Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion, the heat from a flame may provide enough energy to make the reaction self-sustaining.
The stress–energy tensor, sometimes called the stress–energy–momentum tensor or the energy–momentum tensor, is a tensor physical quantity that describes the density and flux of energy and momentum in spacetime, generalizing the stress tensor of Newtonian physics. It is an attribute of matter, radiation, and non-gravitational force fields. This density and flux of energy and momentum are the sources of the gravitational field in the Einstein field equations of general relativity, just as mass density is the source of such a field in Newtonian gravity.
In probability theory and statistics, the beta distribution is a family of continuous probability distributions defined on the interval [0, 1] in terms of two positive parameters, denoted by alpha (α) and beta (β), that appear as exponents of the variable and its complement to 1, respectively, and control the shape of the distribution.
In mathematics and physics, n-dimensional anti-de Sitter space (AdSn) is a maximally symmetric Lorentzian manifold with constant negative scalar curvature. Anti-de Sitter space and de Sitter space are named after Willem de Sitter (1872–1934), professor of astronomy at Leiden University and director of the Leiden Observatory. Willem de Sitter and Albert Einstein worked together closely in Leiden in the 1920s on the spacetime structure of the universe.
In general relativity, the Gibbons–Hawking–York boundary term is a term that needs to be added to the Einstein–Hilbert action when the underlying spacetime manifold has a boundary.
A premixed flame is a flame formed under certain conditions during the combustion of a premixed charge of fuel and oxidiser. Since the fuel and oxidiser—the key chemical reactants of combustion—are available throughout a homogeneous stoichiometric premixed charge, the combustion process once initiated sustains itself by way of its own heat release. The majority of the chemical transformation in such a combustion process occurs primarily in a thin interfacial region which separates the unburned and the burned gases. The premixed flame interface propagates through the mixture until the entire charge is depleted. The propagation speed of a premixed flame is known as the flame speed which depends on the convection-diffusion-reaction balance within the flame, i.e. on its inner chemical structure. The premixed flame is characterised as laminar or turbulent depending on the velocity distribution in the unburned pre-mixture.
In physics, Maxwell's equations in curved spacetime govern the dynamics of the electromagnetic field in curved spacetime or where one uses an arbitrary coordinate system. These equations can be viewed as a generalization of the vacuum Maxwell's equations which are normally formulated in the local coordinates of flat spacetime. But because general relativity dictates that the presence of electromagnetic fields induce curvature in spacetime, Maxwell's equations in flat spacetime should be viewed as a convenient approximation.
Expected shortfall (ES) is a risk measure—a concept used in the field of financial risk measurement to evaluate the market risk or credit risk of a portfolio. The "expected shortfall at q% level" is the expected return on the portfolio in the worst of cases. ES is an alternative to value at risk that is more sensitive to the shape of the tail of the loss distribution.
In nonideal fluid dynamics, the Hagen–Poiseuille equation, also known as the Hagen–Poiseuille law, Poiseuille law or Poiseuille equation, is a physical law that gives the pressure drop in an incompressible and Newtonian fluid in laminar flow flowing through a long cylindrical pipe of constant cross section. It can be successfully applied to air flow in lung alveoli, or the flow through a drinking straw or through a hypodermic needle. It was experimentally derived independently by Jean Léonard Marie Poiseuille in 1838 and Gotthilf Heinrich Ludwig Hagen, and published by Poiseuille in 1840–41 and 1846. The theoretical justification of the Poiseuille law was given by George Stokes in 1845.
Laminar flame speed is an intrinsic characteristic of premixed combustible mixtures. It is the speed at which an un-stretched laminar flame will propagate through a quiescent mixture of unburned reactants. Laminar flame speed is given the symbol sL. According to the thermal flame theory of Ernest-François Mallard and Le Chatelier, the un-stretched laminar flame speed is dependent on only three properties of a chemical mixture: the thermal diffusivity of the mixture, the reaction rate of the mixture and the temperature through the flame zone:
The Darrieus–Landau instability or hydrodynamic instability is an instrinsic flame instability that occurs in premixed flames, caused by the density variation due to the thermal expansion of the gas produced by the combustion process. In simple terms, the stability inquires whether a steadily propagating plane sheet with a discontinuous jump in density is stable or not. It was predicted independently by Georges Jean Marie Darrieus and Lev Landau.
In combustion, the Karlovitz number is defined as the ratio of chemical time scale to Kolmogorov time scale , named after Béla Karlovitz. The number reads as
The Zel'dovich number is a dimensionless number which provides a quantitative measure for the activation energy of a chemical reaction which appears in the Arrhenius exponent, named after the Russian scientist Yakov Borisovich Zel'dovich, who along with David A. Frank-Kamenetskii, first introduced in their paper in 1938. In 1983 ICDERS meeting at Poitiers, it was decided to name after Zel'dovich.
In Combustion, G equation is a scalar field equation which describes the instantaneous flame position, introduced by Forman A. Williams in 1985 in the study of premixed turbulent combustion. The equation is derived based on the Level-set method. The equation was studied by George H. Markstein earlier, in a restrictive form.
In combustion, heat release parameter is a dimensionless parameter which measures the amount of heat released by the combustion process. It is defined as
Activation energy asymptotics (AEA), also known as large activation energy asymptotics, is an asymptotic analysis used in the combustion field utilizing the fact that the reaction rate is extremely sensitive to temperature changes due to the large activation energy of the chemical reaction.
In combustion, flame stretch is a quantity which measures the amount of stretch of the flame surface due to curvature and due to the outer velocity field strain. The concept of flame stretch was introduced by Karlovitz in 1953. George H. Markstein studied flame stretch by treating the flame surface as a hydrodynamic discontinuity. The flame stretch is also discussed by Bernard Lewis and Guenther von Elbe in their book. All these discussions treated flame stretch as an effect of flow velocity gradients. The stretch can be found even if there is no velocity gradient, but due to the flame curvature. So, the definition required a more general formulation and its precise definition was first introduced by Forman A. Williams in 1975 as the ratio of rate of change of flame surface area to the area itself
In the study of diffusion flame, Liñán's equation is a second-order nonlinear ordinary differential equation which describes the inner structure of the diffusion flame, first derived by Amable Liñán in 1974. The equation reads as
In premixed turbulent combustion, Bray–Moss–Libby (BML) model is a closure model for a scalar field, built on the assumption that the reaction sheet is infinitely thin compared with the turbulent scales, so that the scalar can be found either at the state of burnt gas or unburnt gas. The model is named after Kenneth Bray, J. B. Moss and Paul A. Libby.
Diffusive–thermal instability or thermo–diffusive instability is an intrinsic flame instability that occurs both in premixed flames and in diffusion flames and arises because of the difference in the diffusion coefficient values for the fuel and heat transport, characterized by non-unity values of Lewis numbers. The instability mechanism that arises here is the same as in Turing instability explaining chemical morphogenesis, although the mechanism was first discovered in the context of combustion by Yakov Zeldovich in 1944 to explain the cellular structures appearing in lean hydrogen flames. Quantitative stability theory for premixed flames were developed by Gregory Sivashinsky (1977), Guy Joulin and Paul Clavin (1979) and for diffusion flames by Jong S. Kim and Forman A. Williams (1996,1997).
