrons through a thin metal film and observed the predicted interference patterns. At Bell Labs, Clinton Joseph Davisson and Lester Halbert Germer guided the electron beam through a crystalline grid in their experiment popularly known as Davisson–Germer experiment.

De Broglie was awarded the Nobel Prize for Physics in 1929 for his hypothesis. Thomson and Davisson shared the Nobel Prize for Physics in 1937 for their experimental work.

Heisenberg's Uncertainty principle

In his work on formulating quantum mechanics, Werner Heisenberg postulated his uncertainty principle, which states:

where

here indicates standard deviation, a measure of spread or uncertainty;
x and p are a particle's position and linear momentum respectively.
is the reduced Planck's constant (Planck's constant divided by 2).

Heisenberg originally explained this as a consequence of the process of measuring: Measuring position accurately would disturb momentum and vice versa, offering an example (the "gamma-ray microscope") that depended crucially on the de Broglie hypothesis. The thought is now, however, that this only partly explains the phenomenon, but that the uncertainty also exists in the particle itself, even before the measurement is made.

In fact, the modern explanation of the uncertainty principle, extending the Copenhagen interpretation first put forward by Bohr and Heisenberg, depends even more centrally on the wave nature of a particle. Just as it is nonsensical to discuss the precise location of a wave on a string, particles do not have perfectly precise positions; likewise, just as it is nonsensical to discuss the wavelength of a "pulse" wave traveling down a string, particles do not have perfectly precise momenta that corresponds to the inverse of wavelength. Moreover, when position is relatively well defined, the wave is pulse-like and has a very ill-defined wavelength, and thus momentum. And conversely, when momentum, and thus wavelength, is relatively well defined, the wave looks long and sinusoidal, and therefore it has a very ill-defined position.

de Broglie–Bohm theory

Couder experiments, "materializing" the pilot wave model. ExperimentCouder-Young.png
Couder experiments, "materializing" the pilot wave model.

De Broglie himself had proposed a pilot wave construct to explain the observed wave-particle duality. In this view, each particle has a well-defined position and momentum, but is guided by a wave function derived from Schrödinger's equation. The pilot wave theory was initially rejected because it generated non-local effects when applied to systems involving more than one particle. Non-locality, however, soon became established as an integral feature of quantum theory and David Bohm extended de Broglie's model to explicitly include it.

In the resulting representation, also called the de Broglie–Bohm theory or Bohmian mechanics, [18] the wave-particle duality vanishes, and explains the wave behaviour as a scattering with wave appearance, because the particle's motion is subject to a guiding equation or quantum potential.

This idea seems to me so natural and simple, to resolve the wave–particle dilemma in such a clear and ordinary way, that it is a great mystery to me that it was so generally ignored. [19] J.S.Bell

The best illustration of the pilot-wave model was given by Couder's 2010 "walking droplets" experiments, [20] demonstrating the pilot-wave behaviour in a macroscopic mechanical analog. [17]

Wave nature of large objects

Since the demonstrations of wave-like properties in photons and electrons, similar experiments have been conducted with neutrons and protons. Among the most famous experiments are those of Estermann and Otto Stern in 1929. [21] Authors of similar recent experiments with atoms and molecules, described below, claim that these larger particles also act like waves.

A dramatic series of experiments emphasizing the action of gravity in relation to wave–particle duality was conducted in the 1970s using the neutron interferometer. [22] Neutrons, one of the components of the atomic nucleus, provide much of the mass of a nucleus and thus of ordinary matter. In the neutron interferometer, they act as quantum-mechanical waves directly subject to the force of gravity. While the results were not surprising since gravity was known to act on everything, including light (see tests of general relativity and the Pound–Rebka falling photon experiment), the self-interference of the quantum mechanical wave of a massive fermion in a gravitational field had never been experimentally confirmed before.

In 1999, the diffraction of C60 fullerenes by researchers from the University of Vienna was reported. [23] Fullerenes are comparatively large and massive objects, having an atomic mass of about 720 u. The de Broglie wavelength of the incident beam was about 2.5  pm, whereas the diameter of the molecule is about 1  nm, about 400 times larger. In 2012, these far-field diffraction experiments could be extended to phthalocyanine molecules and their heavier derivatives, which are composed of 58 and 114 atoms respectively. In these experiments the build-up of such interference patterns could be recorded in real time and with single molecule sensitivity. [24] [25]

In 2003, the Vienna group also demonstrated the wave nature of tetraphenylporphyrin [26] —a flat biodye with an extension of about 2 nm and a mass of 614 u. For this demonstration they employed a near-field Talbot Lau interferometer. [27] [28] In the same interferometer they also found interference fringes for C60F48., a fluorinated buckyball with a mass of about 1600 u, composed of 108 atoms. [26] Large molecules are already so complex that they give experimental access to some aspects of the quantum-classical interface, i.e., to certain decoherence mechanisms. [29] [30] In 2011, the interference of molecules as heavy as 6910 u could be demonstrated in a Kapitza–Dirac–Talbot–Lau interferometer. [31] In 2013, the interference of molecules beyond 10,000 u has been demonstrated. [32]

Whether objects heavier than the Planck mass (about the weight of a large bacterium) have a de Broglie wavelength is theoretically unclear and experimentally unreachable; above the Planck mass a particle's Compton wavelength would be smaller than the Planck length and its own Schwarzschild radius, a scale at which current theories of physics may break down or need to be replaced by more general ones. [33]

Recently Couder, Fort, et al. showed [34] that we can use macroscopic oil droplets on a vibrating surface as a model of wave–particle duality—localized droplet creates periodical waves around and interaction with them leads to quantum-like phenomena: interference in double-slit experiment, [35] unpredictable tunneling [36] (depending in complicated way on practically hidden state of field), orbit quantization [37] (that particle has to 'find a resonance' with field perturbations it creates—after one orbit, its internal phase has to return to the initial state) and Zeeman effect. [38]

Importance

Wave–particle duality is deeply embedded into the foundations of quantum mechanics. In the formalism of the theory, all the information about a particle is encoded in its wave function, a complex-valued function roughly analogous to the amplitude of a wave at each point in space. This function evolves according to Schrödinger equation. For particles with mass this equation has solutions that follow the form of the wave equation. Propagation of such waves leads to wave-like phenomena such as interference and diffraction. Particles without mass, like photons, have no solutions of the Schrödinger equation so have another wave.

The particle-like behaviour is most evident due to phenomena associated with measurement in quantum mechanics. Upon measuring the location of the particle, the particle will be forced into a more localized state as given by the uncertainty principle. When viewed through this formalism, the measurement of the wave function will randomly lead to wave function collapse to a sharply peaked function at some location. For particles with mass, the likelihood of detecting the particle at any particular location is equal to the squared amplitude of the wave function there. The measurement will return a well-defined position, and is subject to Heisenberg's uncertainty principle.

Following the development of quantum field theory the ambiguity disappeared. The field permits solutions that follow the wave equation, which are referred to as the wave functions. The term particle is used to label the irreducible representations of the Lorentz group that are permitted by the field. An interaction as in a Feynman diagram is accepted as a calculationally convenient approximation where the outgoing legs are known to be simplifications of the propagation and the internal lines are for some order in an expansion of the field interaction. Since the field is non-local and quantized, the phenomena that previously were thought of as paradoxes are explained. Within the limits of the wave-particle duality the quantum field theory gives the same results.

Visualization

There are two ways to visualize the wave-particle behaviour by the standard model and by the de Broglie–Bohr theory.

Below is an illustration of wave–particle duality as it relates to de Broglie's hypothesis and Heisenberg's Uncertainty principle, in terms of the position and momentum space wavefunctions for one spinless particle with mass in one dimension. These wavefunctions are Fourier transforms of each other.

The more localized the position-space wavefunction, the more likely the particle is to be found with the position coordinates in that region, and correspondingly the momentum-space wavefunction is less localized so the possible momentum components the particle could have are more widespread.

Conversely the more localized the momentum-space wavefunction, the more likely the particle is to be found with those values of momentum components in that region, and correspondingly the less localized the position-space wavefunction, so the position coordinates the particle could occupy are more widespread.

Position x and momentum p wavefunctions corresponding to quantum particles. The colour opacity of the particles corresponds to the probability density of finding the particle with position x or momentum component p.
Top: If wavelength l is unknown, so are momentum p, wave-vector k and energy E (de Broglie relations). As the particle is more localized in position space, Dx is smaller than for Dpx.
Bottom: If l is known, so are p, k, and E. As the particle is more localized in momentum space, Dp is smaller than for Dx. Quantum mechanics travelling wavefunctions wavelength.svg
Position x and momentum p wavefunctions corresponding to quantum particles. The colour opacity of the particles corresponds to the probability density of finding the particle with position x or momentum component p.
Top: If wavelength λ is unknown, so are momentum p, wave-vector k and energy E (de Broglie relations). As the particle is more localized in position space, Δx is smaller than for Δpx.
Bottom: If λ is known, so are p, k, and E. As the particle is more localized in momentum space, Δp is smaller than for Δx.

Alternative views

Wave–particle duality is an ongoing conundrum in modern physics. Most physicists accept wave-particle duality as the best explanation for a broad range of observed phenomena; however, it is not without controversy. Alternative views are also presented here. These views are not generally accepted by mainstream physics, but serve as a basis for valuable discussion within the community.

1. Both-particle-and-wave view

The pilot wave model, originally developed by Louis de Broglie and further developed by David Bohm into the hidden variable theory proposes that there is no duality, but rather a system exhibits both particle properties and wave properties simultaneously, and particles are guided, in a deterministic fashion, by the pilot wave (or its "quantum potential"), which will direct them to areas of constructive interference in preference to areas of destructive interference. This idea is held by a significant minority within the physics community. [39]

At least one physicist considers the "wave-duality" as not being an incomprehensible mystery. L.E. Ballentine, Quantum Mechanics, A Modern Development, p. 4, explains:

When first discovered, particle diffraction was a source of great puzzlement. Are "particles" really "waves?" In the early experiments, the diffraction patterns were detected holistically by means of a photographic plate, which could not detect individual particles. As a result, the notion grew that particle and wave properties were mutually incompatible, or complementary, in the sense that different measurement apparatuses would be required to observe them. That idea, however, was only an unfortunate generalization from a technological limitation. Today it is possible to detect the arrival of individual electrons, and to see the diffraction pattern emerge as a statistical pattern made up of many small spots (Tonomura et al., 1989). Evidently, quantum particles are indeed particles, but whose behaviour is very different from classical physics would have us to expect.

The Afshar experiment [40] (2007) may suggest that it is possible to simultaneously observe both wave and particle properties of photons. This claim is, however, disputed by other scientists. [41] [42] [43] [44]

2. Wave-only view

Carver Mead, an American scientist and professor at Caltech, proposes that the duality can be replaced by a "wave-only" view. In his book Collective Electrodynamics: Quantum Foundations of Electromagnetism (2000), Mead purports to analyze the behavior of electrons and photons purely in terms of electron wave functions, and attributes the apparent particle-like behavior to quantization effects and eigenstates. According to reviewer David Haddon: [45]

Mead has cut the Gordian knot of quantum complementarity. He claims that atoms, with their neutrons, protons, and electrons, are not particles at all but pure waves of matter. Mead cites as the gross evidence of the exclusively wave nature of both light and matter the discovery between 1933 and 1996 of ten examples of pure wave phenomena, including the ubiquitous laser of CD players, the self-propagating electrical currents of superconductors, and the Bose–Einstein condensate of atoms.

Albert Einstein, who, in his search for a Unified Field Theory, did not accept wave-particle duality, wrote: [46]

This double nature of radiation (and of material corpuscles) ... has been interpreted by quantum-mechanics in an ingenious and amazingly successful fashion. This interpretation ... appears to me as only a temporary way out...

The many-worlds interpretation (MWI) is sometimes presented as a waves-only theory, including by its originator, Hugh Everett who referred to MWI as "the wave interpretation". [47]

The three wave hypothesis of R. Horodecki relates the particle to wave. [48] [49] The hypothesis implies that a massive particle is an intrinsically spatially, as well as temporally extended, wave phenomenon by a nonlinear law.

The deterministic collapse theory [50] considers collapse and measurement as two independent physical processes. Collapse occurs when two wavepackets spatially overlap and satisfy a mathemetical criterion, which depends on the parameters of both wavepackets. It is a contraction to the overlap volume. In a measurement apparatus one of the two wavepackets is one of the atomic clusters, which constitute the apparatus, and the wavepackets collapse to at most the volume of such a cluster. This mimics the action of a point particle.

3. Particle-only view

Still in the days of the old quantum theory, a pre-quantum-mechanical version of wave–particle duality was pioneered by William Duane, [51] and developed by others including Alfred Landé. [52] Duane explained diffraction of x-rays by a crystal in terms solely of their particle aspect. The deflection of the trajectory of each diffracted photon was explained as due to quantized momentum transfer from the spatially regular structure of the diffracting crystal. [53]

4. Neither-wave-nor-particle view

It has been argued that there are never exact particles or waves, but only some compromise or intermediate between them. For this reason, in 1928 Arthur Eddington [54] coined the name "wavicle" to describe the objects although it is not regularly used today. One consideration is that zero-dimensional mathematical points cannot be observed. Another is that the formal representation of such points, the Dirac delta function is unphysical, because it cannot be normalized. Parallel arguments apply to pure wave states. Roger Penrose states: [55]

Such 'position states' are idealized wavefunctions in the opposite sense from the momentum states. Whereas the momentum states are infinitely spread out, the position states are infinitely concentrated. Neither is normalizable [...].

5. Relational approach to wave–particle duality

Relational quantum mechanics has been developed as a point of view that regards the event of particle detection as having established a relationship between the quantized field and the detector. The inherent ambiguity associated with applying Heisenberg's uncertainty principle is consequently avoided; hence there is no wave-particle duality. [56]

Uses

Although it is difficult to draw a line separating wave–particle duality from the rest of quantum mechanics, it is nevertheless possible to list some applications of this basic idea.

See also

Related Research Articles

Bohr model atomic model introduced by Niels Bohr in 1913

In atomic physics, the Rutherford–Bohr model or Bohr model, presented by Niels Bohr and Ernest Rutherford in 1913, is a system consisting of a small, dense nucleus surrounded by orbiting electrons—similar to the structure of the Solar System, but with attraction provided by electrostatic forces in place of gravity. After the cubic model (1902), the plum-pudding model (1904), the Saturnian model (1904), and the Rutherford model (1911) came the Rutherford–Bohr model or just Bohr model for short (1913). The improvement to the Rutherford model is mostly a quantum physical interpretation of it. The model's key success lay in explaining the Rydberg formula for the spectral emission lines of atomic hydrogen. While the Rydberg formula had been known experimentally, it did not gain a theoretical underpinning until the Bohr model was introduced. Not only did the Bohr model explain the reason for the structure of the Rydberg formula, it also provided a justification for its empirical results in terms of fundamental physical constants.

Double-slit experiment Physics experiment, showing light can be modelled by both waves and particles

In modern physics, the double-slit experiment is a demonstration that light and matter can display characteristics of both classically defined waves and particles; moreover, it displays the fundamentally probabilistic nature of quantum mechanical phenomena. The experiment was first performed with light by Thomas Young in 1801. In 1927, Davisson and Germer demonstrated that electrons show the same behavior, which was later extended to atoms and molecules.

Electromagnetic radiation form of energy emitted and absorbed by charged particles, which exhibits wave-like behavior as it travels through space

In physics, electromagnetic radiation refers to the waves of the electromagnetic field, propagating (radiating) through space, carrying electromagnetic radiant energy. It includes radio waves, microwaves, infrared, (visible) light, ultraviolet, X-rays, and gamma rays.

Photon elementary particle or quantum of light

The photon is a type of elementary particle. It is the quantum of the electromagnetic field including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. The invariant mass of the photon is zero; it always moves at the speed of light in a vacuum.

Photoelectric effect physical phenomenon

The photoelectric effect is the emission of electrons or other free carriers when light hits a material. Electrons emitted in this manner can be called photoelectrons. This phenomenon is commonly studied in electronic physics, as well as in fields of chemistry, such as quantum chemistry and electrochemistry.

Matter waves are a central part of the theory of quantum mechanics, being an example of wave–particle duality. All matter can exhibit wave-like behavior. For example, a beam of electrons can be diffracted just like a beam of light or a water wave. The concept that matter behaves like a wave was proposed by Louis de Broglie in 1924. It is also referred to as the de Broglie hypothesis. Matter waves are referred to as de Broglie waves.

Quantum optics (QO) is a field of research that uses semi-classical and quantum-mechanical physics to investigate phenomena involving light and its interactions with matter at submicroscopic levels. In other words it is quantum mechanics applied to photons or light.

The old quantum theory is a collection of results from the years 1900–1925 which predate modern quantum mechanics. The theory was never complete or self-consistent, but was rather a set of heuristic corrections to classical mechanics. The theory is now understood as the semi-classical approximation to modern quantum mechanics.

The Davisson–Germer experiment was a 1923-27 experiment by Clinton Davisson and Lester Germer at Western Electric, in which electrons, scattered by the surface of a crystal of nickel metal, displayed a diffraction pattern. This confirmed the hypothesis, advanced by Louis de Broglie in 1924, of wave-particle duality, and was an experimental milestone in the creation of quantum mechanics.

Quantum mechanics is the science of the very small. It explains the behavior of matter and its interactions with energy on the scale of atoms and subatomic particles. By contrast, classical physics explains matter and energy only on a scale familiar to human experience, including the behavior of astronomical bodies such as the Moon. Classical physics is still used in much of modern science and technology. However, towards the end of the 19th century, scientists discovered phenomena in both the large (macro) and the small (micro) worlds that classical physics could not explain. The desire to resolve inconsistencies between observed phenomena and classical theory led to two major revolutions in physics that created a shift in the original scientific paradigm: the theory of relativity and the development of quantum mechanics. This article describes how physicists discovered the limitations of classical physics and developed the main concepts of the quantum theory that replaced it in the early decades of the 20th century. It describes these concepts in roughly the order in which they were first discovered. For a more complete history of the subject, see History of quantum mechanics.

The theoretical and experimental justification for the Schrödinger equation motivates the discovery of the Schrödinger equation, the equation that describes the dynamics of nonrelativistic particles. The motivation uses photons, which are relativistic particles with dynamics described by Maxwell's equations, as an analogue for all types of particles.

The history of quantum mechanics is a fundamental part of the history of modern physics. Quantum mechanics' history, as it interlaces with the history of quantum chemistry, began essentially with a number of different scientific discoveries: the 1838 discovery of cathode rays by Michael Faraday; the 1859–60 winter statement of the black-body radiation problem by Gustav Kirchhoff; the 1877 suggestion by Ludwig Boltzmann that the energy states of a physical system could be discrete; the discovery of the photoelectric effect by Heinrich Hertz in 1887; and the 1900 quantum hypothesis by Max Planck that any energy-radiating atomic system can theoretically be divided into a number of discrete "energy elements" ε (epsilon) such that each of these energy elements is proportional to the frequency ν with which each of them individually radiate energy, as defined by the following formula:

The Bohr–Kramers–Slater theory was perhaps the final attempt at understanding the interaction of matter and electromagnetic radiation on the basis of the so-called old quantum theory, in which quantum phenomena are treated by imposing quantum restrictions on classically describable behaviour. It was advanced in 1924, and sticks to a classical wave description of the electromagnetic field. It was perhaps more a research program than a full physical theory, the ideas that are developed not being worked out in a quantitative way.

Planck constant physical constant representing the quantum of action

The Planck constant, or Planck's constant, denoted is a physical constant that is the quantum of electromagnetic action, which relates the energy carried by a photon to its frequency. A photon's energy is equal to its frequency multiplied by the Planck constant. The Planck constant is of fundamental importance in quantum mechanics, and in metrology it is the basis for the definition of the kilogram.

The Planck–Einstein relation is also referred to as the Einstein relation, Planck's energy–frequency relation, the Planck relation, and the Planck equation. Also the eponym Planck formula belongs on this list, but also often refers to Planck's law instead. These various eponyms are far from standard; they are used only sporadically, neither regularly nor very widely. They refer to a formula integral to quantum mechanics, which states that the energy of a photon, E, known as photon energy, is proportional to its frequency, ν:

In 1922 American physicist William Duane presented a discrete momentum-exchange model of the reflection of X-Ray photons by a crystal lattice. Duane showed that such a model gives the same scattering angles as the ones calculated via a wave diffraction model, see Bragg's Law.

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