| Phosphorus | |
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| Phosphorus virescens | |
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| Genus: | Phosphorus |
Phosphorus is a genus of longhorn beetles of the subfamily Lamiinae, [1] containing the following species:
Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Earth. It has a concentration in the Earth's crust of about one gram per kilogram. In minerals, phosphorus generally occurs as phosphate.
In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid H
3PO
4.
A match is a tool for starting a fire. Typically, matches are made of small wooden sticks or stiff paper. One end is coated with a material that can be ignited by frictional heat generated by striking the match against a suitable surface. Wooden matches are packaged in matchboxes, and paper matches are partially cut into rows and stapled into matchbooks. The coated end of a match, known as the match "head", consists of a bead of active ingredients and binder; often colored for easier inspection. There are two main types of matches: safety matches, which can be struck only against a specially prepared surface, and strike-anywhere matches, for which any suitably frictional surface can be used.
A pnictogen is any of the chemical elements in group 15 of the periodic table. This group is also known as the nitrogen family. It consists of the elements nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), and perhaps the chemically uncharacterized synthetic element moscovium (Mc).
Phosphine (IUPAC name: phosphane) is the compound with the chemical formula PH3. It is a colorless, flammable, toxic gas and is classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like garlic or rotting fish, due to the presence of substituted phosphine and diphosphane (P2H4). With traces of P2H4 present, PH3 is spontaneously flammable in air (pyrophoric), burning with a luminous flame. Phosphines are also a group of organophosphorus compounds with the formula R3P (R = organic derivative). Organophosphines are important in catalysts where they complex to various metal ions; complexes derived from a chiral phosphine can catalyze reactions to give chiral, enantioenriched products.
Phossy jaw, formally known as phosphorus necrosis of the jaw, was an occupational disease affecting those who worked with white phosphorus without proper safeguards. It was most commonly seen in workers in the matchstick industry in the 19th and early 20th centuries. It was caused by white phosphorus vapour, which destroys the bones of the jaw. Modern occupational hygiene practices have since eliminated the working conditions that caused this disease.
In Greek mythology, Hesperus is the Evening Star, the planet Venus in the evening. He is the son of the dawn goddess Eos and is the half-brother of her other son, Phosphorus. Hesperus' Roman equivalent is Vesper. By one account Hesperus' father was Cephalus, a mortal, while Phosphorus' was the star god Astraios. Other sources, however, state that Hesperus was the brother of Atlas, and thus the son of Iapetus.
Phosphorite,phosphate rock or rock phosphate is a non-detrital sedimentary rock that contains high amounts of phosphate minerals. The phosphate content of phosphorite (or grade of phosphate rock) varies greatly, from 4% to 20% phosphorus pentoxide (P2O5). Marketed phosphate rock is enriched ("beneficiated") to at least 28%, often more than 30% P2O5. This occurs through washing, screening, de-liming, magnetic separation or flotation. By comparison, the average phosphorus content of sedimentary rocks is less than 0.2%. The phosphate is present as fluorapatite Ca5(PO4)3F typically in cryptocrystalline masses (grain sizes < 1 μm) referred to as collophane-sedimentary apatite deposits of uncertain origin. It is also present as hydroxyapatite Ca5(PO4)3OH or Ca10(PO4)6(OH)2, which is often dissolved from vertebrate bones and teeth, whereas fluorapatite can originate from hydrothermal veins. Other sources also include chemically dissolved phosphate minerals from igneous and metamorphic rocks. Phosphorite deposits often occur in extensive layers, which cumulatively cover tens of thousands of square kilometres of the Earth's crust.
White phosphorus munitions are weapons which use one of the common allotropes of the chemical element phosphorus. White phosphorus is used in smoke, illumination and incendiary munitions, and is commonly the burning element of tracer ammunition. Other common names include WP and the slang term "Willie Pete" or "Willie Peter" derived from William Peter, the World War II phonetic alphabet for "WP", which is still sometimes used in military jargon. White phosphorus is pyrophoric, burns fiercely, and can ignite cloth, fuel, ammunition, and other combustibles.
Phosphorus pentachloride is the chemical compound with the formula PCl5. It is one of the most important phosphorus chlorides, others being PCl3 and POCl3. PCl5 finds use as a chlorinating reagent. It is a colourless, water-sensitive and moisture-sensitive solid, although commercial samples can be yellowish and contaminated with hydrogen chloride.
Phosphorus trichloride is a chemical compound of phosphorus and chlorine, having the chemical formula PCl3. It is a toxic and volatile liquid which reacts violently with water to release HCl gas. It has a trigonal pyramidal shape, owing to the lone pairs on the phosphorus. It is an important industrial chemical, being used for the manufacture of phosphites and other organophosphorus compounds for a wide variety of applications. It has a 31P NMR signal at around +220 ppm with reference to a phosphoric acid standard.
Phosphorus trifluoride (formula PF3), is a colorless and odorless gas. It is highly toxic and reacts slowly with water. Its main use is as a ligand in metal complexes. As a ligand, it parallels carbon monoxide in metal carbonyls, and indeed its toxicity is due to its binding with the iron in blood hemoglobin in a similar way to carbon monoxide.
Phosphorus pentoxide is a chemical compound with molecular formula P4O10 (with its common name derived from its empirical formula, P2O5). This white crystalline solid is the anhydride of phosphoric acid. It is a powerful desiccant and dehydrating agent.
Doctor Phosphorus is a fictional character who has appeared in various comic book series published by DC Comics. Primarily an enemy of Batman, the supervillain exists in DC's main shared universe, known as the DC Universe.
Organophosphorus compounds are organic compounds containing phosphorus. They are used primarily in pest control as an alternative to chlorinated hydrocarbons that persist in the environment. Some organophosphorus compounds are highly effective insecticides, although some are extremely toxic to humans, including sarin and VX nerve agents.
The phosphorus cycle is the biogeochemical cycle that describes the movement of phosphorus through the lithosphere, hydrosphere, and biosphere. Unlike many other biogeochemical cycles, the atmosphere does not play a significant role in the movement of phosphorus, because phosphorus and phosphorus-based compounds are usually solids at the typical ranges of temperature and pressure found on Earth. The production of phosphine gas occurs in only specialized, local conditions. Therefore, the phosphorus cycle should be viewed from whole Earth system and then specifically focused on the cycle in terrestrial and aquatic systems.
Elemental phosphorus can exist in several allotropes, the most common of which are white and red solids. Solid violet and black allotropes are also known. Gaseous phosphorus exists as diphosphorus and atomic phosphorus.
Phosphorus was a British Thoroughbred racehorse and sire. In his British career he ran three times and won two races. His most significant win came when he overcame a leg injury to win the 1837 Epsom Derby. Phosphorus was later sold and exported to Brunswick, but was unable to reproduce his English form. He was unsuccessful as a stallion.
Phosphorus Rex is a supervillain in DC Comics.
Phosphorus monoxide is an unstable radical inorganic compound with molecular formula PO.
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