Flow-accelerated corrosion

Last updated

Flow-accelerated corrosion (FAC), also known as flow-assisted corrosion, is a corrosion mechanism in which a normally protective oxide layer on a metal surface dissolves in a fast flowing water. The underlying metal corrodes to re-create the oxide, and thus the metal loss continues.

Contents

By definition, the rate of FAC depends on the flow velocity. FAC often affects carbon steel piping carrying ultra-pure, deoxygenated water or wet steam. Stainless steel does not suffer from FAC. FAC of carbon steel halts in the presence of small amount of oxygen dissolved in water. FAC rates rapidly decrease with increasing water pH.

FAC has to be distinguished from erosion corrosion because the fundamental mechanisms for the two corrosion modes are different. FAC does not involve impingement of particles, bubbles, or cavitation which cause the mechanical (often crater-like) wear on the surface. By contrast to mechanical erosion, FAC involves dissolution of normally poorly soluble oxide by combined electrochemical, water chemistry and mass-transfer phenomena. Nevertheless, the terms FAC and erosion are sometimes used interchangeably because the actual mechanism may, in some cases, be unclear.

FAC was the cause of several high-profile accidents in power plants, for example, a rupture of a high-pressure condensate line in Virginia Power's Surry nuclear plant in 1986, that resulted in four fatalities and four injuries.

See also

Related Research Articles

Rust Type of iron oxide

Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture. Rust consists of hydrous iron(III) oxides (Fe2O3·nH2O) and iron(III) oxide-hydroxide (FeO(OH), Fe(OH)3), and is typically associated with the corrosion of refined iron.

Weathering Deterioration of rocks and minerals through exposure to the elements

Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs in situ, and so is distinct from erosion, which involves the transport of rocks and minerals by agents such as water, ice, snow, wind, waves and gravity.

Corrosion Gradual destruction of materials by chemical reaction with its environment

Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual destruction of materials by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.

Heat treating Process of heating something to alter it

Heat treating is a group of industrial, thermal and metalworking processes used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgical. Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, to achieve the desired result such as hardening or softening of a material. Heat treatment techniques include annealing, case hardening, precipitation strengthening, tempering, carburizing, normalizing and quenching. Although the term heat treatment applies only to processes where the heating and cooling are done for the specific purpose of altering properties intentionally, heating and cooling often occur incidentally during other manufacturing processes such as hot forming or welding.

Brazing High-temperature soldering; metal-joining technique by high-temperature molten metal filling

Brazing is a metal-joining process in which two or more metal items are joined together by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal.

Wear Damaging, gradual removal or deformation of material at solid surfaces

Wear is the damaging, gradual removal or deformation of material at solid surfaces. Causes of wear can be mechanical or chemical. The study of wear and related processes is referred to as tribology.

Flux (metallurgy)

In metallurgy, a flux is a chemical cleaning agent, flowing agent, or purifying agent. Fluxes may have more than one function at a time. They are used in both extractive metallurgy and metal joining.

Galling Form of wear caused by adhesion between sliding surfaces

Galling is a form of wear caused by adhesion between sliding surfaces. When a material galls, some of it is pulled with the contacting surface, especially if there is a large amount of force compressing the surfaces together. Galling is caused by a combination of friction and adhesion between the surfaces, followed by slipping and tearing of crystal structure beneath the surface. This will generally leave some material stuck or even friction welded to the adjacent surface, whereas the galled material may appear gouged with balled-up or torn lumps of material stuck to its surface.

Pitting corrosion Form of insidious localized corrosion in which a pit develops at the anode site

Pitting corrosion, or pitting, is a form of extremely localized corrosion that leads to the random creation of small holes in metal. The driving power for pitting corrosion is the depassivation of a small area, which becomes anodic while an unknown but potentially vast area becomes cathodic, leading to very localized galvanic corrosion. The corrosion penetrates the mass of the metal, with a limited diffusion of ions.

The Faraday paradox was a once inexplicable aspect of the reaction between nitric acid and steel. Around 1830, the English scientist Michael Faraday found that diluted nitric acid would attack steel, but concentrated nitric acid would not. The attempt to explain this discovery led to advances in electrochemistry.

Fouling Accumulation of unwanted material on solid surfaces

Fouling is the accumulation of unwanted material on solid surfaces. The fouling materials can consist of either living organisms (biofouling) or a non-living substance. Fouling is usually distinguished from other surface-growth phenomena in that it occurs on a surface of a component, system, or plant performing a defined and useful function and that the fouling process impedes or interferes with this function.

Intergranular corrosion

Intergranular corrosion (IGC), also known as intergranular attack (IGA), is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides.

Erosion corrosion, also known as impingement damage, is the combined effect of corrosion and erosion caused by rapid flowing turbulent water. It is probably the second most common cause of copper tube failures behind Type 1 pitting which is also known as Cold Water Pitting of Copper Tube.

Radiation damage is the effect of ionizing radiation on physical objects including non-living structural materials. It can be either detrimental or beneficial for materials.

Crevice corrosion refers to corrosion occurring in occluded spaces such as interstices in which a stagnant solution is trapped and not renewed. These spaces are generally called crevices. Examples of crevices are gaps and contact areas between parts, under gaskets or seals, inside cracks and seams, spaces filled with deposits and under sludge piles.

Erosion corrosion is a degradation of material surface due to mechanical action, often by impinging liquid, abrasion by a slurry, particles suspended in fast flowing liquid or gas, bubbles or droplets, cavitation, etc. The mechanism can be described as follows:

Corrosion engineering is an engineering specialty that applies scientific, technical, engineering skills, and knowledge of natural laws and physical resources to design and implement materials, structures, devices, systems, and procedures to manage corrosion. From a holistic perspective, corrosion is the phenomenon of metals returning to the state they are found in nature. The driving force that causes metals to corrode is a consequence of their temporary existence in metallic form. To produce metals starting from naturally occurring minerals and ores, it is necessary to provide a certain amount of energy, e.g. Iron ore in a blast furnace. It is therefore thermodynamically inevitable that these metals when exposed to various environments would revert to their state found in nature. Corrosion and corrosion engineering thus involves a study of chemical kinetics, thermodynamics, electrochemistry and Materials science.

Tribocorrosion Material degradation due to corrosion and wear.

Tribocorrosion is a material degradation process due to the combined effect of corrosion and wear. The name tribocorrosion expresses the underlying disciplines of tribology and corrosion. Tribology is concerned with the study of friction, lubrication and wear and corrosion is concerned with the chemical and electrochemical interactions between a material, normally a metal, and its environment. As a field of research tribocorrosion is relatively new, but tribocorrosion phenomena have been around ever since machines and installations are being used.

Concrete degradation Damage to concrete affecting its mechanical strength and its durability

Concrete degradation may have many different causes. Concrete is mostly damaged by the corrosion of reinforcement bars due to the carbonatation of hardened cement paste or chloride attack under wet conditions. Chemical damages are caused by the formation of expansive products produced by various chemical reactions, by aggressive chemical species present in groundwater and seawater, or by microorganisms. Other damaging processes can also involve calcium leaching by water infiltration and different physical phenomena initiating cracks formation and propagation. All these detrimental processes and damaging agents adversely affects the concrete mechanical strength and its durability.

Galvanic corrosion Electrochemical process

Galvanic corrosion is an electrochemical process in which one metal corrodes preferentially when it is in electrical contact with another, in the presence of an electrolyte. A similar galvanic reaction is exploited in primary cells to generate a useful electrical voltage to power portable devices.

References

    Further reading