Adsorption/Bio-oxidation process

Last updated

The adsorption/bio-oxidation process (AB process) is a two-stage modification of the activated sludge process used for wastewater treatment. It consists of a high-loaded A-stage and low-loaded B-stage. The process is operated without a primary clarifier, with the A-stage being an open dynamic biological system. Both stages have separate settling tanks and sludge recycling lines, thus maintaining unique microbial communities in both reactors.

Contents

History

Adsorption/bio-oxidation process was invented in the mid-1970s by the professor of the RWTH Aachen University Botho Böhnke. It was based on the finding, made by the German engineer Karl Imhoff in the 50th.[ further explanation needed ] Imhoff stated that the treatment efficiency of 60-80 percent could be achieved in highly loaded activated sludge basins.[ citation needed ]

In 1977 Böhnke published his first article on adsorption/bio-oxidation process. [1] The same year the patent was issued. Extensive research of the following years, conducted by prof. Böhnke together with Bernd and Andreas Diering, ended up in 1985 with the establishment of the company Dr.-Ing. Bernd Diering GmbH. The same year AB-process was for the first time applied in a full-scale at the Krefeld, Germany sewage treatment plant (800 000 P.E.). In 1990, 19 full scale installations existed in Western Germany alone. Further application of the process in Europe was hindered by the tightening of the effluent discharge requirements with respect to nitrogen and phosphorus. The process came into notice in 2000th again due to the increased interest in energy recovery from wastewater.[ citation needed ]

Principle of operation

The A-stage, or adsorption stage is the most innovative component of the process. It is not preceded by primary treatment.

Simple schematic description of the adsorption/bio-oxidation process AB process scheme.png
Simple schematic description of the adsorption/bio-oxidation process

Influent organic matter is removed in the A-stage mainly by flocculation and sorption to sludge due to the high loading rates (2-10 g BOD • g VSS −1 • d−1) and low sludge age (typically 4-10 h). Hydrolysis of complex organic molecules occurs improving biodegradability of the influent of the B-stage. High loading rates and low sludge age favours development of dynamic biocoenosis with a large fraction of microorganisms present in the exponential growth phase. Diverse sludge biocoenosis increase variety of organic compounds that can be degraded in the A-stage and makes the process more stable towards the shock loads. [2] Altogether, up to 80% of the influent organic matter can be removed in the A-stage. [2] The required reactor volume and oxygen supply are lower if compared to the removal in the conventional activated sludge process.[ citation needed ]

The B-stage, or bio-oxidation stage, is a typical low-loaded activated sludge process, where biodegradation of the remaining organic material occurs. The B-stage can be designed for nitrogen and/or phosphorus removal by alternating aerobic, anoxic and anaerobic zones in the reactor.[ citation needed ]

Typical operational conditions of the adsorption/bio-oxidation process

ParameterA-stageB-stage
Loading rate, g BOD • g VSS−1 • d−12 - 100.05 - 0.3
HRT, h0.52 - 4
MLSS, g/L1.5 - 23 - 4
SRT, d0.2 - 0.515 - 20
Dissolved oxygen, mg/L0.2 - 0.70.7 - 1.5

Advantages of the process

Drawbacks of the process

Nutrient removal

Nitrogen removal in the A-stage can reach 30–40%, as nitrogen of organic compounds is incorporated in upflow anaerobic sludge blanket (UASB) reactor sludge.

The sludge age of the B-stage is typically between 8 and 20 days promoting the growth of nitrifiers. Therefore, complete nitrification is usually achieved in the B-stage. [2] Complete denitrification is difficult to achieve, because of the low C:N ratio in the influent of the B-stage. Insufficient carbon supply of carbon source to the B-stage occurs due to the high efficiency of organic matter removal in the A-stage. The problem can be solved by decreasing organic matter removal in the A-stage, external carbon source supply, intermittent aeration or decreased HRT of the A-stage and/or on-line control of certain operational parameters. [6] To achieve biological nitrogen and phosphorus removal anaerobic and anoxic compartments are introduced before the aerated zone of the B-stage.[ citation needed ]

Phosphorus removal from the secondary effluent of the B-stage can be achieved by coagulation with ferric and aluminium salts, e.g. FeCl3 or Al2(SO4)3. [7] [8]

Applications for municipal wastewater treatment

The adsorption/bio-oxidation process was applied at the Krefeld plant (800 000 P.E.) in 1985 for the first time. The plant was expanded and modified and currently treats municipal and industrial wastewater of 1 200 000 P.E. [2]

Currently adsorption/bio-oxidation process is applied at the municipal treatment plants in Germany, the Netherlands (WWTP Dokhaven (Rotterdam), WWTP Utrecht, WWTP Garmerwolde (Groningen) etc.), Austria (WWTP Salzburg, WWTP Strass etc.), Spain, US, China etc. [9]

Adsorption/bio-oxidation process is a part of innovative wastewater treatment concept WaterSchoon, realized in the Netherlands. 250 apartments in the new district Noorderhoek (Sneek, the Netherlands) are equipped with separate collection systems for toilet wastewater and the rest of the household wastewater (or so-called greywater). Both streams are treated separately in order to maximize recovery of resources from wastewater. Adsorption/bio-oxidation process is used for grey water treatment to increase sludge production. Sludge, produced in both stages of the process, is digested together with toilet wastewater in the UASB reactor to maximize energy recovery. [10]

Applications for industrial wastewater treatment

The adsorption/bio-oxidation process is used for treatment of industrial wastewater with high COD, including wastewater from:

The C/N and C/P ratios of industrial wastewater is often too high for complete aerobic biodegradation of the influent organic matter, even after the adsorption stage. Addition of nutrients prior to bio-oxidation stage is required in these cases. [11]

See also

Related Research Articles

<span class="mw-page-title-main">Wastewater treatment</span> Converting wastewater into an effluent for return to the water cycle

Wastewater treatment is a process which removes and eliminates contaminants from wastewater and converts this into an effluent that can be returned to the water cycle. Once returned to the water cycle, the effluent creates an acceptable impact on the environment or is reused for various purposes. The treatment process takes place in a wastewater treatment plant. There are several kinds of wastewater which are treated at the appropriate type of wastewater treatment plant. For domestic wastewater, the treatment plant is called a Sewage Treatment. For industrial wastewater, treatment either takes place in a separate Industrial wastewater treatment, or in a sewage treatment plant. Further types of wastewater treatment plants include Agricultural wastewater treatment and leachate treatment plants.

<span class="mw-page-title-main">Constructed wetland</span> Artificial wetland to treat municipal or industrial wastewater, greywater or stormwater runoff

A constructed wetland is an artificial wetland to treat sewage, greywater, stormwater runoff or industrial wastewater. It may also be designed for land reclamation after mining, or as a mitigation step for natural areas lost to land development. Constructed wetlands are engineered systems that use the natural functions of vegetation, soil, and organisms to provide secondary treatment to wastewater. The design of the constructed wetland has to be adjusted according to the type of wastewater to be treated. Constructed wetlands have been used in both centralized and decentralized wastewater systems. Primary treatment is recommended when there is a large amount of suspended solids or soluble organic matter.

<span class="mw-page-title-main">Waste stabilization pond</span> Ponds designed and built for wastewater treatment

Waste stabilization ponds are ponds designed and built for wastewater treatment to reduce the organic content and remove pathogens from wastewater. They are man-made depressions confined by earthen structures. Wastewater or "influent" enters on one side of the waste stabilization pond and exits on the other side as "effluent", after spending several days in the pond, during which treatment processes take place.

<span class="mw-page-title-main">Activated sludge</span> Wastewater treatment process using aeration and a biological floc

The activated sludgeprocess is a type of biological wastewater treatment process for treating sewage or industrial wastewaters using aeration and a biological floc composed of bacteria and protozoa. It uses air and microorganisms to biologically oxidize organic pollutants, producing a waste sludge containing the oxidized material.

<span class="mw-page-title-main">Industrial wastewater treatment</span> Processes used for treating wastewater that is produced by industries as an undesirable by-product

Industrial wastewater treatment describes the processes used for treating wastewater that is produced by industries as an undesirable by-product. After treatment, the treated industrial wastewater may be reused or released to a sanitary sewer or to a surface water in the environment. Some industrial facilities generate wastewater that can be treated in sewage treatment plants. Most industrial processes, such as petroleum refineries, chemical and petrochemical plants have their own specialized facilities to treat their wastewaters so that the pollutant concentrations in the treated wastewater comply with the regulations regarding disposal of wastewaters into sewers or into rivers, lakes or oceans. This applies to industries that generate wastewater with high concentrations of organic matter, toxic pollutants or nutrients such as ammonia. Some industries install a pre-treatment system to remove some pollutants, and then discharge the partially treated wastewater to the municipal sewer system.

An aerated lagoon is a simple wastewater treatment system consisting of a pond with artificial aeration to promote the biological oxidation of wastewaters.

<span class="mw-page-title-main">Secondary treatment</span> Biological treatment process for wastewater or sewage

Secondary treatment is the removal of biodegradable organic matter from sewage or similar kinds of wastewater. The aim is to achieve a certain degree of effluent quality in a sewage treatment plant suitable for the intended disposal or reuse option. A "primary treatment" step often precedes secondary treatment, whereby physical phase separation is used to remove settleable solids. During secondary treatment, biological processes are used to remove dissolved and suspended organic matter measured as biochemical oxygen demand (BOD). These processes are performed by microorganisms in a managed aerobic or anaerobic process depending on the treatment technology. Bacteria and protozoa consume biodegradable soluble organic contaminants while reproducing to form cells of biological solids. Secondary treatment is widely used in sewage treatment and is also applicable to many agricultural and industrial wastewaters.

<span class="mw-page-title-main">Sequencing batch reactor</span> Type of activated sludge process for the treatment of wastewater

Sequencing batch reactors (SBR) or sequential batch reactors are a type of activated sludge process for the treatment of wastewater. SBR reactors treat wastewater such as sewage or output from anaerobic digesters or mechanical biological treatment facilities in batches. Oxygen is bubbled through the mixture of wastewater and activated sludge to reduce the organic matter. The treated effluent may be suitable for discharge to surface waters or possibly for use on land.

<span class="mw-page-title-main">Sewage sludge treatment</span> Processes to manage and dispose of sludge during sewage treatment

Sewage sludge treatment describes the processes used to manage and dispose of sewage sludge produced during sewage treatment. Sludge treatment is focused on reducing sludge weight and volume to reduce transportation and disposal costs, and on reducing potential health risks of disposal options. Water removal is the primary means of weight and volume reduction, while pathogen destruction is frequently accomplished through heating during thermophilic digestion, composting, or incineration. The choice of a sludge treatment method depends on the volume of sludge generated, and comparison of treatment costs required for available disposal options. Air-drying and composting may be attractive to rural communities, while limited land availability may make aerobic digestion and mechanical dewatering preferable for cities, and economies of scale may encourage energy recovery alternatives in metropolitan areas.

<span class="mw-page-title-main">Aerobic granular reactor</span>

Aerobic granular reactors (AGR) or Aerobic granular sludge (AGS) are a community of microbial organisms, typically around 0.5-3mm in diameter, that remove carbon, nitrogen, phosphorus and other pollutants in a single sludge system. It can also be used for wastewater treatments. Aerobic granular sludge is composed of bacteria, protozoa and fungi,which allows oxygen to follow in and biologically oxidize organic pollutants. AGS is a type of wastewater treatment process for sewages and/or industrial waste treatment. AGR was first discovered by UK engineers, Edward Ardern and W.T. Lockett who were researching better ways for sewage disposal. Another scientist by the name of Dr. Gilbert Fowler, who was at the University of Manchester working on an experiment based on aeration of sewage in a bottle coated with algae. Eventually, all three scientists were able to collaborate with one another to discover AGR/AGS.

Powdered Activated Carbon Treatment (PACT) is a wastewater technology in which powdered activated carbon is added to an anaerobic or aerobic treatment system. The carbon in the biological treatment process adsorbs recalcitrant compounds that are not readily biodegradable, thereby reducing the chemical oxygen demand of the wastewater and removing toxins. The carbon also acts as a "buffer" against the effects of toxic organics in the wastewater.

<span class="mw-page-title-main">Fine bubble diffusers</span>

Fine bubble diffusers are a pollution control technology used to aerate wastewater for sewage treatment.

<span class="mw-page-title-main">Trickling filter</span> Type of wastewater treatment system with a fixed bed of rocks or similar

A trickling filter is a type of wastewater treatment system. It consists of a fixed bed of rocks, coke, gravel, slag, polyurethane foam, sphagnum peat moss, ceramic, or plastic media over which sewage or other wastewater flows downward and causes a layer of microbial slime (biofilm) to grow, covering the bed of media. Aerobic conditions are maintained by splashing, diffusion, and either by forced-air flowing through the bed or natural convection of air if the filter medium is porous. The treatment of sewage or other wastewater with trickling filters is among the oldest and most well characterized treatment technologies.

<span class="mw-page-title-main">Sewage treatment</span> Process of removing contaminants from municipal wastewater

Sewage treatment is a type of wastewater treatment which aims to remove contaminants from sewage to produce an effluent that is suitable to discharge to the surrounding environment or an intended reuse application, thereby preventing water pollution from raw sewage discharges. Sewage contains wastewater from households and businesses and possibly pre-treated industrial wastewater. There are a high number of sewage treatment processes to choose from. These can range from decentralized systems to large centralized systems involving a network of pipes and pump stations which convey the sewage to a treatment plant. For cities that have a combined sewer, the sewers will also carry urban runoff (stormwater) to the sewage treatment plant. Sewage treatment often involves two main stages, called primary and secondary treatment, while advanced treatment also incorporates a tertiary treatment stage with polishing processes and nutrient removal. Secondary treatment can reduce organic matter from sewage,  using aerobic or anaerobic biological processes. A so-called quarternary treatment step can also be added for the removal of organic micropollutants, such as pharmaceuticals. This has been implemented in full-scale for example in Sweden.

Membrane bioreactors are combinations of some membrane processes like microfiltration or ultrafiltration with a biological wastewater treatment process, the activated sludge process. These technologies are now widely used for municipal and industrial wastewater treatment. The two basic membrane bioreactor configurations are the submerged membrane bioreactor and the side stream membrane bioreactor. In the submerged configuration, the membrane is located inside the biological reactor and submerged in the wastewater, while in a side stream membrane bioreactor, the membrane is located outside the reactor as an additional step after biological treatment.

<span class="mw-page-title-main">Aerobic granulation</span>

The biological treatment of wastewater in the sewage treatment plant is often accomplished using conventional activated sludge systems. These systems generally require large surface areas for treatment and biomass separation units due to the generally poor settling properties of the sludge. Aerobic granules are a type of sludge that can self-immobilize flocs and microorganisms into spherical and strong compact structures. The advantages of aerobic granular sludge are excellent settleability, high biomass retention, simultaneous nutrient removal and tolerance to toxicity. Recent studies show that aerobic granular sludge treatment could be a potentially good method to treat high strength wastewaters with nutrients, toxic substances.

Mixed liquor suspended solids (MLSS) is the concentration of suspended solids, in an aeration tank during the activated sludge process, which occurs during the treatment of waste water. The units MLSS is primarily measured in milligram per litre (mg/L), but for activated sludge its mostly measured in gram per litre [g/L] which is equal to kilogram per cubic metre [kg/m3]. Mixed liquor is a combination of raw or unsettled wastewater or pre-settled wastewater and activated sludge within an aeration tank. MLSS consists mostly of microorganisms and non-biodegradable suspended matter. MLSS is an important part of the activated sludge process to ensure that there is a sufficient quantity of active biomass available to consume the applied quantity of organic pollutant at any time. This is known as the food to microorganism ratio, more commonly notated as the F/M ratio. By maintaining this ratio at the appropriate level the biomass will consume high percentages of the food. This minimizes the loss of residual food in the treated effluent. In simple terms, the more the biomass consumes the lower the biochemical oxygen demand (BOD) will be in the discharge. It is important that MLSS removes COD and BOD in order to purify water for clean surface waters, and subsequently clean drinking water and hygiene. Raw sewage enters in the water treatment process with a concentration of sometimes several hundred mg/L of BOD. Upon being treated by screening, pre-settling, activated sludge processes or other methods of treatment, the concentration of BOD in water can be lowered to less than 2 mg/L, which is considered to be clean, safe to discharge to surface waters or to reuse water.

<span class="mw-page-title-main">Vermifilter</span> Aerobic treatment system, consisting of a biological reactor containing media

A vermifilter is an aerobic treatment system, consisting of a biological reactor containing media that filters organic material from wastewater. The media also provides a habitat for aerobic bacteria and composting earthworms that purify the wastewater by removing pathogens and oxygen demand. The "trickling action" of the wastewater through the media dissolves oxygen into the wastewater, ensuring the treatment environment is aerobic for rapid decomposition of organic substances.

<span class="mw-page-title-main">Moving bed biofilm reactor</span> Type of wastewater treatment

Moving bed biofilm reactor (MBBR) is a type of wastewater treatment process that was first invented by Professor Hallvard Ødegaard at Norwegian University of Science and Technology in the late 1980s. The process takes place in an aeration tank with plastic carriers that a biofilm can grow on. The compact size and cheap wastewater treatment costs offers many advantages for the system. The main objective of using MBBR being water reuse and nutrient removal or recovery. In theory, wastewater will be no longer considered waste, it can be considered a resource.

References

  1. Böhnke B. (1977). Das Adsorptions-Belebungsverfahren. Korrespondenz Abwasser, 24. Jahrg., 2/77
  2. 1 2 3 4 5 Boehnke, B., Diering, B., & Zuckut, S. W. (1997). AB process removes organics and nutrients. Water Environment and Technology, 9(3), 23-27.
  3. 1 2 Technologies that Transform. Pollutants into Innocuous Components. www.eolss.net
  4. 1 2 Energy efficiency in the European water industry Archived 2019-05-01 at the Wayback Machine . Stowa report #2010-44
  5. Wang, J.-L., Zhang, J.-T., Chen, X.,`Yi, H.-X. (2011). Characteristics of heavy-metal translating in adsorption and biodegradation activated sludge process. International Conference on Electric Technology and Civil Engineering, ICETCE 2011 - Proceedings.
  6. Wenyi, D., Hong, D., Li-an, Z., Jia, M., Baozhen, W. (2006). Operational retrofits of AB process for biological removal of nitrogen and phosphorus. Water Practice & Technology, 1 (4) doi: 10.2166/WPT.2006078
  7. Xie, J.-L., Shen, X., Peng, Z., Wang, Q. (2011). Study on the phosphorus removal from the secondary effluent of AB process by ferric chloride. 5th International Conference on Bioinformatics and Biomedical Engineering, ICBBE 2011 - Proceedings
  8. Hu, Y.-Y., Luo, X.-X., Cheng, J.-H., Luo, G. (2008). Experimental investigation of chemically-enhanced phosphorus removal with adsorption-biodegradation process. Journal of South China University of Technology (Natural Science)
  9. Inventarisatie van AB-systemen in NL Archived 2016-03-05 at the Wayback Machine . www.stowa.nl
  10. Archived 2017-09-09 at the Wayback Machine . www.waterschoon.nl
  11. 1 2 Knudsen, L., Pedersen, J. A., & Munck, J. (1994). Advanced treatment of paper mill effluents by a two-stage activated sludge process. Water Science and Technology, 30 (3), 173-181
  12. 1 2 Schulze-Rettmer, R., Kim, S. S., & Son, S. S. (1992). Experience with two-stage activated sludge plants for industrial wastewaters in Korea. Water Science and Technology, 25 (4-5), 427-428.
  13. 1 2 Jenkins, D. & Wanner, J, (Eds.) (2014). Activated Sludge - 100 Years and Counting. IWA publishing ISBN   9781780404943.