Limiting oxygen index

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The limiting oxygen index (LOI) is the minimum concentration of oxygen, expressed as a percentage, that will support combustion of a polymer. It is measured by passing a mixture of oxygen and nitrogen over a burning specimen, and reducing the oxygen level until a critical level is reached. [1]

Oxygen Chemical element with atomic number 8

Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group on the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. By mass, oxygen is the third-most abundant element in the universe, after hydrogen and helium. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula O
2
. Diatomic oxygen gas constitutes 20.8% of the Earth's atmosphere. As compounds including oxides, the element makes up almost half of the Earth's crust.

Combustion high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized in a mixture termed as smoke

Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion in a fire produces a flame, and the heat produced can make combustion self-sustaining. Combustion is often a complicated sequence of elementary radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that incandescent light in the form of either glowing or a flame is produced. A simple example can be seen in the combustion of hydrogen and oxygen into water vapor, a reaction commonly used to fuel rocket engines. This reaction releases 242 kJ/mol of heat and reduces the enthalpy accordingly :

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LOI values for different plastics are determined by standardized tests, such as the ISO 4589 and ASTM D2863. [2]

The LOI value is also dependent on the surrounding temperature of the sample. The percent of oxygen required for combustion reduces as the surrounding temperature is increased.

Plastics and cable material is tested for its LOI value at both ambient temperature and elevated temperature to understand its oxygen requirement under actual fire conditions.

Materials with an LOI greater than the atmospheric oxygen concentration are called fire retardant materials. [3]

See also

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References

  1. Definition taken from Principles of Polymer Engineering (2nd edition) by N.G. McCrum , C.P. Buckley, and C.B. Bucknall
  2. ASTM D 2863, Standard Test Method for Measuring the Minimum Oxygen Concentration to Support Candle-Like Combustion of Plastics (Oxygen Index).
  3. "Fire-retardant materials". www.ias.ac.in. Retrieved 2019-01-11.