| Rank | Match | Lane | Nation | Athletes | Result | Notes |
|---|
 | 4 | 2 |  Ukraine | Danylo Danylenko, Tetyana Melnyk, Stanislav Senyk, Anna Ryzhykova | 3:17.31 | |
 | 3 | 2 |  Czech Republic | Jan Tesař, Barbora Malíková, Lada Vondrová, Michal Desenský | 3:19.05 | |
 | 4 | 5 |  Portugal | Ricardo dos Santos, Cátia Azevedo, Rivinilda Mentai, João Coelho | 3:19.63 | |
| 4 | 4 | 6 |  Turkey | Yavuz Can, Emel Şanlı Kırcın, Derya Yıldırım, Batuhan Altıntaş | 3:20.31 | |
| 5 | 2 | 4 |  Slovenia | Luka Janežič, Anita Horvat, Lovro Mesec Košir, Jerneja Smonkar | 3:20.66 | |
| 6 | 2 | 5 |  Russia | Timofey Chalyy, Vyacheslav Kolesnichenko, Polina Miller, Vera Rudakova | 3:21.02 | |
| 7 | 2 | 2 |  France | Loïc Naprix, Jean Bertin, Farah Clerc, Lénora Guion-Firmin | 3:21.08 | |
| 8 | 1 | 4 |  Germany | Arne Leppelsack, Maximilian Grupen, Karolina Pahlitzsch, Corinna Schwab | 3:21.90 | |
| 9 | 1 | 2 |  Slovakia | Martin Kučera, Šimon Bujna, Daniela Ledecká, Alexandra Štuková | 3:22.65 | |
| 10 | 3 | 7 |  Belarus | Ihar Zubko, Krystsina Muliarchyk, Aliaksei Lazarau, Yuliya Kastsiuchkova | 3:22.74 | |
| 11 | 4 | 7 |  Spain | Alberto Gavaldá, Gen Esteban San Millán, Bárbara Camblor, Carmen Sánchez | 3:22.99 | |
| 12 | 2 | 6 |  Italy | Francesco Cappellin, Eusebio Haliti, Marta Milani, Ylenia Vitale | 3:23.19 | |
| 13 | 3 | 3 |  Lithuania | Rokas Pacevičius, Modesta Justė Morauskaitė, Artūras Janauskas, Erika Krūminaitė | 3:23.75 | |
| 14 | 1 | 7 |  Greece | Antonios Alexandridis, Elpida-Ioanna Karkalatou, Despoina Mourta, Panagiotis Trivyzas | 3:24.26 | |
| 15 | 3 | 5 |  Ireland | Brandon Arrey, Sinead Denny, Catherine McManus, Andrew Mellon | 3:24.37 | |
| 16 | 1 | 3 |  Switzerland | Luca Flück, Joel Burgunder, Daniela Kyburz, Rachel Pellaud | 3:24.82 | |
| 17 | 2 | 7 |  Estonia | Helin Meier, Jaak-Heinrich Jagor, Marek Niit, Liis Roose | 3:25.88 | |
| 18 | 2 | 3 |  Romania | Cristian Radu, Cristina Bălan, Sanda Belgyan, Mihai Pislaru | 3:25.96 | |
| 19 | 1 | 6 |  Hungary | Boldizsár Boda, Evelin Nádházy, Virág Simon, Balázs Vindics | 3:26.12 | |
| 20 | 4 | 4 |  Denmark | Gustav Lundholm Nielsen, Emma Bomme, Benjamin Lobo Vedel, Zarah Buchwald | 3:27.68 | |
| 21 | 4 | 3 |  Bulgaria | Zhivko Stoyanov, Kristina Borukova, Nikolay Georgiev, Liliyana Georgieva | 3:29.25 | |
| 22 | 3 | 4 |  Latvia | Iļja Petrušenko, Austris Karpinskis, Marija Medvedeva, Patrīcija Sarmule | 3:30.40 | |
| 23 | 3 | 6 |  Poland | Aleksandra Lubicka, Bartłomiej Czajkowski, Mariola Karaś, Bartosz Rożnowski | 3:31.60 | |
| 24 | 1 | 5 |  Cyprus | Stavros Spyrou, Konstantinos Christou, Christiana Katsari, Kalliopi Kountouri | 3:32.61 | |
