In a chemical reaction, chemical equilibrium is the state in which both the reactants and products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the system. This state results when the forward reaction proceeds at the same rate as the reverse reaction. The reaction rates of the forward and backward reactions are generally not zero, but they are equal. Thus, there are no net changes in the concentrations of the reactants and products. Such a state is known as dynamic equilibrium.
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities of the chemical species undergoing reduction and oxidation respectively. It was named after Walther Nernst, a German physical chemist who formulated the equation.
Evapotranspiration (ET) is the combined processes by which water moves from the earth's surface into the atmosphere. It covers both water evaporation and transpiration. Evapotranspiration is an important part of the local water cycle and climate, and measurement of it plays a key role in agricultural irrigation and water resource management.
In thermodynamics, the Joule–Thomson effect describes the temperature change of a real gas or liquid when it is forced through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment. This procedure is called a throttling process or Joule–Thomson process. At room temperature, all gases except hydrogen, helium, and neon cool upon expansion by the Joule–Thomson process when being throttled through an orifice; these three gases experience the same effect but only at lower temperatures. Most liquids such as hydraulic oils will be warmed by the Joule–Thomson throttling process.
In thermodynamics and fluid mechanics, the compressibility is a measure of the instantaneous relative volume change of a fluid or solid as a response to a pressure change. In its simple form, the compressibility may be expressed as
In chemical thermodynamics, activity is a measure of the "effective concentration" of a species in a mixture, in the sense that the species' chemical potential depends on the activity of a real solution in the same way that it would depend on concentration for an ideal solution. The term "activity" in this sense was coined by the American chemist Gilbert N. Lewis in 1907.
In physical chemistry, Henry's law is a gas law that states that the amount of dissolved gas in a liquid is directly proportional to its partial pressure above the liquid. The proportionality factor is called Henry's law constant. It was formulated by the English chemist William Henry, who studied the topic in the early 19th century.
Potential evaporation (PE) or potential evapotranspiration (PET) is defined as the amount of evaporation that would occur if a sufficient water source were available. If the actual evapotranspiration is considered the net result of atmospheric demand for moisture from a surface and the ability of the surface to supply moisture, then PET is a measure of the demand side. Surface and air temperatures, insolation, and wind all affect this. A dryland is a place where annual potential evaporation exceeds annual precipitation.
The Penman equation describes evaporation (E) from an open water surface, and was developed by Howard Penman in 1948. Penman's equation requires daily mean temperature, wind speed, air pressure, and solar radiation to predict E. Simpler Hydrometeorological equations continue to be used where obtaining such data is impractical, to give comparable results within specific contexts, e.g. humid vs arid climates.
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. In an ideal mixture, the microscopic interactions between each pair of chemical species are the same and, as a result, properties of the mixtures can be expressed directly in terms of simple concentrations or partial pressures of the substances present e.g. Raoult's law. Deviations from ideality are accommodated by modifying the concentration by an activity coefficient. Analogously, expressions involving gases can be adjusted for non-ideality by scaling partial pressures by a fugacity coefficient.
Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions.
Ecohydrology is an interdisciplinary scientific field studying the interactions between water and ecological systems. It is considered a sub discipline of hydrology, with an ecological focus. These interactions may take place within water bodies, such as rivers and lakes, or on land, in forests, deserts, and other terrestrial ecosystems. Areas of research in ecohydrology include transpiration and plant water use, adaption of organisms to their water environment, influence of vegetation and benthic plants on stream flow and function, and feedbacks between ecological processes, the soil carbon sponge and the hydrological cycle.
Infiltration is the process by which water on the ground surface enters the soil. It is commonly used in both hydrology and soil sciences. The infiltration capacity is defined as the maximum rate of infiltration. It is most often measured in meters per day but can also be measured in other units of distance over time if necessary. The infiltration capacity decreases as the soil moisture content of soils surface layers increases. If the precipitation rate exceeds the infiltration rate, runoff will usually occur unless there is some physical barrier.
An atmometer or evaporimeter is a scientific instrument used for measuring the rate of water evaporation from a wet surface to the atmosphere. Atmometers are mainly used by farmers and growers to measure evapotranspiration (ET) rates of crops at any field location. Evapotranspiration is a measure of all of the water that evaporates from land surfaces plus the water that transpires from plant surfaces. Based on the amount of water that does evaporate and transpire, the user can water crops correspondingly, which results in less water use and possibly increased crop yields. Companies that currently sell atmometers include C&M Meteorological Supply and Calsense.
The wet-bulb temperature (WBT) is the temperature read by a thermometer covered in water-soaked cloth over which air is passed. At 100% relative humidity, the wet-bulb temperature is equal to the air temperature ; at lower humidity the wet-bulb temperature is lower than dry-bulb temperature because of evaporative cooling.
An aridity index (AI) is a numerical indicator of the degree of dryness of the climate at a given location. The American Meteorological Society defined it in meteorology and climatology, as "the degree to which a climate lacks effective, life-promoting moisture". Aridity is different from drought because aridity is permanent whereas drought is temporary. A number of aridity indices have been proposed ; these indicators serve to identify, locate or delimit regions that suffer from a deficit of available water, a condition that can severely affect the effective use of the land for such activities as agriculture or stock-farming.
The Penman–Monteith equation approximates net evapotranspiration (ET) from meteorological data, as a replacement for direct measurement of evapotranspiration. The equation is widely used, and was derived by the United Nations Food and Agriculture Organization for modeling potential evapotranspiration ET0.
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity is defined scientifically as a force multiplied by a time divided by an area. Thus its SI units are newton-seconds per square metre, or pascal-seconds.
Breeding for drought resistance is the process of breeding plants with the goal of reducing the impact of dehydration on plant growth.
BAITSSS is biophysical Evapotranspiration (ET) computer model that determines water use, primarily in agriculture landscape, using remote sensing-based information. It was developed and refined by Ramesh Dhungel and the water resources group at University of Idaho's Kimberly Research and Extension Center since 2010. It has been used in different areas in the United States including Southern Idaho, Northern California, northwest Kansas, Texas, and Arizona.
