Cubanite

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Cubanite
Cubanite-47299.jpg
Striated, cyclically-twinned cubanite crystals from the Chibougamau mines of Quebec (size: 1.5 × 1.3 × 1.0 cm)
General
Category Sulfide mineral
Formula
(repeating unit)
CuFe2S3
IMA symbol Cbn [1]
Strunz classification 2.CB.55a
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Pcmn
Unit cell a = 6.467(1) Å,
b = 11.117(1) Å,
c = 6.231(2) Å; Z = 4
Identification
ColorBronze to brass-yellow
Crystal habit Crystals elongated to thick tabular, striated also massive
Twinning Common with twin plane {110} in pairs, also as fourlings and pseudohexagonal sixlings
Cleavage Parting on {110} and {130}
Fracture Conchoidal
Mohs scale hardness3.5–4
Luster Metallic
Streak Black
Diaphaneity Opaque
Specific gravity 4.0–4.2
Optical propertiesDistinctly anisotropic on polished surface
Other characteristicsStrongly magnetic
References [2] [3] [4]

Cubanite is a copper iron sulfide mineral that commonly occurs as a minor alteration mineral in magmatic sulfide deposits. It has the chemical formula CuFe2S3 and when found, it has a bronze to brass-yellow appearance. On the Mohs hardness scale, cubanite falls between 3.5 and 4 and has a orthorhombic crystal system. [2] Cubanite is chemically similar to chalcopyrite; however, it is the less common copper iron sulfide mineral due to crystallization requirements.

Contents

Cubanite occurs in high temperature hydrothermal mineral deposits with pyrrhotite and pentlandite as intergrowths with chalcopyrite. [4] It results from exsolution from chalcopyrite at temperatures below 200 to 210 °C. [4] If cubanite is exposed to temperatures above 210 °C, it will transform into isocubanite. After this transformation, if it begins to cool, it will not revert to cubanite. [5] Upon its transformation to isocubanite it will lose its highly magnetic property due to its change from an orthorhombic to a cubic crystal structure. [6] Cubanite has been identified on chondrites and within dust grain samples and has improved the precision of copper isotope analysis.

Etymology and history

Iridescent and highly lustrous brass-yellow cubanite crystal from Chibougamau, Quebec (size: 1.7 x 1.0 x 0.7 cm) Cubanite-237462.jpg
Iridescent and highly lustrous brass-yellow cubanite crystal from Chibougamau, Quebec (size: 1.7 x 1.0 x 0.7 cm)

Cubanite comes from the Spanish word Cubano, or Cuban in English, and the suffix -ite, when naming a mineral. Cubanite was first described in 1843 for its occurrence in the Mayarí-Baracoa Belt, HolguÍn Province, Cuba. It may also be referenced as barracanite in some literature. [2]

Association and alteration

As a minor alteration mineral, cubanite can only form when there is hydrothermal alteration of magmatic ores. The ores that are associated with cubanite are unaltered pyrrhotite-pentlandite-chalcopyrite ores that experience alteration to millerite-pyrite-chalcopyrite-cubanite ores, like those seen in the Bushveld Complex. [7] For cubanite to form from chalcopyrite, a loss of copper relative to sulfur and iron and an increase in iron relative to sulfur must occur. [7] This significant change in mineralogy results crystal structure change from tetragonal chalcopyrite to orthorhombic cubanite. With an increase in temperature above 210 °C, alteration continues and cubanite will transform into isocubanite, an isometric polymorph. There will be no transformation back to cubanite upon the cooling of the isocubanite. [5]

Extraterrestrial cubanite

Tagish Lake Meteorite, Classified as CI-2 due to presence of chondrules Tagish Lake meteorite.jpg
Tagish Lake Meteorite, Classified as CI-2 due to presence of chondrules

Although cubanite forms in hydrothermal mineral deposits, there are occurrences of cubanite that did not form on earth. Cubanite has been found in carbonaceous chondrite meteorites, specifically class CI-chondrites, as well as in cometary samples from NASA’s Stardust spacecraft. [8] Data from the Itokawa asteroid, collected by the Hayabusa spacecraft, indicated that a 2-micrometre grain of cubanite was found on the S-type asteroid. This is the first time cubanite has been found on another asteroid that was not class C-type. However, further inspection of the sample revealed that the cubanite likely formed exogeneous to the Itokawa body. [9]

Synthetic cubanite

Although synthetic and chondritic cubanite have structural variations, synthesis of cubanite still grants insight into the formation of CI-chondrites. Using a lab-based variant of hydrothermal recrystallization, temperatures between 150-200 °C, and a pH of 9, scientists were able to determine compositions needed to replicate CI-chondrite mineralogy.  Experiments that began with copper + iron + sulfur, covellite + troilite, and copper + sulfur + troilite all formed cubanite. Starting with troilite instead of iron metal reinforces previous studies that sulfides on Cl-chondrites are the resultant of oxidation of troilite by hydrothermal processes. [8]

Copper isotope analysis

Due to its complex growth nature, Cubanite has been the test subject for instrumental preference in copper isotope microanalysis. It was found that ultra violet laser ablation multiple collector inductively coupled plasma mass spectrometry (UV-fs-LA-MC-ICP-MS) improves precision in respect to copper isotopes, when compared to the use of near infrared (NIR-fs-LA-MC-ICP-MS) methods. [10]

Inductively Coupled Plasma Mass Spectrometry (ICP-MS) analytical instrument ICP-MS.jpg
Inductively Coupled Plasma Mass Spectrometry (ICP-MS) analytical instrument

Related Research Articles

<span class="mw-page-title-main">Pentlandite</span> Iron–nickel sulfide

Pentlandite is an iron–nickel sulfide with the chemical formula (Fe,Ni)9S8. Pentlandite has a narrow variation range in nickel to iron ratios (Ni:Fe), but it is usually described as 1:1. In some cases, this ratio is skewed by the presence of pyrrhotite inclusions. It also contains minor cobalt, usually at low levels as a fraction of weight.

<span class="mw-page-title-main">Chalcopyrite</span> Copper iron sulfide mineral

Chalcopyrite ( KAL-kə-PY-ryte, -⁠koh-) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black.

<span class="mw-page-title-main">Bornite</span> Sulfide mineral

Bornite, also known as peacock ore, is a sulfide mineral with chemical composition Cu5FeS4 that crystallizes in the orthorhombic system (pseudo-cubic).

<span class="mw-page-title-main">Skarn</span> Hard, coarse-grained, hydrothermally altered metamorphic rocks

Skarns or tactites are coarse-grained metamorphic rocks that form by replacement of carbonate-bearing rocks during regional or contact metamorphism and metasomatism. Skarns may form by metamorphic recrystallization of impure carbonate protoliths, bimetasomatic reaction of different lithologies, and infiltration metasomatism by magmatic-hydrothermal fluids. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals. These minerals form as a result of alteration which occurs when hydrothermal fluids interact with a protolith of either igneous or sedimentary origin. In many cases, skarns are associated with the intrusion of a granitic pluton found in and around faults or shear zones that commonly intrude into a carbonate layer composed of either dolomite or limestone. Skarns can form by regional or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from a variety of sources; magmatic, metamorphic, meteoric, marine, or even a mix of these. The resulting skarn may consist of a variety of different minerals which are highly dependent on both the original composition of the hydrothermal fluid and the original composition of the protolith.

<span class="mw-page-title-main">Nickeline</span> Nickel arsenide mineral

Nickeline or niccolite is a mineral consisting primarily of nickel arsenide (NiAs). The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.

<span class="mw-page-title-main">Covellite</span> Sulfide mineral

Covellite is a rare copper sulfide mineral with the formula CuS. This indigo blue mineral is commonly a secondary mineral in limited abundance and although it is not an important ore of copper itself, it is well known to mineral collectors.

<span class="mw-page-title-main">Pyrrhotite</span> Magnetic iron sulfide mineral

Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S. It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is weakly magnetic. The magnetism decreases as the iron content decreases, and troilite is non-magnetic. Pyrrhotite is generally tabular and brassy/bronze in color with a metallic luster. The mineral occurs with mafic igneous rocks like norites, and may form from pyrite during metamorphic processes. Pyrrhotite is associated and mined with other sulfide minerals like pentlandite, pyrite, chalcopyrite, and magnetite, and has been found globally.

<span class="mw-page-title-main">Marcasite</span> Iron disulfide (FeS2) with orthorhombic crystal structure

The mineral marcasite, sometimes called "white iron pyrite", is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both structures contain the disulfide S22− ion, having a short bonding distance between the sulfur atoms. The structures differ in how these di-anions are arranged around the Fe2+ cations. Marcasite is lighter and more brittle than pyrite. Specimens of marcasite often crumble and break up due to the unstable crystal structure.

<span class="mw-page-title-main">Volcanogenic massive sulfide ore deposit</span> Metal sulfide ore deposit

Volcanogenic massive sulfide ore deposits, also known as VMS ore deposits, are a type of metal sulfide ore deposit, mainly copper-zinc which are associated with and created by volcanic-associated hydrothermal events in submarine environments.

<span class="mw-page-title-main">Fukuchilite</span>

Fukuchilite, Cu
3
FeS
8
, is a copper iron sulfide named after the Japanese mineralogist Nobuyo Fukuchi (1877–1934), that occurs in ore bodies of gypsum-anhydrite at the intersection points of small masses of barite, covellite, gypsum and pyrite, and is mostly found in the Hanawa mine in the Akita prefecture of Honshū, Japan where it was first discovered in 1969. It occurs in masses within the third geologic unit of the Kuroko type deposits within the mine.

<span class="mw-page-title-main">Troilite</span> Rare iron sulfide mineral: FeS

Troilite is a rare iron sulfide mineral with the simple formula of FeS. It is the iron-rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1-x)S which is iron deficient. As troilite lacks the iron deficiency which gives pyrrhotite its characteristic magnetism, troilite is non-magnetic.

<span class="mw-page-title-main">Ore genesis</span> How the various types of mineral deposits form within the Earths crust

Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined.

<span class="mw-page-title-main">Layered intrusion</span>

A layered intrusion is a large sill-like body of igneous rock which exhibits vertical layering or differences in composition and texture. These intrusions can be many kilometres in area covering from around 100 km2 (39 sq mi) to over 50,000 km2 (19,000 sq mi) and several hundred metres to over one kilometre (3,300 ft) in thickness. While most layered intrusions are Archean to Proterozoic in age, they may be any age such as the Cenozoic Skaergaard intrusion of east Greenland or the Rum layered intrusion in Scotland. Although most are ultramafic to mafic in composition, the Ilimaussaq intrusive complex of Greenland is an alkalic intrusion.

<span class="mw-page-title-main">Heazlewoodite</span>

Heazlewoodite, Ni3S2, is a rare sulfur-poor nickel sulfide mineral found in serpentinitized dunite. It occurs as disseminations and masses of opaque, metallic light bronze to brassy yellow grains which crystallize in the trigonal crystal system. It has a hardness of 4, a specific gravity of 5.82. Heazlewoodite was first described in 1896 from Heazlewood, Tasmania, Australia.

<span class="mw-page-title-main">Mackinawite</span> Iron nickel sulfide mineral

Mackinawite is an iron nickel sulfide mineral with the chemical formula (Fe,Ni)
1+x
S
. The mineral crystallizes in the tetragonal crystal system and has been described as a distorted, close packed, cubic array of S atoms with some of the gaps filled with Fe. Mackinawite occurs as opaque bronze to grey-white tabular crystals and anhedral masses. It has a Mohs hardness of 2.5 and a specific gravity of 4.17. It was first described in 1962 for an occurrence in the Mackinaw mine, Snohomish County, Washington for which it was named.

Iron oxide copper gold ore deposits (IOCG) are important and highly valuable concentrations of copper, gold and uranium ores hosted within iron oxide dominant gangue assemblages which share a common genetic origin.

Mooihoekite is a copper iron sulfide mineral with chemical formula of Cu9Fe9S16. The mineral was discovered in 1972 and received its name from its discovery area, the Mooihoek mine in Transvaal, South Africa.

<span class="mw-page-title-main">Djerfisherite</span>

Djerfisherite is an alkali copper–iron sulfide mineral and a member of the djerfisherite group.

<span class="mw-page-title-main">Millerite</span> Nickel sulfide mineral

Millerite is a nickel sulfide mineral, NiS. It is brassy in colour and has an acicular habit, often forming radiating masses and furry aggregates. It can be distinguished from pentlandite by crystal habit, its duller colour, and general lack of association with pyrite or pyrrhotite.

Farallon Negro is a volcano in the Catamarca province of Argentina. Active between about 9-8 million years ago, it was formerly a stratovolcano or a multi vent volcano. Eventually, erosion removed most of the volcano and exposed the underlying structure including subvolcanic intrusions.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Mindat.org
  3. Webmineral
  4. 1 2 3 Handbook of Mineralogy
  5. 1 2 Chandra, U.; Parthasarathy, G.; Sharma, P. (2010-10-01). "SYNTHETIC CUBANITE CuFe2S3: PRESSURE-INDUCED TRANSFORMATION TO ISOCUBANITE". The Canadian Mineralogist. 48 (5): 1137–1147. Bibcode:2010CaMin..48.1137C. doi:10.3749/canmin.48.5.1137. ISSN   0008-4476.
  6. Sawada, M.; Ozima, M.; Fujiki, Y. (1962). "Magnetic Properties of Cubanite (CuFe2S3)". Journal of Geomagnetism and Geoelectricity. 14 (2): 107–112. Bibcode:1962JGG....14..107S. doi: 10.5636/jgg.14.107 . ISSN   0022-1392.
  7. 1 2 Holwell, David A.; Adeyemi, Zeinab; Ward, Laura A.; Smith, Daniel J.; Graham, Shaun D.; McDonald, Iain; Smith, Jennifer W. (December 2017). "Low temperature alteration of magmatic Ni-Cu-PGE sulfides as a source for hydrothermal Ni and PGE ores: A quantitative approach using automated mineralogy". Ore Geology Reviews. 91: 718–740. Bibcode:2017OGRv...91..718H. doi: 10.1016/j.oregeorev.2017.08.025 . hdl: 2381/40374 . ISSN   0169-1368.
  8. 1 2 Berger, Eve L.; Keller, Lindsay P.; Lauretta, Dante S. (2015). "An experimental study of the formation of cubanite (CuFe2S3) in primitive meteorites". Meteoritics & Planetary Science. 50 (1): 1–14. Bibcode:2015M&PS...50....1B. doi: 10.1111/maps.12399 . ISSN   1945-5100. S2CID   95725179.
  9. Burgess, Katherine; Stroud, Rhonda (August 2020). "STEM of Three Itokawa Grains: Space Weathering and Presence of Cubanite". Microscopy and Microanalysis. 26 (S2): 2602–2604. Bibcode:2020MiMic..26S2602B. doi: 10.1017/S1431927620022151 . ISSN   1431-9276. S2CID   225397714.
  10. IKEHATA, Kei; HIRATA, Takafumi (2013). "Evaluation of UV-fs-LA-MC-ICP-MS for Precise in situ Copper Isotopic Microanalysis of Cubanite". Analytical Sciences. 29 (12): 1213–1217. doi: 10.2116/analsci.29.1213 . hdl: 2241/120627 . ISSN   0910-6340. PMID   24334990.