A prism spectrometer is an optical spectrometer which uses a dispersive prism as its dispersive element. The prism refracts light into its different colors (wavelengths). The dispersion occurs because the angle of refraction is dependent on the refractive index of the prism's material, which in turn is slightly dependent on the wavelength of light that is traveling through it.
Light is emitted from a source such as a vapor lamp. A slit selects a thin strip of light which passes through the collimator where it gets parallelized. The aligned light then passes through the prism in which it is refracted twice (once when entering and once when leaving). Due to the nature of a dispersive element the angle with which light is refracted depends on its wavelength. This leads to a spectrum of thin lines of light, each being observable at a different angle. A lens or telescope is then used to form images of the original slit, with images formed using different wavelengths of light at different positions. If a real image is formed, it can be recorded on film or an image sensor, making the device a spectrograph.
Replacing the prism with a diffraction grating would result in a grating spectrometer. Optical gratings are less expensive, provide much higher resolution, and are easier to calibrate, due to their linear diffraction dependency. A prism's refraction angle varies nonlinearly with wavelength. On the other hand, gratings have significant intensity losses.
A prism spectrometer may be used to determine the composition of a material from its emitted spectral lines.
A prism spectrometer may be used to measure the refractive index of a material if the wavelengths of the light used are known. The calibration of a prism spectrometer is carried out with known spectral lines from vapor lamps or laser light.
Diffraction refers to various phenomena that occur when a wave encounters an obstacle or a slit. It is defined as the bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a secondary source of the propagating wave. Italian scientist Francesco Maria Grimaldi coined the word "diffraction" and was the first to record accurate observations of the phenomenon in 1660.
Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultraviolet, and infrared light. Because light is an electromagnetic wave, other forms of electromagnetic radiation such as X-rays, microwaves, and radio waves exhibit similar properties.
An optical spectrometer is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials. The variable measured is most often the light's intensity but could also, for instance, be the polarization state. The independent variable is usually the wavelength of the light or a unit directly proportional to the photon energy, such as reciprocal centimeters or electron volts, which has a reciprocal relationship to wavelength.
In optics, a diffraction grating is an optical component with a periodic structure that splits and diffracts light into several beams travelling in different directions. The emerging coloration is a form of structural coloration. The directions of these beams depend on the spacing of the grating and the wavelength of the light so that the grating acts as the dispersive element. Because of this, gratings are commonly used in monochromators and spectrometers.
In optics, dispersion is the phenomenon in which the phase velocity of a wave depends on its frequency. Media having this common property may be termed dispersive media. Sometimes the term chromatic dispersion is used for specificity. Although the term is used in the field of optics to describe light and other electromagnetic waves, dispersion in the same sense can apply to any sort of wave motion such as acoustic dispersion in the case of sound and seismic waves, in gravity waves, and for telecommunication signals along transmission lines or optical fiber.
An optical prism is a transparent optical element with flat, polished surfaces that refract light. At least one surface must be angled—elements with two parallel surfaces are not prisms. The traditional geometrical shape of an optical prism is that of a triangular prism with a triangular base and rectangular sides, and in colloquial use "prism" usually refers to this type. Some types of optical prism are not in fact in the shape of geometric prisms. Prisms can be made from any material that is transparent to the wavelengths for which they are designed. Typical materials include glass, plastic, and fluorite.
The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to an atom or molecule making a transition from a high energy state to a lower energy state. The photon energy of the emitted photon is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances.
Optics is the branch of physics which involves the behavior and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behavior of visible, ultraviolet, and infrared light. Because light is an electromagnetic wave, other forms of electromagnetic radiation such as X-rays, microwaves, and radio waves exhibit similar properties.
A monochromator is an optical device that transmits a mechanically selectable narrow band of wavelengths of light or other radiation chosen from a wider range of wavelengths available at the input. The name is from the Greek roots mono-, "single", and chroma, "colour", and the Latin suffix -ator, denoting an agent.
X-ray spectroscopy is a general term for several spectroscopic techniques for characterization of materials by using x-ray excitation.
A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array allowing the full spectrum to be obtained with a single acquisition. Most spectrometers have a base measurement of counts which is the un-calibrated reading and is thus impacted by the sensitivity of the detector to each wavelength. By applying a calibration, the spectrometer is then able to provide measurements of spectral irradiance, spectral radiance and/or spectral flux. This data is also then used with built in or PC software and numerous algorithms to provide readings or Irradiance (W/cm2), Illuminance, Radiance (W/sr), Luminance (cd), Flux, Chromaticity, Color Temperature, Peak and Dominant Wavelength. Some more complex spectrometer software packages also allow calculation of PAR µmol/m²/s, Metamerism, and candela calculations based on distance and include features like 2- and 20-degree observer, baseline overlay comparisons, transmission and reflectance.
An imaging spectrometer is an instrument used in hyperspectral imaging and imaging spectroscopy to acquire a spectrally-resolved image of an object or scene, often referred to as a datacube due to the three-dimensional representation of the data. Two axes of the image corresponds to vertical and horizontal distance and the third to wavelength. The principle of operation is the same as that of the simple spectrometer, but special care is taken to avoid optical aberrations for better image quality.
In optics, a dispersive prism is an optical prism, usually having the shape of a geometrical triangular prism, used as a spectroscopic component. Spectral dispersion is the best known property of optical prisms, although not the most frequent purpose of using optical prisms in practice. Triangular prisms are used to disperse light, that is, to break light up into its spectral components. Different wavelengths (colors) of light will be deflected by the prism at different angles, producing a spectrum on a detector. This is a result of the prism's material index of refraction varying with wavelength. By application of Snell's law, one can see that as the wavelength changes, and the refractive index changes, the deflection angle of a light beam will change, separating the colors of the light spatially. Generally, longer wavelengths (red) thereby undergo a smaller deviation than shorter wavelengths (blue) where the refractive index is larger.
An echelle grating is a type of diffraction grating characterised by a relatively low groove density, but a groove shape which is optimized for use at high incidence angles and therefore in high diffraction orders. Higher diffraction orders allow for increased dispersion (spacing) of spectral features at the detector, enabling increased differentiation of these features. Echelle gratings are, like other types of diffraction gratings, used in spectrometers and similar instruments. They are most useful in cross-dispersed high resolution spectrographs, such as HARPS, PRL Advanced Radial Velocity Abu Sky Search (PARAS), and numerous other astronomical instruments.
An ultrasonic grating is a type of diffraction grating produced by interfering ultrasonic waves in a medium altering the physical properties of the medium, and hence the refractive index, in a grid-like pattern. The term acoustic grating is a more general term that includes operation at audible frequencies.
Fourier-transform infrared spectroscopy (FTIR) is a technique used to obtain an infrared spectrum of absorption or emission of a solid, liquid or gas. An FTIR spectrometer simultaneously collects high-spectral-resolution data over a wide spectral range. This confers a significant advantage over a dispersive spectrometer, which measures intensity over a narrow range of wavelengths at a time.
The history of spectroscopy began in the 17th century. New designs in optics, specifically prisms, enabled systematic observations of the solar spectrum. Isaac Newton first applied the word spectrum to describe the rainbow of colors that combine to form white light. During the early 1800s, Joseph von Fraunhofer conducted experiments with dispersive spectrometers that enabled spectroscopy to become a more precise and quantitative scientific technique. Since then, spectroscopy has played and continues to play a significant role in chemistry, physics and astronomy. Fraunhofer observed and measured dark lines in the Sun's spectrum.
Fiber-optic filter is an optical fiber instrument used for wavelength selection, which can select desired wavelengths to pass and reject the others. It is Widely used in DWDM systems dynamic wavelength selection, DWDM signal separation, optical performance monitoring, field tunable optical noise filtering and optical amplifier noise suppression, etc. Optical multiplexers (couplers) makes different wavelength coupling into an optical fiber and different wavelength carries different information. At the receiving end, if you want to separate desired wavelengths from optical fiber, it is necessary to use optical filter.
A spectrometer is a scientific instrument used to separate and measure spectral components of a physical phenomenon. Spectrometer is a broad term often used to describe instruments that measure a continuous variable of a phenomenon where the spectral components are somehow mixed. In visible light a spectrometer can separate white light and measure individual narrow bands of color, called a spectrum. A mass spectrometer measures the spectrum of the masses of the atoms or molecules present in a gas. The first spectrometers were used to split light into an array of separate colors. Spectrometers were developed in early studies of physics, astronomy, and chemistry. The capability of spectroscopy to determine chemical composition drove its advancement and continues to be one of its primary uses. Spectrometers are used in astronomy to analyze the chemical composition of stars and planets, and spectrometers gather data on the origin of the universe.
A virtually imaged phased array (VIPA) is an angular dispersive device that, like a prism or a diffraction grating, splits light into its spectral components. It works almost independently of polarization. In contrast to prisms or regular diffraction gratings, it has a much higher angular dispersion but has a smaller free spectral range. This aspect is similar to that of an Echelle grating which is usually used in reflection, since high diffraction orders are also used there. The VIPA can be a compact optical component with high wavelength resolving power.