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Levinson's theorem is an important theorem in non-relativistic quantum scattering theory. It relates the number of bound states of a potential to the difference in phase of a scattered wave at zero and infinite energies. It was published by Norman Levinson in 1949. [1]
The difference in the -wave phase shift of a scattered wave at zero energy, , and infinite energy, , for a spherically symmetric potential is related to the number of bound states by:
where or . The case is exceptional and it can only happen in -wave scattering. The following conditions are sufficient to guarantee the theorem: [2]
In physics, the cross section is a measure of the probability that a specific process will take place when some kind of radiant excitation intersects a localized phenomenon. For example, the Rutherford cross-section is a measure of probability that an alpha particle will be deflected by a given angle during a collision with an atomic nucleus. Cross section is typically denoted σ (sigma) and is expressed in units of area, more specifically in barns. In a way, it can be thought of as the size of the object that the excitation must hit in order for the process to occur, but more exactly, it is a parameter of a stochastic process.
A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen constitutes about 75% of the baryonic mass of the universe.
In mathematics, the Dirac delta distribution, also known as the unit impulse, is a generalized function or distribution over the real numbers, whose value is zero everywhere except at zero, and whose integral over the entire real line is equal to one.
Noether's theorem or Noether's first theorem states that every differentiable symmetry of the action of a physical system with conservative forces has a corresponding conservation law. The theorem was proven by mathematician Emmy Noether in 1915 and published in 1918. The action of a physical system is the integral over time of a Lagrangian function, from which the system's behavior can be determined by the principle of least action. This theorem only applies to continuous and smooth symmetries over physical space.
In mathematical logic, the compactness theorem states that a set of first-order sentences has a model if and only if every finite subset of it has a model. This theorem is an important tool in model theory, as it provides a useful method for constructing models of any set of sentences that is finitely consistent.
In probability theory, the law of large numbers (LLN) is a theorem that describes the result of performing the same experiment a large number of times. According to the law, the average of the results obtained from a large number of trials should be close to the expected value and tends to become closer to the expected value as more trials are performed.
The path integral formulation is a description in quantum mechanics that generalizes the action principle of classical mechanics. It replaces the classical notion of a single, unique classical trajectory for a system with a sum, or functional integral, over an infinity of quantum-mechanically possible trajectories to compute a quantum amplitude.
An important problem in quantum mechanics is that of a particle in a spherically symmetric potential, i.e., a potential that depends only on the distance between the particle and a defined center point. In particular, if the particle in question is an electron and the potential is derived from Coulomb's law, then the problem can be used to describe a hydrogen-like (one-electron) atom.
Geometrical optics, or ray optics, is a model of optics that describes light propagation in terms of rays. The ray in geometric optics is an abstraction useful for approximating the paths along which light propagates under certain circumstances.
In the theory of stochastic processes, the Karhunen–Loève theorem, also known as the Kosambi–Karhunen–Loève theorem is a representation of a stochastic process as an infinite linear combination of orthogonal functions, analogous to a Fourier series representation of a function on a bounded interval. The transformation is also known as Hotelling transform and eigenvector transform, and is closely related to principal component analysis (PCA) technique widely used in image processing and in data analysis in many fields.
A multipole expansion is a mathematical series representing a function that depends on angles—usually the two angles used in the spherical coordinate system for three-dimensional Euclidean space, . Similarly to Taylor series, multipole expansions are useful because oftentimes only the first few terms are needed to provide a good approximation of the original function. The function being expanded may be real- or complex-valued and is defined either on , or less often on for some other .
In mathematics, the Riesz–Fischer theorem in real analysis is any of a number of closely related results concerning the properties of the space L2 of square integrable functions. The theorem was proven independently in 1907 by Frigyes Riesz and Ernst Sigismund Fischer.
Møller–Plesset perturbation theory (MP) is one of several quantum chemistry post–Hartree–Fock ab initio methods in the field of computational chemistry. It improves on the Hartree–Fock method by adding electron correlation effects by means of Rayleigh–Schrödinger perturbation theory (RS-PT), usually to second (MP2), third (MP3) or fourth (MP4) order. Its main idea was published as early as 1934 by Christian Møller and Milton S. Plesset.
In mathematics, especially functional analysis, a Fréchet algebra, named after Maurice René Fréchet, is an associative algebra over the real or complex numbers that at the same time is also a Fréchet space. The multiplication operation for is required to be jointly continuous. If is an increasing family of seminorms for the topology of , the joint continuity of multiplication is equivalent to there being a constant and integer for each such that for all . Fréchet algebras are also called B0-algebras.
In physics, Hamilton's principle is William Rowan Hamilton's formulation of the principle of stationary action. It states that the dynamics of a physical system are determined by a variational problem for a functional based on a single function, the Lagrangian, which may contain all physical information concerning the system and the forces acting on it. The variational problem is equivalent to and allows for the derivation of the differential equations of motion of the physical system. Although formulated originally for classical mechanics, Hamilton's principle also applies to classical fields such as the electromagnetic and gravitational fields, and plays an important role in quantum mechanics, quantum field theory and criticality theories.
The Sokhotski–Plemelj theorem is a theorem in complex analysis, which helps in evaluating certain integrals. The real-line version of it is often used in physics, although rarely referred to by name. The theorem is named after Julian Sochocki, who proved it in 1868, and Josip Plemelj, who rediscovered it as a main ingredient of his solution of the Riemann–Hilbert problem in 1908.
The electric dipole moment is a measure of the separation of positive and negative electrical charges within a system, that is, a measure of the system's overall polarity. The SI unit for electric dipole moment is the coulomb-meter (C⋅m). The debye (D) is another unit of measurement used in atomic physics and chemistry.
In mathematics, the small boundary property is a property of certain topological dynamical systems. It is dynamical analog of the inductive definition of Lebesgue covering dimension zero.
In representation theory of mathematics, the Waldspurger formula relates the special values of two L-functions of two related admissible irreducible representations. Let k be the base field, f be an automorphic form over k, π be the representation associated via the Jacquet–Langlands correspondence with f. Goro Shimura (1976) proved this formula, when and f is a cusp form; Günter Harder made the same discovery at the same time in an unpublished paper. Marie-France Vignéras (1980) proved this formula, when and f is a newform. Jean-Loup Waldspurger, for whom the formula is named, reproved and generalized the result of Vignéras in 1985 via a totally different method which was widely used thereafter by mathematicians to prove similar formulas.
In the mathematical discipline of ergodic theory, a Sinai–Ruelle–Bowen (SRB) measure is an invariant measure that behaves similarly to, but is not an ergodic measure. In order to be ergodic, the time average would need to be equal the space average for almost all initial states , with being the phase space. For an SRB measure , it suffices that the ergodicity condition be valid for initial states in a set of positive Lebesgue measure.
