A Penning mixture is a mixture of gases that is used in electric gas-discharge lamps. It is defined as a mixture of one inert gas with a minute amount of another gas, one that has lower ionization voltage than the main constituent. It is named after Frans Michel Penning. [1] [2]
The well-known neon lighting and neon lamps and displays are filled not with pure neon, but with a Penning mixture.
The other gas, called a quenching gas, has to have a lower ionization energy than the first excited state of the noble gas. The energy of the excited, but neutral, noble gas atoms then can ionize the quench gas particles by energy transfer via collisions; known as the Penning effect.
A very common Penning mixture of about 98–99.5% of neon with 0.5–2% argon is used in some neon lamps, especially those rated for 120 volts. The mixture is easier to ionize than either neon or argon alone, and lowers the breakdown voltage at which the tube becomes conductive and starts producing light. The optimal level of argon is about 0.25%, but some of it gets adsorbed onto the borosilicate glass used for the tubes, so higher concentrations are used to take the losses into account; higher argon content is used in higher-power tubes, as hotter glass adsorbs more argon. The argon changes the color of the "neon light", making it slightly more yellowish. The neon gas used in some nixie tubes includes a small amount of mercury vapor (for various reasons), which glows blue.
A Penning mixture of neon and argon is also used as a starter gas in sodium vapor lamps, where it is responsible for the faint pinkish glow before the sodium emission begins.
The Penning mixture used in plasma displays is usually helium or neon with small percentage of xenon, at several hundred torr.
Penning mixtures with the formulas of argon–xenon, neon–argon, argon–acetylene, and xenon–TMA are used as filler gases in gaseous ionization detectors.
Other kinds of Penning mixture include helium–xenon.
Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of air.
The Geiger–Müller tube or G–M tube is the sensing element of the Geiger counter instrument used for the detection of ionizing radiation. It is named after Hans Geiger, who invented the principle in 1908, and Walther Müller, who collaborated with Geiger in developing the technique further in 1928 to produce a practical tube that could detect a number of different radiation types.
A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, which produces short-wave ultraviolet light that then causes a phosphor coating on the inside of the lamp to glow. A fluorescent lamp converts electrical energy into useful light much more efficiently than an incandescent lamp, but is less efficient than most LED lamps. The typical luminous efficacy of fluorescent lighting systems is 50–100 lumens per watt, several times the efficacy of incandescent bulbs with comparable light output. For comparison, the luminous efficiency of an incandescent bulb may only be 16 lumens per watt.
A cold cathode is a cathode that is not electrically heated by a filament. A cathode may be considered "cold" if it emits more electrons than can be supplied by thermionic emission alone. It is used in gas-discharge lamps, such as neon lamps, discharge tubes, and some types of vacuum tube. The other type of cathode is a hot cathode, which is heated by electric current passing through a filament. A cold cathode does not necessarily operate at a low temperature: it is often heated to its operating temperature by other methods, such as the current passing from the cathode into the gas.
A neon lamp is a miniature gas-discharge lamp. The lamp typically consists of a small glass capsule that contains a mixture of neon and other gases at a low pressure and two electrodes. When sufficient voltage is applied and sufficient current is supplied between the electrodes, the lamp produces an orange glow discharge. The glowing portion in the lamp is a thin region near the cathode; the larger and much longer neon signs are also glow discharges, but they use the positive column which is not present in the ordinary neon lamp. Neon glow lamps were widely used as indicator lamps in the displays of electronic instruments and appliances. They are still sometimes used for their electrical simplicity in high-voltage circuits.
In the signage industry, neon signs are electric signs lighted by long luminous gas-discharge tubes that contain rarefied neon or other gases. They are the most common use for neon lighting, which was first demonstrated in a modern form in December 1910 by Georges Claude at the Paris Motor Show. While they are used worldwide, neon signs were popular in the United States from about the 1920s to 1950s. The installations in Times Square, many originally designed by Douglas Leigh, were famed, and there were nearly 2,000 small shops producing neon signs by 1940. In addition to signage, neon lighting is used frequently by artists and architects, and in plasma display panels and televisions. The signage industry has declined in the past several decades, and cities are now concerned with preserving and restoring their antique neon signs.
A gas-filled tube, also commonly known as a discharge tube or formerly as a Plücker tube, is an arrangement of electrodes in a gas within an insulating, temperature-resistant envelope. Gas-filled tubes exploit phenomena related to electric discharge in gases, and operate by ionizing the gas with an applied voltage sufficient to cause electrical conduction by the underlying phenomena of the Townsend discharge. A gas-discharge lamp is an electric light using a gas-filled tube; these include fluorescent lamps, metal-halide lamps, sodium-vapor lamps, and neon lights. Specialized gas-filled tubes such as krytrons, thyratrons, and ignitrons are used as switching devices in electric devices.
A sodium-vapor lamp is a gas-discharge lamp that uses sodium in an excited state to produce light at a characteristic wavelength near 589 nm.
A glow discharge is a plasma formed by the passage of electric current through a gas. It is often created by applying a voltage between two electrodes in a glass tube containing a low-pressure gas. When the voltage exceeds a value called the striking voltage, the gas ionization becomes self-sustaining, and the tube glows with a colored light. The color depends on the gas used.
A plasma ball, plasma globe, or plasma lamp is a clear glass container filled with noble gases, usually a mixture of neon, krypton, and xenon, that has a high-voltage electrode in the center of the container. When voltage is applied, a plasma is formed within the container. Plasma filaments extend from the inner electrode to the outer glass insulator, giving the appearance of multiple constant beams of colored light. Plasma balls were popular as novelty items in the 1980s.
High-intensity discharge lamps are a type of electrical gas-discharge lamp which produces light by means of an electric arc between tungsten electrodes housed inside a translucent or transparent fused quartz or fused alumina arc tube. This tube is filled with noble gas and often also contains suitable metal or metal salts. The noble gas enables the arc's initial strike. Once the arc is started, it heats and evaporates the metallic admixture. Its presence in the arc plasma greatly increases the intensity of visible light produced by the arc for a given power input, as the metals have many emission spectral lines in the visible part of the spectrum. High-intensity discharge lamps are a type of arc lamp.
A Geissler tube is a precursor to modern gas discharge tubes, demonstrating the principles of electrical glow discharge, akin to contemporary neon lights, and central to the discovery of the electron. This device was developed in 1857 by Heinrich Geissler, a German physicist and glassblower. A Geissler tube is composed of a sealed glass cylinder of various shapes, which is partially evacuated and equipped with a metal electrode at each end. It contains rarefied gases—such as neon or argon, air, mercury vapor, or other conductive substances, and sometimes ionizable minerals or metals like sodium. When a high voltage is applied between the electrodes, there is an electric current through the tube, causing gas molecules to ionize by shedding electrons. The free electrons reunite with the ions and the resulting energic atoms emit light via fluorescence, with the emitted color characteristic of the contained material.
A mercury-vapor lamp is a gas-discharge lamp that uses an electric arc through vaporized mercury to produce light. The arc discharge is generally confined to a small fused quartz arc tube mounted within a larger soda lime or borosilicate glass bulb. The outer bulb may be clear or coated with a phosphor; in either case, the outer bulb provides thermal insulation, protection from the ultraviolet radiation the light produces, and a convenient mounting for the fused quartz arc tube.
A metal-halide lamp is an electrical lamp that produces light by an electric arc through a gaseous mixture of vaporized mercury and metal halides. It is a type of high-intensity discharge (HID) gas discharge lamp. Developed in the 1960s, they are similar to mercury vapor lamps, but contain additional metal halide compounds in the quartz arc tube, which improve the efficiency and color rendition of the light. The most common metal halide compound used is sodium iodide. Once the arc tube reaches its running temperature, the sodium dissociates from the iodine, adding orange and reds to the lamp's spectrum from the sodium D line as the metal ionizes. As a result, metal-halide lamps have high luminous efficacy of around 75–100 lumens per watt, which is about twice that of mercury vapor lights and 3 to 5 times that of incandescent lights and produce an intense white light. Lamp life is 6,000 to 15,000 hours. As one of the most efficient sources of high CRI white light, metal halides as of 2005 were the fastest growing segment of the lighting industry. They are used for wide area overhead lighting of commercial, industrial, and public places, such as parking lots, sports arenas, factories, and retail stores, as well as residential security lighting, automotive headlamps and indoor cannabis grow operations.
The induction lamp, electrodeless lamp, or electrodeless induction lamp is a gas-discharge lamp in which an electric or magnetic field transfers the power required to generate light from outside the lamp envelope to the gas inside. This is in contrast to a typical gas discharge lamp that uses internal electrodes connected to the power supply by conductors that pass through the lamp envelope. Eliminating the internal electrodes provides two advantages:
An ion laser is a gas laser that uses an ionized gas as its lasing medium. Like other gas lasers, ion lasers feature a sealed cavity containing the laser medium and mirrors forming a Fabry–Pérot resonator. Unlike helium–neon lasers, the energy level transitions that contribute to laser action come from ions. Because of the large amount of energy required to excite the ionic transitions used in ion lasers, the required current is much greater, and as a result almost all except for the smallest ion lasers are water-cooled. A small air-cooled ion laser might produce, for example, 130 milliwatts of output light with a tube current of about 10 amperes and a voltage of 105 volts. Since one ampere times one volt is one watt, this is an electrical power input of about one kilowatt. Subtracting the (desirable) light output of 130 mW from power input, this leaves the large amount of waste heat of nearly one kW. This has to be dissipated by the cooling system. In other words, the power efficiency is very low.
Gas-discharge lamps are a family of artificial light sources that generate light by sending an electric discharge through an ionized gas, a plasma.
Penning ionization is a form of chemi-ionization, an ionization process involving reactions between neutral atoms or molecules. The Penning effect is put to practical use in applications such as gas-discharge neon lamps and fluorescent lamps, where the lamp is filled with a Penning mixture to improve the electrical characteristics of the lamps.
Frans Michel Penning was a Dutch experimental physicist. He received his PhD from the University of Leiden in 1923, and studied low pressure gas discharges at the Philips Laboratory in Eindhoven, developing new electron tubes during World War II. Many detailed observations of gas ionization were done with colleagues, finding notable results for helium and magnetic fields. He made precise measurements of Townsend discharge coefficients and cathode voltage fall. Penning made important contributions to the advancement of high resolution mass spectrometry.
Electric discharge in gases occurs when electric current flows through a gaseous medium due to ionization of the gas. Depending on several factors, the discharge may radiate visible light. The properties of electric discharges in gases are studied in connection with design of lighting sources and in the design of high voltage electrical equipment.