Hornblende

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Hornblende
Apatite-(CaOH)-Hornblende-38354.jpg
Hornblende crystal (dark green) about 35 mm long, with apatite (white)
General
CategorySilicate mineral
Formula
(repeating unit)
Ca2(Mg,Fe,Al)5(Al,Si)8O22(OH)2
IMA symbol Hbl [1]
Crystal system Monoclinic
Space group C2/m
Identification
ColorBlack to dark green or brown
Crystal habit Hexagonal/granular
Cleavage Imperfect at 56° and 124°
Fracture Uneven
Mohs scale hardness5–6
Luster Vitreous to dull
Streak Pale gray, gray-white, [2] [3] white, colorless [4]
Specific gravity 2.9
Pleochroism Strong
References [5]

Hornblende is a complex inosilicate series of minerals. [6] It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.

Contents

The general formula is (Ca,Na)2−3(Mg,Fe,Al)5(Al,Si)8O22(OH,F)2.

Physical properties

Hornblende has a hardness of 5–6, a specific gravity of 3.0 to 3.6, and is typically an opaque green, dark green, brown, or black color. It tends to form slender prismatic to bladed crystals, diamond-shaped in cross section, or is present as irregular grains or fibrous masses. [7]

Its planes of cleavage intersect at 56° and 124° angles. Hornblende is most often confused with the pyroxene series and biotite mica, which are also dark minerals found in granite and charnockite. Pyroxenes differ in their cleavage planes, which intersect at 87° and 93°. [8]

Hornblende is an inosilicate (chain silicate) mineral, built around double chains of silica tetrahedra. These chains extend the length of the crystal and are bonded to their neighbors by additional metal ions to form the complete crystal structure. [9]

Compositional variances

Hornblende is part of the calcium-amphibole group of amphibole minerals. [10] It is highly variable in composition, and includes at least five solid solution series:

In addition, titanium, manganese, or chromium can substitute for some of the cations and oxygen, fluorine, or chlorine for some of the hydroxide (OH). The different chemical types are almost impossible to distinguish even by optical or X-ray methods, and detailed chemical analysis using an electron microprobe is required. [11]

There is a solid solution series between hornblende and the closely related amphibole minerals, tremoliteactinolite, at elevated temperature. A miscibility gap exists at lower temperatures, and, as a result, hornblende often contains exsolution lamellae of grunerite. [12]

Occurrence

Hornblende diorite from the Henry Mountains, Utah, US Horndio.jpg
Hornblende diorite from the Henry Mountains, Utah, US

Hornblende is a common constituent of many igneous and metamorphic rocks such as granite, syenite, diorite, gabbro, basalt, andesite, gneiss, and schist. It crystallizes in preference to pyroxene minerals from cooler magma that is richer in silica and water. [13]

It is the principal mineral of amphibolites, which form during medium- to high-grade metamorphism of mafic to intermediate igneous rock (igneous rocks with relative low silica content) in the presence of pore water. Much of the pore water comes from the breakdown of micas or other hydrous minerals. However, hornblende itself breaks down at very high temperatures. [13] Hornblende alters easily to chlorite, biotite, or other mafic minerals. [14]

A rare variety of hornblende contains less than 5% of iron oxide, is gray to white in color, and is named edenite from its locality in Edenville, Orange County, New York.

Oxyhornblende is a variety in which most of the iron has been oxidized to the ferric state, Fe3+. Charge balance is preserved by the substitution of oxygen ions for hydroxide. Oxyhornblende is also typically enriched in titanium. It is found almost exclusively in volcanic rock and is sometimes called basaltic hornblende. [15] [16]

Etymology

The word hornblende is derived from German Horn ('horn') and blende ('deceive'), in allusion to its similar appearance to metal-bearing ore minerals. [17]

See also

Related Research Articles

<span class="mw-page-title-main">Mafic</span> Silicate mineral or igneous rock that is rich in magnesium and iron

A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include basalt, diabase and gabbro. Mafic rocks often also contain calcium-rich varieties of plagioclase feldspar. Mafic materials can also be described as ferromagnesian.

<span class="mw-page-title-main">Amphibole</span> Group of inosilicate minerals

Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4
tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.

<span class="mw-page-title-main">Pyroxene</span> Group of inosilicate minerals with single chains of silica tetrahedra

The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula XY(Si,Al)2O6, where X represents calcium (Ca), sodium (Na), iron or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron. Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes.

<span class="mw-page-title-main">Actinolite</span> Mineral

Actinolite is an amphibole silicate mineral with the chemical formula Ca2(Mg4.5–2.5Fe2+0.5–2.5)Si8O22(OH)2.

<span class="mw-page-title-main">Andesite</span> Type of volcanic rock

Andesite is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predominantly of sodium-rich plagioclase plus pyroxene or hornblende.

<span class="mw-page-title-main">Amphibolite</span> Metamorphic rock type

Amphibolite is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky) structure. The small flakes of black and white in the rock often give it a salt-and-pepper appearance.

<span class="mw-page-title-main">Augite</span> Common rock-forming pyroxene mineral

Augite, also known as Augurite, is a common rock-forming pyroxene mineral with formula (Ca,Na)(Mg,Fe,Al,Ti)(Si,Al)2O6. The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.

<span class="mw-page-title-main">Nepheline syenite</span> Holocrystalline plutonic rock

Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.

<span class="mw-page-title-main">Peridotite</span> Coarse-grained ultramafic igneous rock type

Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.

<span class="mw-page-title-main">Enstatite</span> Pyroxene: magnesium-iron silicate with MgSiO3 and FeSiO3 end-members

Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, (Mg,Fe)SiO
3
, has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20).

<span class="mw-page-title-main">Hypersthene</span>

Hypersthene is a common rock-forming inosilicate mineral belonging to the group of orthorhombic pyroxenes. Its chemical formula is (Mg,Fe)SiO3. It is found in igneous and some metamorphic rocks as well as in stony and iron meteorites. Many references have formally abandoned this term, preferring to categorise this mineral as enstatite or ferrosilite. It forms a solid solution series with the minerals enstatite and ferrosilite, being a mid-way member between the two. Pure enstatite contains no iron, while pure ferrosilite contains no magnesium; hypersthene is the name given to the mineral when a significant amount of both elements are present. Enstatite is stable at atmospheric pressure, but ferrosilite is stable only at elevated pressure, decomposing into quartz and fayalite at atmospheric pressure unless stabilized by magnesium or other impurities.

<span class="mw-page-title-main">Silicate mineral</span> Rock-forming minerals with predominantly silicate anions

Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.

<span class="mw-page-title-main">Chlorite group</span> Type of mineral

The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.

<span class="mw-page-title-main">Lamprophyre</span> Ultrapotassic igneous rocks

Lamprophyres are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.

<span class="mw-page-title-main">Essexite</span> Igneous rock type

Essexite, also called nepheline monzogabbro, is a dark gray or black holocrystalline plutonic igneous rock. Its name is derived from the type locality in Essex County, Massachusetts, in the United States.

Normative mineralogy is a calculation of the composition of a rock sample that estimates the idealised mineralogy of a rock based on a quantitative chemical analysis according to the principles of geochemistry.

<span class="mw-page-title-main">Tschermakite</span> Amphibole, double chain inosilicate mineral

The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the thermodynamic properties of its assemblage can be applied to solving other solid solution series from a variety of amphibole minerals.

<span class="mw-page-title-main">Gedrite</span>

Gedrite is a crystal belonging to the orthorhombic ferromagnesian subgroup of the amphibole supergroup of the double chain inosilicate minerals with the ideal chemical formula Mg2(Mg3Al2)(Si6Al2)O22(OH)2.

This list gives an overview of the classification of minerals (silicates) and includes mostly International Mineralogical Association (IMA) recognized minerals and its groupings. This list complements the List of minerals recognized by the International Mineralogical Association series of articles and List of minerals. Rocks, ores, mineral mixtures, non-IMA approved minerals and non-named minerals are mostly excluded.

<span class="mw-page-title-main">Magnesiohastingsite</span>

Magnesiohastingsite is a calcium-containing amphibole and a member of the hornblende group. It is an inosilicate (chain silicate) with the formula NaCa2(Mg4Fe3+)(Si6Al2)O22(OH)2 and molar mass 864.69 g. In synthetic magnesiohastingsite it appears that iron occurs both as ferrous iron Fe2+ and as ferric iron Fe3+, but the ideal formula features only ferric iron. It was named in 1928 by Marland P. Billings. The name is for its relationship to hastingsite and its magnesium content. Hastingsite was named for the locality in Dungannon Township, Hastings County, Ontario, Canada.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Ferrohornblende, Mindat.org
  3. Magnesiohornblende, Mindat.org
  4. "Hornblende Mineral | Uses and Properties".
  5. Phillips, M.W.; Draheim, J.E.; Popp, R.K.; Clowe, C.A.; Pinkerton, A.A. (1989). "Effects of oxidation-dehydrogenation in tschermakitic hornblende". American Mineralogist. 74: 764–773. Retrieved 30 December 2020.
  6. Hornblende Root Name Group, Mindat.org
  7. Nesse, William D. (2000). Introduction to mineralogy. New York: Oxford University Press. pp. 285–286. ISBN   9780195106916.
  8. Pough, Frederick H. (1976). A Field Guide To Rocks and Minerals (4 ed.). Boston: Houghton Mifflin. p. 249.
  9. Nesse 2000, p. 277–279.
  10. Nesse 2000, p. 278.
  11. Nesse 2000, p. 285.
  12. Klein, Cornelis; Hurlbut, Cornelius S. Jr. (1993). Manual of mineralogy : (after James D. Dana) (21st ed.). New York: Wiley. pp. 496–497. ISBN   047157452X.
  13. 1 2 Nesse 2000, p. 279.
  14. Nesse 2000, p. 286.
  15. Jackson, Julia A., ed. (1997). "basaltic hornblende". Glossary of geology (Fourth ed.). Alexandria, Virginia: American Geological Institute. ISBN   0922152349.
  16. Nesse 2000, p. 285–286.
  17. Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (2005). "Ferrohornblende" (PDF). Handbook of Mineralogy. Mineral Data Publishing. Archived (PDF) from the original on 2011-08-22. Retrieved 14 March 2022.