Melinda H. Keefe

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Melinda H. Keefe
Melinda H. Keefe CHF-Innovation-Day-2017 005.jpg
Melinda H. Keefe, Innovation Day, 2017
NationalityAmerican
Alma mater Pennsylvania State University, Northwestern University
Awards Gordon E. Moore Medal (SCI)
Scientific career
FieldsArchitectural coatings, Art conservation science
Institutions Dow Chemical Company

Melinda H. Keefe is a research and development director at the Dow Chemical Company, where she works on architectural coatings. She helped to develop the award-winning Evoque pre-composite polymer platform, reducing TiO
2
usage.

Contents

Keefe also leads a collaborative project in which Dow works with art conservators at institutions such as the Tate Modern and the Getty Conservation Institute. Her work on wet cleaning systems has helped to identify solvents that conservators can use to remove dirt without damaging layers of paint. In 2012, Keefe identified a suitable solvent to repair Mark Rothko's vandalized painting Black on Maroon 1958. Keefe has received a number of awards including the 14th annual SCI Gordon E. Moore Medal.

Education

Melinda H. Keefe was initially an art major, [1] [2] before earning a B.S. in chemistry at Pennsylvania State University (1997) and a Ph.D. in inorganic chemistry at Northwestern University (2001). [3]

Research

Keefe has published in the areas of polymer synthesis, paint formulation, high-throughput coatings, and art conservation science. [1] [2] and has applied for a number of patents. [4]

Architectural coatings

Keefe joined Dow in 2001, [5] and is now an R&D manager, specializing in the development of architectural coatings. These include the Evoque pre-composite polymer platform. [6] The Evoque polymer encapsulates titanium dioxide to more evenly distribute TiO
2
within coatings. [7] This improves the hiding efficiency of the coating (its ability to cover the color of the base material to which the coating is applied). Less TiO
2
, often the most expensive and energy-intensive component of a coating, is required. Evoque received the 2013 Greener Reaction Conditions Award in the EPA's Presidential Green Chemistry Challenge for industrial contributions to green science. [8] [9] [1] The Dow Coatings Team, including Keefe, received the 2017 "Heroes of Chemistry" Award from the American Chemical Society for the development of Evoque. [10]

Art restoration

In 2005, treatments for the conservation of modern and contemporary paintings were described as an area "in desperate need of research and focus". [11] In 2008 Keefe began a partnership with Dow, the Tate and the Getty Conservation Institute to work on the development of specialized solvents for use by art conservators. [12] [1] Keefe helped to develop wet cleaning systems for the identification of possible cleaning liquids capable of removing surface dirt without damaging multiple paint layers. [13] Dow provided high-throughput (HTP) analytical devices for the rapid screening of potential cleaning solutions, varying the percentage of each additive and monitoring factors such as paint gloss, color, flexibility, migrated surfactant removal and residue detection. [11]

“One of the challenges about art conservation is that every piece is different, each has its own mixtures in terms of raw materials and what it has been exposed to,” explained Keefe. “There is not going to be one perfect solution, but we could find one that is well suited for your needs. You don’t want to do anything that will harm the painting or the integrity of the art.” [14]

In 2012, after Mark Rothko's painting Black on Maroon 1958 was damaged by a vandal using black graffiti ink, Keefe helped identify ethyl lactate as a suitable solvent for use in its restoration. After 18 months of work, the painting returned to display at London’s Tate Modern gallery in May, 2014. [12] [15] [1]

Awards

Related Research Articles

<span class="mw-page-title-main">Paint</span> Pigment applied over a surface that dries as a solid film

Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many colors—and in many different types. Paint is typically stored, sold, and applied as a liquid, but most types dry into a solid. Most paints are either oil-based or water-based and each has distinct characteristics. For one, it is illegal in most municipalities to discard oil-based paint down household drains or sewers. Clean-up solvents are also different for water-based paint than they are for oil-based paint. Water-based paints and oil-based paints will cure differently based on the outside ambient temperature of the object being painted Usually, the object being painted must be over 10 °C (50 °F), although some manufacturers of external paints/primers claim they can be applied when temperatures are as low as 2 °C (35 °F).

<span class="mw-page-title-main">Varnish</span> Transparent hard protective finish or film

Varnish is a clear transparent hard protective coating or film. It is not a stain. It usually has a yellowish shade due to the manufacturing process and materials used, but it may also be pigmented as desired. It is sold commercially in various shades.

Green chemistry, also called sustainable chemistry, is an area of chemistry and chemical engineering focused on the design of products and processes that minimize or eliminate the use and generation of hazardous substances. While environmental chemistry focuses on the effects of polluting chemicals on nature, green chemistry focuses on the environmental impact of chemistry, including lowering consumption of nonrenewable resources and technological approaches for preventing pollution.

<span class="mw-page-title-main">Primer (paint)</span> Preparatory coating put on materials before painting

A primer or undercoat is a preparatory coating put on materials before painting. Priming ensures better adhesion of paint to the surface, increases paint durability, and provides additional protection for the material being painted.

Polyvinylidene chloride, or polyvinylidene dichloride (PVDC), is a homopolymer of vinylidene chloride.

<span class="mw-page-title-main">Conservation science (cultural property)</span>

With respect to cultural property, conservation science is the interdisciplinary study of the conservation of art, architecture, technical art history and other cultural works through the use of scientific inquiry. General areas of research include the technology and structure of artistic and historic works. In other words, the materials and techniques from which cultural, artistic and historic objects are made.

An anti-graffiti coating is a coating that prevents graffiti paint from bonding to surfaces.

<span class="mw-page-title-main">Conservation and restoration of silver objects</span>

The conservation and restoration of silver objects is an activity dedicated to the preservation and protection of objects of historical and personal value made from silver. When applied to cultural heritage this activity is generally undertaken by a conservator-restorer.

<span class="mw-page-title-main">Conservation and restoration of ceramic objects</span>

Conservation and restoration of ceramic objects is a process dedicated to the preservation and protection of objects of historical and personal value made from ceramic. Typically, this activity of conservation-restoration is undertaken by a conservator-restorer, especially when dealing with an object of cultural heritage. Ceramics are created from a production of coatings of inorganic, nonmetallic materials using heating and cooling to create a glaze. These coatings are often permanent and sustainable for utilitarian and decorative purposes. The cleaning, handling, storage, and in general treatment of ceramics is consistent with that of glass because they are made of similar oxygen-rich components, such as silicates. In conservation ceramics are broken down into three groups: unfired clay, earthenware or terracotta, and stoneware and porcelain.

<span class="mw-page-title-main">Conservation and restoration of iron and steel objects</span>

Iron, steel, and ferrous metals constitute a large portion of collections in museums. The conservation and restoration of iron and steel objects is an activity dedicated to the preservation and protection of objects of historical and personal value made from iron or steel. When applied to cultural heritage this activity is generally undertaken by a conservator-restorer. Historically, objects made from iron or steel were created for religious, artistic, technical, military and domestic uses. Though it is generally not possible to completely halt deterioration of any object, the act of conservation and restoration strives to prevent and slow the deterioration of the object as well as protecting the object for future use. One of the first steps in caring for iron is to examine them and determine their state, determine if they are corroding, and consider options for treatment.

<i>Black on Maroon</i> Painting by Mark Rothko

Black on Maroon is a mixed media painting by Mark Rothko, created in 1958. It is housed at the Tate Modern, in London.

<span class="mw-page-title-main">Conservation and restoration of painting frames</span>

The conservation and restoration of painting frames is the process through which picture frames are preserved. Frame conservation and restoration includes general cleaning of the frame, as well as in depth processes such as replacing damaged ornamentation, gilding, and toning.

<span class="mw-page-title-main">Conservation and restoration of frescos</span> Art preservation techniques

The conservation and restoration of frescoes is the process of caring for and maintaining frescos, and includes documentation, examination, research, and treatment to insure their long-term viability, when desired.

The conservation and restoration of lacquerware prevents and mitigates deterioration or damage to objects made with lacquer. The two main types of lacquer are Asian, made with sap from the Urushi tree, and European, made with a variety of shellac and natural resins. Lacquer can be damaged by age, light, water, temperature, or damaged substrate.

<span class="mw-page-title-main">Conservation and restoration of paintings</span>

The conservation and restoration of paintings is carried out by professional painting conservators. Paintings cover a wide range of various mediums, materials, and their supports. Painting types include fine art to decorative and functional objects spanning from acrylics, frescoes, and oil paint on various surfaces, egg tempera on panels and canvas, lacquer painting, water color and more. Knowing the materials of any given painting and its support allows for the proper restoration and conservation practices. All components of a painting will react to its environment differently, and impact the artwork as a whole. These material components along with collections care will determine the longevity of a painting. The first steps to conservation and restoration is preventive conservation followed by active restoration with the artist's intent in mind.

The conservation-restoration of panel paintings involves preventive and treatment measures taken by paintings conservators to slow deterioration, preserve, and repair damage. Panel paintings consist of a wood support, a ground, and an image layer. They are typically constructed of two or more panels joined together by crossbeam braces which can separate due to age and material instability caused by fluctuations in relative humidity and temperature. These factors compromise structural integrity and can lead to warping and paint flaking. Because wood is particularly susceptible to pest damage, an IPM plan and regulation of the conditions in storage and display are essential. Past treatments that have fallen out of favor because they can cause permanent damage include transfer of the painting onto a new support, planing, and heavy cradling. Today's conservators often have to remediate damage from previous restoration efforts. Modern conservation-restoration techniques favor minimal intervention that accommodates wood's natural tendency to react to environmental changes. Treatments may include applying flexible battens to minimize deformation or simply leaving distortions alone, instead focusing on preventive care to preserve the artwork in its original state.

The Modern and Contemporary Art Research Initiative is a program started by the Getty Conservation Institute (GCI). It began in 2007 in response to the variety of new materials and technologies being used by contemporary artists in their work, and the lack of known conservation treatments for these new materials. This area was seen as a gap in the field of conservation, but also posed unique challenges when considering the intention of the artist and the physical aging that his or her materials might endure. According to Thomas F. Reese, "Conservators...must enter into the critical spirit of the works themselves if they are to save and transmit not merely decontextualized fragments but their essence to the future."

Peter Trefonas is a retired DuPont Fellow at DuPont, where he had worked on the development of electronic materials. He is known for innovations in the chemistry of photolithography, particularly the development of anti-reflective coatings and polymer photoresists that are used to create circuitry for computer chips. This work has supported the patterning of smaller features during the lithographic process, increasing miniaturization and microprocessor speed.

<span class="mw-page-title-main">Gordon E. Moore Medal (SCI)</span> Award

The Gordon E. Moore Medal is an award given yearly by the Society of Chemical Industry to someone who has displayed early career success involving innovation in chemical industries. Success is judged in terms of both market impact and effects on quality of life of their work.

In the field of conservation and restoration of cultural property, greening practices such as sustainable materials use and disposal aim to improve the sustainability of conservation practice by choosing materials and methods that have a lower environmental impact and disposing of materials responsibly. When carrying out conservation treatments or preventive conservation, conservators use resources such as consumable materials, energy and water. These resources have an impact on the environment both through their extraction and disposal. In order to reduce this impact, conservators can choose sustainable alternatives to existing materials and practices such as reusable or recycled materials or materials with reduced toxicity.

References

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  3. 1 2 "Dow's Melinda H. Keefe Will Receive SCI Gordon E. Moore Medal". Chemical Processing. May 26, 2017. Retrieved 8 October 2017.
  4. "Patents by Inventor Melinda H. Keefe". Justia Patents. Retrieved 9 October 2017.
  5. 1 2 "ACS recognizes three Dow scientists as 2015 Rising Stars". Midland Daily News. November 15, 2014. Retrieved 8 October 2017.
  6. "Dow's Dr Melinda Keefe to receive SCI Gordon E Moore Medal". Polymers Paint Color Journal. Retrieved 8 October 2017.
  7. Klier, John; Bohling, James; Keefe, Melinda (July 2016). "Evolution of functional polymer colloids for coatings and other applications". AIChE Journal. 62 (7): 2238–2247. doi:10.1002/aic.15211.
  8. 1 2 Ritter, Stephen K. (December 16, 2013). "Greener Reaction Conditions Award: Dow Chemical Industry Giant Wins For Its Innovative Polymer-Based Technology That Reduces The Amount Of Titanium Dioxide Pigment Needed In Paint". Chemical & Engineering News. 91 (50): 5–10.
  9. 1 2 "Presidential Green Chemistry Challenge: 2013 Greener Reaction Conditions Award The Dow Chemical Company EVOQUE TM Pre-Composite Polymer Technology". United States Environmental Protection Agency (EPA). Retrieved 8 October 2017.
  10. 1 2 "Dow Coatings Team Receives Chemistry Honor". Paint Square. May 16, 2017. Retrieved 8 October 2017.
  11. 1 2 Ormsby, Bronwyn; Learner, Tom (Fall 2016). "Recent Developments in the Cleaning of Modern Paints". Conservation Perspectives. 31 (2). Retrieved 9 October 2017.
  12. 1 2 3 Dunn, Catherine (2014). "Melinda Keefe, Ph.D." Heroes of the 500. Fortune 500. Retrieved 8 October 2017.
  13. Ormsby, Bronwyn; Phenix, Alan (Fall 2009). "Cleaning Acrylic Emulsion Paintings". Conservation Perspectives. 24 (2). Retrieved 9 October 2017.
  14. Scott, Maiken (July 16, 2015). "Scientist applies her skills to understand art's true chemistry". WHYY. Retrieved 10 October 2017.
  15. Sherwin, Adam (14 May 2014). "Vandalised Rothko painting back on display at Tate Modern after 18-month repair job" . The Independent. Archived from the original on 2022-05-12. Retrieved 27 May 2014.
  16. "Award Winners & Finalists, 2013". R&D 100 Conference. Retrieved 9 October 2017.
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  18. "SCI Gordon E. Moore Medal". Science History Institute .