Elastomer

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An elastomer is a polymer with viscoelasticity (i.e. both viscosity and elasticity) and with weak intermolecular forces, generally low Young's modulus (E) and high failure strain compared with other materials. [1] The term, a portmanteau of elastic polymer, [2] is often used interchangeably with rubber , although the latter is preferred when referring to vulcanisates. [3] Each of the monomers which link to form the polymer is usually a compound of several elements among carbon, hydrogen, oxygen and silicon. Elastomers are amorphous polymers maintained above their glass transition temperature, so that considerable molecular reconformation is feasible without breaking of covalent bonds. At ambient temperatures, such rubbers are thus relatively compliant (E ≈ 3 MPa) and deformable. Their primary uses are for seals, adhesives and molded flexible parts.[ citation needed ]

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IUPAC definition for an elastomer in polymer chemistry IUPAC definition for an elastomer in polymer chemistry.png
IUPAC definition for an elastomer in polymer chemistry

Rubber-like solids with elastic properties are called elastomers. Polymer chains are held together in these materials by relatively weak intermolecular bonds, which permit the polymers to stretch in response to macroscopic stresses.

(A) is an unstressed polymer; (B) is the same polymer under stress. When the stress is removed, it will return to the A configuration. (The dots represent cross-links) Polymer picture.svg
(A) is an unstressed polymer; (B) is the same polymer under stress. When the stress is removed, it will return to the A configuration. (The dots represent cross-links)

Elastomers are usually thermosets (requiring vulcanization) but may also be thermoplastic (see thermoplastic elastomer). The long polymer chains cross-link during curing (i.e. vulcanizing). The molecular structure of elastomers can be imagined as a 'spaghetti and meatball' structure, with the meatballs signifying cross-links. The elasticity is derived from the ability of the long chains to reconfigure themselves to distribute an applied stress. The covalent cross-linkages ensure that the elastomer will return to its original configuration when the stress is removed.

Crosslinking most likely occurs in an equilibrated polymer without any solvent. The free energy expression derived from the Neohookean model of rubber elasticity is in terms of free energy change due to deformation per unit volume of the sample. The strand concentration, v, is the number of strands over the volume which does not depend on the overall size and shape of the elastomer. [4] Beta relates the end-to-end distance of polymer strands across crosslinks over polymers that obey random walk statistics.

In the specific case of shear deformation, the elastomer besides abiding to the simplest model of rubber elasticity is also incompressible. For pure shear we relate the shear strain, to the extension ratios lambdas. Pure shear is a two-dimensional stress state making lambda equal to 1, reducing the energy strain function above to:

To get shear stress, then the energy strain function is differentiated with respect to shear strain to get the shear modulus, G, times the shear strain:

Shear stress is then proportional to the shear strain even at large strains. [5] Notice how a low shear modulus correlates to a low deformation strain energy density and vice versa. Shearing deformation in elastomers, require less energy to change shape than volume.

Examples

Unsaturated rubbers that can be cured by sulfur vulcanization:

Saturated rubbers that cannot be cured by sulfur vulcanization:

Various other types of elastomers:

See also

Related Research Articles

<span class="mw-page-title-main">Hooke's law</span> Physical law: force needed to deform a spring scales linearly with distance

In physics, Hooke's law is an empirical law which states that the force needed to extend or compress a spring by some distance scales linearly with respect to that distance—that is, Fs = kx, where k is a constant factor characteristic of the spring, and x is small compared to the total possible deformation of the spring. The law is named after 17th-century British physicist Robert Hooke. He first stated the law in 1676 as a Latin anagram. He published the solution of his anagram in 1678 as: ut tensio, sic vis. Hooke states in the 1678 work that he was aware of the law since 1660.

In engineering, deformation refers to the change in size or shape of an object. Displacements are the absolute change in position of a point on the object. Deflection is the relative change in external displacements on an object. Strain is the relative internal change in shape of an infinitesimal cube of material and can be expressed as a non-dimensional change in length or angle of distortion of the cube. Strains are related to the forces acting on the cube, which are known as stress, by a stress-strain curve. The relationship between stress and strain is generally linear and reversible up until the yield point and the deformation is elastic. Elasticity in materials occurs when applied stress does not surpass the energy required to break molecular bonds, allowing the material to deform reversibly and return to its original shape once the stress is removed. The linear relationship for a material is known as Young's modulus. Above the yield point, some degree of permanent distortion remains after unloading and is termed plastic deformation. The determination of the stress and strain throughout a solid object is given by the field of strength of materials and for a structure by structural analysis.

<span class="mw-page-title-main">Poisson's ratio</span> Measure of material deformation perpendicular to loading

In materials science and solid mechanics, Poisson's ratioν (nu) is a measure of the Poisson effect, the deformation of a material in directions perpendicular to the specific direction of loading. The value of Poisson's ratio is the negative of the ratio of transverse strain to axial strain. For small values of these changes, ν is the amount of transversal elongation divided by the amount of axial compression. Most materials have Poisson's ratio values ranging between 0.0 and 0.5. For soft materials, such as rubber, where the bulk modulus is much higher than the shear modulus, Poisson's ratio is near 0.5. For open-cell polymer foams, Poisson's ratio is near zero, since the cells tend to collapse in compression. Many typical solids have Poisson's ratios in the range of 0.2 to 0.3. The ratio is named after the French mathematician and physicist Siméon Poisson.

Dynamic mechanical analysis is a technique used to study and characterize materials. It is most useful for studying the viscoelastic behavior of polymers. A sinusoidal stress is applied and the strain in the material is measured, allowing one to determine the complex modulus. The temperature of the sample or the frequency of the stress are often varied, leading to variations in the complex modulus; this approach can be used to locate the glass transition temperature of the material, as well as to identify transitions corresponding to other molecular motions.

In materials science and continuum mechanics, viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like water, resist shear flow and strain linearly with time when a stress is applied. Elastic materials strain when stretched and immediately return to their original state once the stress is removed.

<span class="mw-page-title-main">EPDM rubber</span> Type of synthetic rubber

EPDM rubber is a type of synthetic rubber that is used in many applications.

A synthetic rubber is an artificial elastomer. They are polymers synthesized from petroleum byproducts. About 32 million metric tons of rubbers are produced annually in the United States, and of that amount two thirds are synthetic. Synthetic rubber, just like natural rubber, has many uses in the automotive industry for tires, door and window profiles, seals such as O-rings and gaskets, hoses, belts, matting, and flooring. They offer a different range of physical and chemical properties which can improve the reliability of a given product or application. Synthetic rubbers are superior to natural rubbers in two major respects: thermal stability, and resistance to oils and related compounds. They are more resistant to oxidizing agents, such as oxygen and ozone which can reduce the life of products like tires.

<span class="mw-page-title-main">Delamination</span> Mode of failure for which a material fractures into layers

Delamination is a mode of failure where a material fractures into layers. A variety of materials, including laminate composites and concrete, can fail by delamination. Processing can create layers in materials, such as steel formed by rolling and plastics and metals from 3D printing which can fail from layer separation. Also, surface coatings, such as paints and films, can delaminate from the coated substrate.

In continuum mechanics, the finite strain theory—also called large strain theory, or large deformation theory—deals with deformations in which strains and/or rotations are large enough to invalidate assumptions inherent in infinitesimal strain theory. In this case, the undeformed and deformed configurations of the continuum are significantly different, requiring a clear distinction between them. This is commonly the case with elastomers, plastically deforming materials and other fluids and biological soft tissue.

A neo-Hookean solid is a hyperelastic material model, similar to Hooke's law, that can be used for predicting the nonlinear stress-strain behavior of materials undergoing large deformations. The model was proposed by Ronald Rivlin in 1948 using invariants, though Mooney had already described a version in stretch form in 1940, and Wall had noted the equivalence in shear with the Hooke model in 1942.

Elastic energy is the mechanical potential energy stored in the configuration of a material or physical system as it is subjected to elastic deformation by work performed upon it. Elastic energy occurs when objects are impermanently compressed, stretched or generally deformed in any manner. Elasticity theory primarily develops formalisms for the mechanics of solid bodies and materials. The elastic potential energy equation is used in calculations of positions of mechanical equilibrium. The energy is potential as it will be converted into other forms of energy, such as kinetic energy and sound energy, when the object is allowed to return to its original shape (reformation) by its elasticity.

<span class="mw-page-title-main">Acrylate polymer</span> Group of polymers prepared from acrylate monomers

An acrylate polymer is any of a group of polymers prepared from acrylate monomers. These plastics are noted for their transparency, resistance to breakage, and elasticity.

Rubber elasticity refers to a property of crosslinked rubber: it can be stretched by up to a factor of 10 from its original length and, when released, returns very nearly to its original length. This can be repeated many times with no apparent degradation to the rubber. Rubber is a member of a larger class of materials called elastomers and it is difficult to overestimate their economic and technological importance. Elastomers have played a key role in the development of new technologies in the 20th century and make a substantial contribution to the global economy. Rubber elasticity is produced by several complex molecular processes and its explanation requires a knowledge of advanced mathematics, chemistry and statistical physics, particularly the concept of entropy. Entropy may be thought of as a measure of the thermal energy that is stored in a molecule. Common rubbers, such as polybutadiene and polyisoprene, are produced by a process called polymerization. Very long molecules (polymers) are built up sequentially by adding short molecular backbone units through chemical reactions. A rubber polymer follows a random, zigzag path in three dimensions, intermingling with many other rubber molecules. An elastomer is created by the addition of a few percent of a cross linking molecule such as sulfur. When heated, the crosslinking molecule causes a reaction that chemically joins (bonds) two of the rubber molecules together at some point. Because the rubber molecules are so long, each one participates in many crosslinks with many other rubber molecules forming a continuous molecular network. As a rubber band is stretched, some of the network chains are forced to become straight and this causes a decrease in their entropy. It is this decrease in entropy that gives rise to the elastic force in the network chains.

Membrane roofing is a type of roofing system for buildings, RV's, Ponds and in some cases tanks. It is used to create a watertight covering to protect the interior of a building. Membrane roofs are most commonly made from synthetic rubber, thermoplastic, or modified bitumen. Membrane roofs are most commonly used in commercial application, though they are becoming increasingly common in residential application.

The Ogden material model is a hyperelastic material model used to describe the non-linear stress–strain behaviour of complex materials such as rubbers, polymers, and biological tissue. The model was developed by Raymond Ogden in 1972. The Ogden model, like other hyperelastic material models, assumes that the material behaviour can be described by means of a strain energy density function, from which the stress–strain relationships can be derived.

Rubber toughening is a process in which rubber nanoparticles are interspersed within a polymer matrix to increase the mechanical robustness, or toughness, of the material. By "toughening" a polymer it is meant that the ability of the polymeric substance to absorb energy and plastically deform without fracture is increased. Considering the significant advantages in mechanical properties that rubber toughening offers, most major thermoplastics are available in rubber-toughened versions; for many engineering applications, material toughness is a deciding factor in final material selection.

In mechanics, strain is defined as relative deformation, compared to a reference position configuration. Different equivalent choices may be made for the expression of a strain field depending on whether it is defined with respect to the initial or the final configuration of the body and on whether the metric tensor or its dual is considered.

In continuum mechanics, an Arruda–Boyce model is a hyperelastic constitutive model used to describe the mechanical behavior of rubber and other polymeric substances. This model is based on the statistical mechanics of a material with a cubic representative volume element containing eight chains along the diagonal directions. The material is assumed to be incompressible. The model is named after Ellen Arruda and Mary Cunningham Boyce, who published it in 1993.

The acoustoelastic effect is how the sound velocities of an elastic material change if subjected to an initial static stress field. This is a non-linear effect of the constitutive relation between mechanical stress and finite strain in a material of continuous mass. In classical linear elasticity theory small deformations of most elastic materials can be described by a linear relation between the applied stress and the resulting strain. This relationship is commonly known as the generalised Hooke's law. The linear elastic theory involves second order elastic constants and yields constant longitudinal and shear sound velocities in an elastic material, not affected by an applied stress. The acoustoelastic effect on the other hand include higher order expansion of the constitutive relation between the applied stress and resulting strain, which yields longitudinal and shear sound velocities dependent of the stress state of the material. In the limit of an unstressed material the sound velocities of the linear elastic theory are reproduced.

<span class="mw-page-title-main">Charles Goodyear Medal</span> Award

The Charles Goodyear Medal is the highest honor conferred by the American Chemical Society, Rubber Division. Established in 1941, the award is named after Charles Goodyear, the discoverer of vulcanization, and consists of a gold medal, a framed certificate and prize money. The medal honors individuals for "outstanding invention, innovation, or development which has resulted in a significant change or contribution to the nature of the rubber industry". Awardees give a lecture at an ACS Rubber Division meeting, and publish a review of their work in the society's scientific journal Rubber Chemistry and Technology.

References

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  2. Gent, Alan N. "Elastomer Chemical Compound". Encyclopædia Britannica. Archived from the original on 2017-02-07. Retrieved 7 February 2017.
  3. Alger, Mark (21 April 1989). Polymer Science Dictionary. Springer. p. 503. ISBN   1851662200. Archived from the original on 2017-02-07. Retrieved 7 February 2017.
  4. Boczkowska, Anna; Awietjan, Stefan F.; Pietrzko, Stanisław; Kurzydłowski, Krzysztof J. (2012-03-01). "Mechanical Properties of Magnetorheological Elastomers under Shear Deformation". Composites Part B: Engineering. 43 (2): 636–640. doi:10.1016/j.compositesb.2011.08.026. ISSN   1359-8368.
  5. Liao, Guojiang; Gong, Xinglong; Xuan, Shouhu (2013-09-01). "Influence of Shear Deformation on the Normal Force of Magnetorheological Elastomer". Materials Letters. 106: 270–272. Bibcode:2013MatL..106..270L. doi:10.1016/j.matlet.2013.05.035. ISSN   0167-577X.