The Ashland/Northern States Power Lakefront Superfund site is a contaminated region of the Wisconsin shoreline of Lake Superior that is being studied for remediation by Northern States Power Wisconsin (NSPW), as well as the Environmental Protection Agency (EPA), the Wisconsin Department of Natural Resources (WDNR). [1] This site has held a manufactured gas plant from 1845 to 1947, as well as lumber manufacturing and treatment mills for four decades at the start of the 20th century, railcar loading facilities, and a municipal landfill. [2] Additionally, a wastewater treatment plant is located on the premises, but is not in operation. [3] Contamination of the site is currently believed to have been caused by all the parties mentioned above, or former owners of the property whose companies are no longer in business. The area is listed as a Superfund site by the EPA under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). Releases of hazardous substances occurred onshore and migrated into sediment in Chequamagon Bay on Lake Superior.
Lake Superior, the largest of the Great Lakes of North America, is also the world's largest freshwater lake by surface area, and the third largest freshwater lake by volume. The lake is shared by the Canadian province of Ontario to the north, the U.S. state of Minnesota to the west, and Wisconsin and the Upper Peninsula of Michigan to the south. The farthest north and west of the Great Lakes chain, Superior has the highest elevation of all five great lakes and drains into the St. Mary's River.
The Wisconsin Department of Natural Resources (WDNR) is an agency of the state of Wisconsin charged with conserving and managing Wisconsin's natural resources. The Wisconsin Natural Resources Board has the authority to set policy for the WDNR. The WDNR is led by the Secretary, who is appointed by the Governor of Wisconsin. The WDNR develops regulations and guidance in accordance with laws passed by the Wisconsin Legislature. It administers wildlife, fish, forests, endangered resources, air, water, waste, and other issues related to natural resources. The central office of the WDNR is located in downtown Madison, near the state capitol.
Industrial wastewater treatment describes the processes used for treating wastewater that is produced by industries as an undesirable by-product. After treatment, the treated industrial wastewater may be reused or released to a sanitary sewer or to a surface water in the environment.
The history of the site can be broken down into the operational histories of each of the components to the contaminated site.
During the late 19th and early 20th centuries, the most common form of energy and lighting used in homes, industry, and public was flammable gas that was burned for whatever effect was desired (heat, light, etc.). This gas was made at a Manufactured Gas Plant (MGP). At the Ashland site, the MGP was located on the bluffs behind and slightly raised above the shoreline, and was in operation from 1845 until 1947. Here, coal, peat, and other materials were heated, creating a gas that could be stored and pumped out to consumers. However, this created tar and tar-tainted water as by-products that had to be disposed of. Some of the tar may have been used to treat lumber at the nearby lumber manufacturers. The rest had to be disposed of, a portion of which was dumped or released. A result was that many of the by-products ended up in local terrestrial and aquatic environments. This was the source of the MGP's main contribution to the contamination to the site. [2] Although NSPW did not own or operate the MGP itself, it eventually acquired the liabilities as a successor to the former MGP operator.
From 1901 until 1939, a company known as the John Schroeder Lumber Company owned and operated a sawmill on the banks of Lake Superior, down below the MGP mentioned above. In the course of its life, the mill manufactured and treated various wood products. These process included cutting logs into beams and planks, treating woods with tars and other chemicals to seal them, etc. By-products of these process were wood chips, saw dust, and particulates of the tar/creosote products used. After the plant was closed, its title passed to the County of Ashland and then to the City of Ashland, who eventually built a wastewater treatment plant on nearby land. [3] [4]
For a period of time, a portion of this locale was used as a landfill by the City mostly for municipal waste and destruction debris. [3] It opened sometime in the 1880s and closed in 1951.
Built in 1951 and expanded in 1972, the wastewater treatment plant serviced the greater Ashland area. In the process of exploring further expansion options in 1989, contaminated soil and groundwater samples were found, indicating a potential problem. The City closed that plant, and built a new one a few miles away. Five years later, in 1994, an investigation was launched into the area to determine the reach of the contamination. [5]
The primary contaminants are tar (VOCs, SVOCs, heavy metals, oil sheens) and wood by-products (sawdust, chips, lumber, tar), as well as landfill waste. Additionally, some of the organic contaminants are concentrated into non-aqueous phase liquids (NAPL). [6]
Tar itself is a dangerous substance. In its makeup, it often contains polycyclic aromatic hydrocarbons and trace heavy metals, both of which are suspected to be carcinogenic. [7] Additionally, the tar releases Volatile Organic Compounds (VOCs) and Semi Volatile Organic Compounds (SVOCs). VOCs and SVOCs contain carbon as a basis to their structure, and are prone to evaporating under normally reasonable temperatures and pressures. They are usually highly noxious, and can be harmful to the photochemical processes that are important to our atmosphere. [8] The removal of these products is the main end goal for the remediation of the site, and is proving to be the greatest challenge to clean.
Unlike tar, the wood is not inherently dangerous. It is the location and abundance of it that makes it a problem. Estimates say that the depth of wood by-products in the region of the bay ranges from two feet to ten feet thick, on top of approximately six feet of contaminated sediment. [4] This makes the extraction of the contaminated sediment difficult and greatly increases the amount of material that has to be removed and cleaned.
Landfill waste plays a smaller role at the site, because it is not nearly as toxic as the tar, nor is it as large of volume as the wood by-products. In many ways, the landfill waste plays a similar role to the wood by-products, in that they are both excess waste materials that will have to be extracted and cleaned before being processed.
The environmental effects of the pollutants are fairly straightforward in that they are all potentially harmful to nature. The toxic tar releases chemicals that cause imbalances in the water and in the air, as well as seeding the sediments with more heavy metals than inherently exist in them. This can have a detrimental effect on local flora and fauna as their systems have to deal with potentially increased toxicity. On the atmospheric side, VOCs and SVOCs contribute to ground-level ozone, smog, and generally lower the air quality in the region they are present, though the amount of VOCs and SVOCs released into the atmosphere is very low under current conditions at the site [8]
In this case, the ecology has yet to be greatly influenced by the presence of these chemicals, probably due to the layer of wood by-products and landfill waste piled on top. So far the only fauna to show a potential rise in toxicity is the rainbow smelt, but the results haven’t been verified yet. Otherwise, all game fish have been shown to be clean for consumption according with guidelines that were already in place. It is unknown at the moment if any species of terrestrial creatures are experiencing any increased toxicity. [9]
The largest biological effect that the chemical immediately has on the human body is the offensive smell and, if touched, a potential burning sensation and possible development of a rash. In the longer run, the VOCs, SVOCs, and heavy metals are all proven carcinogens, and should be avoided with care. [7]
There are numerous challenges that come along with the cleanup of any contaminated site. At this location, however, two unique geological figures further the challenges in subtle ways. First, the site sits over a large artesian aquifer, which is an underground spring that is pressurized but capped by a large sheet of impermeable clay. So, care must be taken in the cleanup process to not puncture that clay barrier and unleash the torrents of the spring, because it will create safety risks and most likely spread the contaminants farther and wider into the lake basins. [10] The second hurdle is that Lake Superior is the world’s largest freshwater lake. Meaning that once a chemical is dispersed into one part of the body of water, it will be near impossible to contain it there. So the removal must be swift and clean in its methods. [11]
As of early 2013, the parties involved are revolving around three main ideas to remediate sediment: wet dredging, dry dredging, or an engineered shoreline. Wet dredging is using a bucket or claw like scoop to bring up tons of sediment from the lake floor. In dry dredging, an artificial barrier is built around the region to be worked on, then pumped dry. Then workers scrape off the top layers, and when they're done they remove the barrier. The engineered shoreline remedy would involve wet dredging the sediments further from shore and placing them near-shore, creating new land for redevelopment of the waterfront. [6] The cost range of these plans is from $35 million to $77 million. [10]
As of early 2013, remediation of on-land contaminated areas is underway, and the parties involved are trying to determine the best, safest, and most cost-effective way to go about cleaning up the Ashland Lakefront Superfund site. [10] [12]
Toxic waste is any unwanted material in all forms that can cause harm. Many of today's household products such as televisions, computers and phones contain toxic chemicals that can pollute the air and contaminate soil and water. Disposing of such waste is a major public health issue.
Domtar Corporation is the largest integrated producer of uncoated free-sheet paper in North America and the second largest in the world based on production capacity, and is also a manufacturer of papergrade pulp.
Environmental remediation deals with the removal of pollution or contaminants from environmental media such as soil, groundwater, sediment, or surface water. This would mean that once requested by the government or a land remediation authority, immediate action should be taken as this can impact negatively on human health and the environment.
The Fox River is a river in eastern Wisconsin in the Great Lakes region of the United States. It is the principal tributary of the Bay of Green Bay, and via the Bay, the largest tributary of Lake Michigan. The well-known city of Green Bay, one of the first European settlements in North America, is on the river at its mouth on lower Green Bay.
Berry's Creek is a tributary of the Hackensack River in the New Jersey Meadowlands in Bergen County, New Jersey. The creek watershed contains a diverse array of wetlands, marshes, and wildlife. The creek runs through a densely populated region and has been subject to extensive industrial pollution during the 19th and 20th centuries. Several companies discharged toxic chemicals into the creek in the 20th century, and these chemicals have remained in the sediment. The creek has the highest concentrations of methyl mercury of any fresh-water sediment in the world. Portions of the creek watershed are Superfund sites and cleanup projects began in the late 20th century.
The Sydney Tar Ponds were a hazardous waste site on Cape Breton Island in Nova Scotia, Canada.
Lake Calumet is the largest body of water within the city of Chicago. Formerly a shallow, postglacial lake draining into Lake Michigan, it has been changed beyond recognition by industrial redevelopment and decay. Parts of the lake have been dredged, and other parts reshaped by landfill. Together with the rest of the city of Chicago, the remnant of the lake now drains into the Des Plaines River and the Mississippi River basin.
The Kin-Buc Landfill is a 220-acre (0.89 km2) Superfund site located in Edison, New Jersey where 70 million US gallons (260,000 m3) of liquid toxic waste and 1 million tons of solid waste were dumped. It was active from the late 1940s to 1976. Cleanup operations have been underway to address environmental issues with contamination from 1980s through to 2000s. This site was one of the largest superfund sites in New Jersey having taken in around 90 million US gallons (340,000 m3). The site is heavily contaminated with PCBs, which leaked into Edmonds Creek, a tributary of Raritan River.
The 120-acre (0.49 km2) Pfohl Brothers Landfill was a privately owned and operated landfill in Cheektowaga, New York. The landfill accepted municipal and industrial wastes from 1932 until 1971. It is located 1/2 mile east of the Buffalo Niagara International Airport and sits on the north bank of Ellicott Creek. It lies west of Transit Road and south of the New York State Thruway near Thruway Exit 49. It is bisected by Aero Drive.
Havertown Superfund refers to the polluted groundwater site in Havertown, Pennsylvania. While its designation as a Superfund cleanup site did not occur until the early 1990s, the site's environmental hazards had been identified as early as 1973.
In 1990, the Allied Paper, Inc./Portage Creek/Kalamazoo River in southwestern Michigan was declared by the Environmental Protection Agency (EPA) to be a Superfund site – in other words, an abandoned industrial site containing significant amounts of toxic waste. The EPA and companies responsible for the waste in this area, which includes a three-mile section of Portage Creek as well as part of the Kalamazoo River, into which it flows, are currently involved in an effort to reduce the amount of toxic waste at the site, which is contaminated by PCBs from paper mills and other factories.
The Lipari Landill is an inactive landfill on a 6-acre (2.4 ha) former gravel pit in Mantua Township, New Jersey, United States, that was used from 1958 to 1971 as a dump site for household and industrial wastes. Toxic organic compounds and heavy metals dumped at the site have percolated into the ground water and leached into lakes and streams in the surrounding area. The site has been identified as the worst toxic dump in the United States and was ranked at the top of the United States Environmental Protection Agency's Superfund eligibility list.
The former Operating Industries Inc. Landfill is a Superfund site located in Monterey Park, California at 900 N Potrero Grande Drive. From 1948 to 1984, the landfill accepted 30 million tons of solid municipal waste and 300 million US gallons (1,100,000 m3) of liquid chemicals. Accumulating over time, the chemical waste polluted the air, leached into groundwater, and posed a fire hazard, spurring severely critical public health complaints. Recognizing OII Landfill's heavy pollution, EPA placed the financial responsibility of the dump's clean-up on the main waste-contributing companies, winning hundreds of millions of dollars in settlements for the protection of human health and the environment.
The Koppers Co., Inc. (KCI) Superfund Site is one of three Superfund sites in Oroville, California, along with Louisiana Pacific Sawmill and Western Pacific Railyard. The KCI Superfund Site is a 200-acre site which served as a wood treatment plant for 50 years. Wood was treated with many chemicals to prevent wood deterioration. The accumulation of these chemicals from spills, fires, and uses has caused this site to be contaminated with the hazardous waste material. Due to soil and groundwater contamination, the site was placed on the National Priorities List in 1984 for remedial action plans to clean up the site to protect surrounding residential areas concerning environmental and human health risks.
Hocomonco Pond is a recreational pond located in Westborough, Massachusetts near Route 9. Also called Hobomoc Pond, it was named for Hobomok, a Wamesit Indian evil spirit. The pond and adjacent land are a Superfund site.
Between 1947 and 1977, General Electric polluted the Hudson River by discharging polychlorinated biphenyls (PCBs), causing a range of harmful effects to wildlife and people who eat fish from the river or drink the water. Other kinds of pollution, including mercury contamination and cities discharging untreated sewage, have also caused problems in the river.
The Newmark Groundwater Contamination Site is a Superfund site located at the base of the San Bernardino Mountains in Southern California. The contamination was discovered in 1980 and resulted in the closing of 20 water supply wells and intensive cleanup efforts in the following years. More than 25 percent of the San Bernardino municipal water supply has been affected by the water contamination since its discovery. The source of the contamination is attributed to a World War II Army landfill and depot, used from 1942 to 1947.
Emmell's Septic Landfill (ESL) is located at 128 Zurich Ave, Galloway Township, New Jersey and takes up about 38 acres of space. The landfill was in operation from 1967 until 1979. ESL disposed of liquid and solid waste including many chemicals such as volatile organic compounds (VOCs), Polychlorinated Biphenyls (PCBs), Trichloroethene and Vinyl chloride which all had their own effect on the environment and community. These chemicals affected the groundwater required millions of dollars to reconstruct the groundwater pathways and provide clean water to residents. The landfill holds a Hazardous Ranking Score of a 50/100, qualifying for the Superfund National Priority List. In August 1999, the state acknowledged the site's contamination and held town meetings and provided research upon the site such as groundwater samples. In July 1997, a sitewide investigation was called upon by the United States Environmental Protection Agency. In total the clean up was estimated to cost $5 million to fund this superfund site, and a grant of $3.9 million was given by the Federal Government under the Recovery Act Funding (Previti). Today, the project is still ongoing however, greatly improved since the landfill was discovered.
Bog Creek Farm, located in Howell Township, New Jersey, is a designated Environmental Protection Agency (EPA) Superfund site. Laying on 12 acres of land, Bog Creek Farm is home to several hazardous and life-threatening contamination beginning in 1973 and continuing for a year. Over a decade later, actions began to take place to clean and restore the contaminated soil and water. Bog Creek Farm is situated near several other farms that house horses, growing crops and flowers, and livestock. Less than a mile down the road lies Allaire State Park, a park used by golfers, hunters, and fisherman.
The Horseshoe Road Complex Superfund Site in Sayreville, New Jersey is a 12-acre property located near the Raritan River. The industrial site has been out of operation since the early 1980s after a fire revealed 70 drums containing silver cyanide, ethyl acetate, and acetonitrile. The drums caught the attention of the Environmental Protection Agency (EPA) and by 1995 the Horseshoe Road Complex was on the National Priorities List. The site had three areas consisting of the Atlantic Development Corporation (ADC), Horseshoe Road Drum Dump, and Sayreville Pesticide Dump. The neighboring Atlantic Resources Corporation, the location for precious metal recovery, is addressed with the Horseshoe Road Complex (HRC) site due to the intermixing of chemical contamination. The on-site contamination is not an immediate threat to the surrounding community, although prolonged or repeated exposure to the site itself, will result in health effects. The HRC Superfund site is now in its final steps of cleanup in accordance to the EPA's plan.
"Ashland Lakefront Project Background," Xcel Energy Website, Accessed April 2013
"Superfund Cleanup in Bay Debated," The Daily Press, Ashland Wisconsin, March 29, 2013
“Wastewater Treatment Plant Demolition,” The Daily Press, Ashland Wisconsin, April 23, 2013