A framboid is a micromorphological feature common to certain sedimentary minerals, particularly pyrite (FeS2). The first known use of the term is ascribed to Rust in 1935 and is derived from the French 'framboise', meaning 'raspberry', reflecting the appearance of the structure under magnification.
Framboidal structure comprises roughly spherical aggregates of discrete equi-regular euhedral microcrystallites of around 0.5 μm in diameter, with the average aggregate size ranging from 5-20 μm. Framboid diameter tends to correlate positively with microcrystal size, and microcrystal packing is most commonly irregular and disordered. Framboids were once thought to be a fossilised bacterial colonies or microorganisms, but successful synthesis of this structure under laboratory conditions and observation of framboids in locations hostile to microbial life have discounted this theory.
Framboidal pyrite is commonly found in coastal sediments, for instance marsh soils, marine and estuarine sediments, and beach sands. It can also be observed in coal as well as magmatic and carbonate rocks. Other minerals known to exhibit framboidal structures include magnetite, hematite, and greigite. Greigite is considered an essential precursor of framboidal pyrite formation.
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, Al2Si2O5(OH)4).
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles to settle in place. The particles that form a sedimentary rock are called sediment, and may be composed of geological detritus (minerals) or biological detritus. The geological detritus originated from weathering and erosion of existing rocks, or from the solidification of molten lava blobs erupted by volcanoes. The geological detritus is transported to the place of deposition by water, wind, ice or mass movement, which are called agents of denudation. Biological detritus was formed by bodies and parts of dead aquatic organisms, as well as their fecal mass, suspended in water and slowly piling up on the floor of water bodies. Sedimentation may also occur as dissolved minerals precipitate from water solution.
The mineral pyrite ( PY-ryte), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula FeS2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Goethite is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the α-polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient times for its use as a pigment. Evidence has been found of its use in paint pigment samples taken from the caves of Lascaux in France. It was first described in 1806 based on samples found in the Hollertszug Mine in Herdorf, Germany. The mineral was named after the German polymath and poet Johann Wolfgang von Goethe (1749–1832).
Silt is granular material of a size between sand and clay and composed mostly of broken grains of quartz. Silt may occur as a soil or as sediment mixed in suspension with water. Silt usually has a floury feel when dry, and lacks plasticity when wet. Silt also can be felt by the tongue as granular when placed on the front teeth.
A concretion is a hard, compact mass formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular shapes also occur. The word 'concretion' is derived from the Latin concretio "(act of) compacting, condensing, congealing, uniting", itself from con meaning 'together' and crescere meaning "to grow". Concretions form within layers of sedimentary strata that have already been deposited. They usually form early in the burial history of the sediment, before the rest of the sediment is hardened into rock. This concretionary cement often makes the concretion harder and more resistant to weathering than the host stratum.
The mineral marcasite, sometimes called "white iron pyrite", is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both structures contain the disulfide S22− ion, having a short bonding distance between the sulfur atoms. The structures differ in how these di-anions are arranged around the Fe2+ cations. Marcasite is lighter and more brittle than pyrite. Specimens of marcasite often crumble and break up due to the unstable crystal structure.
Magnetotactic bacteria are a polyphyletic group of bacteria that orient themselves along the magnetic field lines of Earth's magnetic field. Discovered in 1963 by Salvatore Bellini and rediscovered in 1975 by Richard Blakemore, this alignment is believed to aid these organisms in reaching regions of optimal oxygen concentration. To perform this task, these bacteria have organelles called magnetosomes that contain magnetic crystals. The biological phenomenon of microorganisms tending to move in response to the environment's magnetic characteristics is known as magnetotaxis. However, this term is misleading in that every other application of the term taxis involves a stimulus-response mechanism. In contrast to the magnetoreception of animals, the bacteria contain fixed magnets that force the bacteria into alignment—even dead cells are dragged into alignment, just like a compass needle.
Soil chemistry is the study of the chemical characteristics of soil. Soil chemistry is affected by mineral composition, organic matter and environmental factors. In the early 1870s a consulting chemist to the Royal Agricultural Society in England, named J. Thomas Way, performed many experiments on how soils exchange ions, and is considered the father of soil chemistry. Other scientists who contributed to this branch of ecology include Edmund Ruffin, and Linus Pauling.
Acid sulfate soils are naturally occurring soils, sediments or organic substrates that are formed under waterlogged conditions. These soils contain iron sulfide minerals and/or their oxidation products. In an undisturbed state below the water table, acid sulfate soils are benign. However, if the soils are drained, excavated or otherwise exposed to air, the sulfides react with oxygen to form sulfuric acid.
The pore space of soil contains the liquid and gas phases of soil, i.e., everything but the solid phase that contains mainly minerals of varying sizes as well as organic compounds.
Mackinawite is an iron nickel sulfide mineral with the chemical formula (Fe,Ni)
1+xS. The mineral crystallizes in the tetragonal crystal system and has been described as a distorted, close packed, cubic array of S atoms with some of the gaps filled with Fe. Mackinawite occurs as opaque bronze to grey-white tabular crystals and anhedral masses. It has a Mohs hardness of 2.5 and a specific gravity of 4.17. It was first described in 1962 for an occurrence in the Mackinaw mine, Snohomish County, Washington for which it was named.
Martian soil is the fine regolith found on the surface of Mars. Its properties can differ significantly from those of terrestrial soil, including its toxicity due to the presence of perchlorates. The term Martian soil typically refers to the finer fraction of regolith. So far, no samples have been returned to Earth, the goal of a Mars sample-return mission, but the soil has been studied remotely with the use of Mars rovers and Mars orbiters.
Microspherulites are microscopic spherical particles with diameter less than two mm, usually in the 100 micrometre range, mainly consisting of mineral material. Only bodies created by natural physico-chemical processes, with no contribution of either biological or human activity, are considered to be microspherulites. Generally speaking, the common feature (sphericity) indicates that each sphere represents an internal equilibrium of forces within a fluid medium.
Green rust is a generic name for various green crystalline chemical compounds containing iron(II) and iron(III) cations, the hydroxide (HO−
) anion, and another anion such as carbonate (CO2−
3), chloride (Cl−
), or sulfate (SO2−
4), in a layered double hydroxide structure. The most studied varieties are
Iron-rich sedimentary rocks are sedimentary rocks which contain 15 wt.% or more iron. However, most sedimentary rocks contain iron in varying degrees. The majority of these rocks were deposited during specific geologic time periods: The Precambrian, the early Paleozoic, and the middle to late Mesozoic. Overall, they make up a very small portion of the total sedimentary record.
Iron(II,III) sulfide is a blue-black (sometimes pinkish) chemical compound of iron and sulfur with formula Fe3S4 or FeS·Fe2S3, which is much similar to iron(II,III) oxide. It occurs naturally as the sulfide mineral greigite and is magnetic. It is a bio-mineral produced by and found in magnetotactic bacteria. It is a mixed valence compound, featuring both Fe2+ and Fe3+ centers, in 1:2 ratio.
Particulate organic matter (POM) is a fraction of total organic matter operationally defined as that which does not pass through a filter pore size that typically ranges in size from 0.053 millimeters (53 μm) to 2 millimeters.
Soil aggregate stability is a measure of the ability of soil aggregates—soil particles that bind together—to resist breaking apart when exposed to external forces such as water erosion and wind erosion, shrinking and swelling processes, and tillage. Soil aggregate stability is a measure of soil structure and can be affected by soil management.