Mattauch isobar rule

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The Mattauch isobar rule, formulated by Josef Mattauch in 1934, states that if two adjacent elements on the periodic table have isotopes of the same mass number, one of these isotopes must be radioactive. [1] [2] Two nuclides that have the same mass number (isobars) can both be stable only if their atomic numbers differ by more than one. In fact, for currently observationally stable nuclides, the difference can only be 2 or 4, and in theory, two nuclides that have the same mass number cannot be both stable (at least to beta decay or double beta decay), but many such nuclides which are theoretically unstable to double beta decay have not been observed to decay, e.g. 134Xe. [1] However, this rule cannot make predictions on the half-lives of these radioisotopes. [1]

Contents

Technetium and promethium

A consequence of this rule is that technetium and promethium both have no stable isotopes, as each of the neighboring elements on the periodic table (molybdenum and ruthenium, and neodymium and samarium, respectively) have a beta-stable isotope for each mass number for the range in which the isotopes of the unstable elements usually would be stable to beta decay. (Note that although 147Sm is unstable, it is stable to beta decay; thus 147 is not a counterexample). [1] [2] These ranges can be calculated using the liquid drop model (for example the stability of technetium isotopes), in which the isobar with the lowest mass excess or greatest binding energy is shown to be stable to beta decay [3] because energy conservation forbids a spontaneous transition to a less stable state. [4]

Thus no stable nuclides have proton number 43 or 61, and by the same reasoning no stable nuclides have neutron number 19, 21, 35, 39, 45, 61, 71, 89, 115, or 123.

Exceptions

The only known exceptions to the Mattauch isobar rule are the cases of antimony-123 and tellurium-123 and of hafnium-180 and tantalum-180m, where both nuclei are observationally stable. It is predicted that 123Te would undergo electron capture to form 123Sb, but this decay has not yet been observed; 180mTa should be able to undergo isomeric transition to 180Ta, beta decay to 180W, electron capture to 180Hf, or alpha decay to 176Lu, but none of these decay modes have been observed. [5]

In addition, beta decay has been seen for neither curium-247 nor berkelium-247, though it is expected that the former should decay into the latter. Both nuclides are alpha-unstable.

As mentioned above, the Mattauch isobar rule cannot make predictions as to the half-lives of the beta-unstable isotopes. Hence there are a few cases where isobars of adjacent elements both occur primordially, as the half-life of the unstable isobar is over a billion years. This occurs for the following mass numbers:

See also

Related Research Articles

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A chemical element is a chemical substance that cannot be broken down into other substances by chemical reactions. The basic particle that constitutes a chemical element is the atom. Chemical elements are identified by the number of protons in the nuclei of their atoms, known as the element's atomic number. For example, oxygen has an atomic number of 8, meaning that each oxygen atom has 8 protons in its nucleus. Two or more atoms of the same element can combine to form molecules, in contrast to chemical compounds or mixtures, which contain atoms of different elements. Atoms can be transformed into different elements in nuclear reactions, which change an atom's atomic number.

<span class="mw-page-title-main">Promethium</span> Chemical element, symbol Pm and atomic number 61

Promethium is a chemical element; it has symbol Pm and atomic number 61. All of its isotopes are radioactive; it is extremely rare, with only about 500–600 grams naturally occurring in Earth's crust at any given time. Promethium is one of only two radioactive elements that are followed in the periodic table by elements with stable forms, the other being technetium. Chemically, promethium is a lanthanide. Promethium shows only one stable oxidation state of +3.

<span class="mw-page-title-main">Stable nuclide</span> Nuclide that does not undergo radioactive decay

Stable nuclides are nuclides that are not radioactive and so do not spontaneously undergo radioactive decay. When such nuclides are referred to in relation to specific elements, they are usually termed stable isotopes.

<span class="mw-page-title-main">Electron capture</span> Process in which a proton-rich nuclide absorbs an inner atomic electron

Electron capture is a process in which the proton-rich nucleus of an electrically neutral atom absorbs an inner atomic electron, usually from the K or L electron shells. This process thereby changes a nuclear proton to a neutron and simultaneously causes the emission of an electron neutrino.

<span class="mw-page-title-main">Nuclide</span> Atomic species

A nuclide is a class of atoms characterized by their number of protons, Z, their number of neutrons, N, and their nuclear energy state.

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<span class="mw-page-title-main">Mass number</span> Number of heavy particles in the atomic nucleus

The mass number (symbol A, from the German word: Atomgewicht, "atomic weight"), also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is approximately equal to the atomic (also known as isotopic) mass of the atom expressed in atomic mass units. Since protons and neutrons are both baryons, the mass number A is identical with the baryon number B of the nucleus (and also of the whole atom or ion). The mass number is different for each isotope of a given chemical element, and the difference between the mass number and the atomic number Z gives the number of neutrons (N) in the nucleus: N = AZ.

<span class="mw-page-title-main">Double beta decay</span> Type of radioactive decay

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Technetium (43Tc) is one of the two elements with Z < 83 that have no stable isotopes; the other such element is promethium. It is primarily artificial, with only trace quantities existing in nature produced by spontaneous fission or neutron capture by molybdenum. The first isotopes to be synthesized were 97Tc and 99Tc in 1936, the first artificial element to be produced. The most stable radioisotopes are 97Tc, 98Tc, and 99Tc.

Neptunium (93Np) is usually considered an artificial element, although trace quantities are found in nature, so a standard atomic weight cannot be given. Like all trace or artificial elements, it has no stable isotopes. The first isotope to be synthesized and identified was 239Np in 1940, produced by bombarding 238
U
with neutrons to produce 239
U
, which then underwent beta decay to 239
Np
.

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<span class="mw-page-title-main">Neutron number</span> The number of neutrons in a nuclide

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<span class="mw-page-title-main">Isotope</span> Different atoms of the same element

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References

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