Heat exchangers typically used to provide heat to the bottom of industrial distillation columns
Reboilers are heat exchangers typically used to provide heat to the bottom of industrial distillation columns. They boil the liquid from the bottom of a distillation column to generate vapors which are returned to the column to drive the distillation separation. The heat supplied to the column by the reboiler at the bottom of the column is removed by the condenser at the top of the column.
Proper reboiler operation is vital to effective distillation. In a typical classical distillation column, all the vapor driving the separation comes from the reboiler. The reboiler receives a liquid stream from the column bottom and may partially or completely vaporize that stream. Steam usually provides the heat required for the vaporization.
Types of reboilers
The most critical element of reboiler design is the selection of the proper type of reboiler for a specific service. Most reboilers are of the shell and tube heat exchanger type and normally steam is used as the heat source in such reboilers. However, other heat transfer fluids like hot oil or Dowtherm (TM) may be used. Fuel-fired furnaces may also be used as reboilers in some cases.
Commonly used heat exchanger type reboilers are:
Image 1: Typical steam-heated kettle reboiler for distillation towers
Kettle Type reboilers
Kettle reboilers (Image 1) are very simple and reliable. they are similar to shell and tube type heat exchangers. They may require pumping of the column bottoms liquid into the kettle, or there may be sufficient liquid head to deliver the liquid into the reboiler. In this reboiler type, steam flows through the tube bundle and exits as condensate. The liquid from the bottom of the tower, commonly called the bottoms, flows through the shell side. There is a retaining wall or overflow weir separating the tube bundle from the reboiler section where the residual reboiled liquid (called the bottoms product) is withdrawn, so that the tube bundle is kept covered with liquid and reduce the amount of low-boiling compounds in the bottoms product.
Image 2: Typical horizontal thermosyphon reboiler
Thermosyphon reboilers
Thermosyphon reboilers (Image 2) do not require pumping of the column bottoms liquid into the reboiler. Natural circulation is obtained by using the density difference between the reboiler inlet column bottoms liquid and the reboiler outlet liquid-vapor mixture to provide sufficient liquid head to deliver the tower bottoms into the reboiler. Thermosyphon reboilers (also known as calandrias) are more complex than kettle reboilers and require more attention from the plant operators. There are many types of thermosyphon reboilers including vertical, horizontal, once-through or recirculating.
Fired reboiler
Fired heaters (Image 3), also known as furnaces, may be used as a distillation column reboiler. A pump is required to circulate the column bottoms through the heat transfer tubes in the furnace's convection and radiant sections. The heat source for the fired heater reboiler may be either fuel gas or fuel oil.
Image 4: Typical steam-heated forced circulation reboiler for distillation towers
Forced circulation reboilers
A forced circulation reboiler (Image 4) uses a pump to circulate the column bottoms liquid through the reboilers. This is useful if the reboiler must be located far from the column, or if the bottoms product is extremely viscous.
Some fluids are temperature sensitive such as those subject to polymerization by contact with high temperature heat transfer tube walls. High liquid recirculation rates are used to reduce tube wall temperatures, thereby reducing polymerization on the tube and associated fouling.
Distillation, also classical distillation, is the process of separating the component substances of a liquid mixture of two or more chemically discrete substances; the separation process is realized by way of the selective boiling of the mixture and the condensation of the vapors in a still.
A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct contact. They are widely used in space heating, refrigeration, air conditioning, power stations, chemical plants, petrochemical plants, petroleum refineries, natural-gas processing, and sewage treatment. The classic example of a heat exchanger is found in an internal combustion engine in which a circulating fluid known as engine coolant flows through radiator coils and air flows past the coils, which cools the coolant and heats the incoming air. Another example is the heat sink, which is a passive heat exchanger that transfers the heat generated by an electronic or a mechanical device to a fluid medium, often air or a liquid coolant.
A boiler is a closed vessel in which fluid is heated. The fluid does not necessarily boil. The heated or vaporized fluid exits the boiler for use in various processes or heating applications, including water heating, central heating, boiler-based power generation, cooking, and sanitation.
Fractional distillation is the separation of a mixture into its component parts, or fractions. Chemical compounds are separated by heating them to a temperature at which one or more fractions of the mixture will vaporize. It uses distillation to fractionate. Generally the component parts have boiling points that differ by less than 25 °C (45 °F) from each other under a pressure of one atmosphere. If the difference in boiling points is greater than 25 °C, a simple distillation is typically used.
A fractionating column or fractional column is equipment used in the distillation of liquid mixtures to separate the mixture into its component parts, or fractions, based on their differences in volatility. Fractionating columns are used in small-scale laboratory distillations as well as large-scale industrial distillations.
A heat pipe is a heat-transfer device that employs phase transition to transfer heat between two solid interfaces.
A chiller is a machine that removes heat from a liquid coolant via a vapor-compression, absorption refrigeration, or absorption refrigeration cycles. This liquid can then be circulated through a heat exchanger to cool equipment, or another process stream. As a necessary by-product, refrigeration creates waste heat that must be exhausted to ambience, or for greater efficiency, recovered for heating purposes. Vapor compression chillers may use any of a number of different types of compressors. Most common today are the hermetic scroll, semi-hermetic screw, or centrifugal compressors. The condensing side of the chiller can be either air or water cooled. Even when liquid cooled, the chiller is often cooled by an induced or forced draft cooling tower. Absorption and adsorption chillers require a heat source to function.
Vacuum distillation or Distillation under reduced pressure is a type of distillation performed under reduced pressure, which allows the purification of compounds not readily distilled at ambient pressures or simply to save time or energy. This technique separates compounds based on differences in their boiling points. This technique is used when the boiling point of the desired compound is difficult to achieve or will cause the compound to decompose. Reduced pressures decrease the boiling point of compounds. The reduction in boiling point can be calculated using a temperature-pressure nomograph using the Clausius–Clapeyron relation.
A shell-and-tube heat exchanger is a class of heat exchanger designs. It is the most common type of heat exchanger in oil refineries and other large chemical processes, and is suited for higher-pressure applications. As its name implies, this type of heat exchanger consists of a shell with a bundle of tubes inside it. One fluid runs through the tubes, and another fluid flows over the tubes to transfer heat between the two fluids. The set of tubes is called a tube bundle, and may be composed of several types of tubes: plain, longitudinally finned, etc.
Thermosiphon is a method of passive heat exchange, based on natural convection, which circulates a fluid without the necessity of a mechanical pump. Thermosiphoning is used for circulation of liquids and volatile gases in heating and cooling applications such as heat pumps, water heaters, boilers and furnaces. Thermosiphoning also occurs across air temperature gradients such as those utilized in a wood fire chimney or solar chimney.
Continuous distillation, a form of distillation, is an ongoing separation in which a mixture is continuously fed into the process and separated fractions are removed continuously as output streams. Distillation is the separation or partial separation of a liquid feed mixture into components or fractions by selective boiling and condensation. The process produces at least two output fractions. These fractions include at least one volatile distillate fraction, which has boiled and been separately captured as a vapor condensed to a liquid, and practically always a bottoms fraction, which is the least volatile residue that has not been separately captured as a condensed vapor.
An absorption refrigerator is a refrigerator that uses a heat source to provide the energy needed to drive the cooling process. Solar energy, burning a fossil fuel, waste heat from factories, and district heating systems are examples of convenient heat sources that can be used. An absorption refrigerator uses two coolants: the first coolant performs evaporative cooling and then is absorbed into the second coolant; heat is needed to reset the two coolants to their initial states. Absorption refrigerators are commonly used in recreational vehicles (RVs), campers, and caravans because the heat required to power them can be provided by a propane fuel burner, by a low-voltage DC electric heater or by a mains-powered electric heater. Absorption refrigerators can also be used to air-condition buildings using the waste heat from a gas turbine or water heater in the building. Using waste heat from a gas turbine makes the turbine very efficient because it first produces electricity, then hot water, and finally, air-conditioning—trigeneration.
The steam-electric power station is a power station in which the electric generator is steam driven. Water is heated, turns into steam and spins a steam turbine which drives an electrical generator. After it passes through the turbine, the steam is condensed in a condenser. The greatest variation in the design of steam-electric power plants is due to the different fuel sources.
A zeotropicmixture, or non-azeotropic mixture, is a mixture with liquid components that have different boiling points. For example, nitrogen, methane, ethane, propane, and isobutane constitute a zeotropic mixture. Individual substances within the mixture do not evaporate or condense at the same temperature as one substance. In other words, the mixture has a temperature glide, as the phase change occurs in a temperature range of about four to seven degrees Celsius, rather than at a constant temperature. On temperature-composition graphs, this temperature glide can be seen as the temperature difference between the bubble point and dew point. For zeotropic mixtures, the temperatures on the bubble (boiling) curve are between the individual component's boiling temperatures. When a zeotropic mixture is boiled or condensed, the composition of the liquid and the vapor changes according to the mixtures's temperature-composition diagram.
A turboexpander, also referred to as a turbo-expander or an expansion turbine, is a centrifugal or axial-flow turbine, through which a high-pressure gas is expanded to produce work that is often used to drive a compressor or generator.
An evaporator is a type of heat exchanger device that facilitates evaporation by utilizing conductive and convective heat transfer to provide the necessary thermal energy for phase transition from liquid to vapor. Within evaporators, a circulating liquid is exposed to an atmospheric or reduced pressure environment, causing it to boil at a lower temperature compared to normal atmospheric boiling.
A delayed coker is a type of coker whose process consists of heating a residual oil feed to its thermal cracking temperature in a furnace with multiple parallel passes. This cracks the heavy, long chain hydrocarbon molecules of the residual oil into coker gas oil and petroleum coke.
A boiler or steam generator is a device used to create steam by applying heat energy to water. Although the definitions are somewhat flexible, it can be said that older steam generators were commonly termed boilers and worked at low to medium pressure but, at pressures above this, it is more usual to speak of a steam generator.
A rising film or vertical long tube evaporator is a type of evaporator that is essentially a vertical shell and tube heat exchanger. The liquid being evaporated is fed from the bottom into long tubes and heated with steam condensing on the outside of the tube from the shell side. This is to produce steam and vapour within the tube bringing the liquid inside to a boil. The vapour produced then presses the liquid against the walls of the tubes and causes the ascending force of this liquid. As more vapour is formed, the centre of the tube will have a higher velocity which forces the remaining liquid against the tube wall forming a thin film which moves upwards. This phenomenon of the rising film gives the evaporator its name.
Refining of crude oils essentially consists of primary separation processes and secondary conversion processes. The petroleum refining process is the separation of the different hydrocarbons present in crude oil into useful fractions and the conversion of some of the hydrocarbons into products having higher quality performance.
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