Rubidium bromide

Last updated
Rubidium bromide
Rubidium-bromide-3D-ionic.png
Names
IUPAC name
Rubidium bromide
Other names
Rubidium(I) bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.238 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • InChI=1S/BrH.Rb/h1H;/q;+1/p-1 Yes check.svgY
    Key: JAAGVIUFBAHDMA-UHFFFAOYSA-M Yes check.svgY
  • InChI=1/BrH.Rb/h1H;/q;+1/p-1
    Key: JAAGVIUFBAHDMA-REWHXWOFAB
  • [Rb+].[Br-]
Properties
RbBr
Molar mass 165.372 g/mol
Appearancewhite crystalline solid
Density 3.350 g/cm3
Melting point 693 °C (1,279 °F; 966 K)
Boiling point 1,340 °C (2,440 °F; 1,610 K)
98 g/100 mL
56.4·10−6 cm3/mol
Hazards
Flash point Non-flammable
Related compounds
Other anions
Rubidium fluoride
Rubidium chloride
Rubidium iodide
Rubidium astatide
Other cations
Lithium bromide
Sodium bromide
Potassium bromide
Caesium bromide
Francium bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Rubidium bromide is an inorganic compound with the chemical formula Rb Br . It is a salt of hydrogen bromide. It consists of bromide anions Br and rubidium cations Rb+. It has a NaCl crystal structure, with a lattice constant of 685 picometres. [1]

There are several methods for synthesising rubidium bromide. One involves reacting rubidium hydroxide with hydrobromic acid:

RbOH + HBr → RbBr + H2O

Another method is to neutralize rubidium carbonate with hydrobromic acid:

Rb2CO3 + 2 HBr → 2 RbBr + H2O + CO2

Rubidium metal would react directly with bromine to form RbBr, but this is not a sensible production method, since rubidium metal is substantially more expensive than the carbonate or hydroxide; moreover, the reaction would be explosive.

Related Research Articles

<span class="mw-page-title-main">Bromine</span> Chemical element, symbol Br and atomic number 35

Bromine is a chemical element; it has symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig and Antoine Jérôme Balard, its name was derived from the Ancient Greek βρῶμος (bromos) meaning "stench", referring to its sharp and pungent smell.

Hydrobromic acid is an aqueous solution of hydrogen bromide. It is a strong acid formed by dissolving the diatomic molecule hydrogen bromide (HBr) in water. "Constant boiling" hydrobromic acid is an aqueous solution that distills at 124.3 °C (255.7 °F) and contains 47.6% HBr by mass, which is 8.77 mol/L. Hydrobromic acid is one of the strongest mineral acids known.

<span class="mw-page-title-main">Hydrogen bromide</span> Chemical compound

Hydrogen bromide is the inorganic compound with the formula HBr. It is a hydrogen halide consisting of hydrogen and bromine. A colorless gas, it dissolves in water, forming hydrobromic acid, which is saturated at 68.85% HBr by weight at room temperature. Aqueous solutions that are 47.6% HBr by mass form a constant-boiling azeotrope mixture that boils at 124.3 °C (255.7 °F). Boiling less concentrated solutions releases H2O until the constant-boiling mixture composition is reached.

A bromide ion is the negatively charged form (Br) of the element bromine, a member of the halogens group on the periodic table. Most bromides are colorless. Bromides have many practical roles, being found in anticonvulsants, flame-retardant materials, and cell stains. Although uncommon, chronic toxicity from bromide can result in bromism, a syndrome with multiple neurological symptoms. Bromide toxicity can also cause a type of skin eruption, see potassium bromide. The bromide ion has an ionic radius of 196 pm.

<span class="mw-page-title-main">Rubidium nitrate</span> Chemical compound RbNO3

Rubidium nitrate is an inorganic compound with the formula RbNO3. This alkali metal nitrate salt is white and highly soluble in water.

<span class="mw-page-title-main">Lithium bromide</span> Chemical compound

Lithium bromide (LiBr) is a chemical compound of lithium and bromine. Its extreme hygroscopic character makes LiBr useful as a desiccant in certain air conditioning systems.

Cyanogen bromide is the inorganic compound with the formula (CN)Br or BrCN. It is a colorless solid that is widely used to modify biopolymers, fragment proteins and peptides, and synthesize other compounds. The compound is classified as a pseudohalogen.

<span class="mw-page-title-main">Rubidium fluoride</span> Chemical compound

Rubidium fluoride (RbF) is the fluoride salt of rubidium. It is a cubic crystal with rock-salt structure.

<span class="mw-page-title-main">Zinc bromide</span> Chemical compound

Zinc bromide (ZnBr2) is an inorganic compound with the chemical formula ZnBr2. It is a colourless salt that shares many properties with zinc chloride (ZnCl2), namely a high solubility in water forming acidic solutions, and good solubility in organic solvents. It is hygroscopic and forms a dihydrate ZnBr2·2H2O.

Bromine compounds are compounds containing the element bromine (Br). These compounds usually form the -1, +1, +3 and +5 oxidation states. Bromine is intermediate in reactivity between chlorine and iodine, and is one of the most reactive elements. Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X2/X couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V). Bromination often leads to higher oxidation states than iodination but lower or equal oxidation states to chlorination. Bromine tends to react with compounds including M–M, M–H, or M–C bonds to form M–Br bonds.

<span class="mw-page-title-main">Iron(II) bromide</span> Chemical compound

Iron(II) bromide refers to inorganic compounds with the chemical formula FeBr2(H2O)x. The anhydrous compound (x = 0) is a yellow or brownish-colored paramagnetic solid. The tetrahydrate is also known, all being pale colored solids. They are common precursor to other iron compounds.

<span class="mw-page-title-main">Allyl bromide</span> Chemical compound

Allyl bromide (3-bromopropene) is an organic halide. It is an alkylating agent used in synthesis of polymers, pharmaceuticals, synthetic perfumes and other organic compounds. Physically, allyl bromide is a colorless liquid with an irritating and persistent smell, however, commercial samples are yellow or brown. Allyl bromide is more reactive but more expensive than allyl chloride, and these considerations guide its use.

<span class="mw-page-title-main">Strontium bromide</span> Chemical compound

Strontium bromide is a chemical compound with a formula SrBr2. At room temperature it is a white, odourless, crystalline powder. Strontium bromide imparts a bright red colour in a flame test, showing the presence of strontium ions. It is used in flares and also has some pharmaceutical uses.

<span class="mw-page-title-main">Tetraethylammonium bromide</span> Chemical compound

Tetraethylammonium bromide (TEAB) is a quaternary ammonium compound with the chemical formula C8H20N+Br, often written as "Et4N+Br" in the chemical literature. It has been used as the source of tetraethylammonium ions in pharmacological and physiological studies, but is also used in organic chemical synthesis.

<span class="mw-page-title-main">Barium bromide</span> Chemical compound

Barium bromide is the chemical compound with the formula BaBr2. It is ionic and hygroscopic in nature.

<span class="mw-page-title-main">Beryllium bromide</span> Chemical compound

Beryllium bromide is the chemical compound with the formula BeBr2. It is very hygroscopic and dissolves well in water. The compound is a polymer with tetrahedral coordinated Be centres.

<span class="mw-page-title-main">Rubidium iodide</span> Chemical compound

Rubidium iodide is a salt of rubidium and iodine, with the chemical formula RbI. It is a white solid with a melting point of 642 °C.

<span class="mw-page-title-main">Bromous acid</span> Chemical compound

Bromous acid is the inorganic compound with the formula of HBrO2. It is an unstable compound, although salts of its conjugate base – bromites – have been isolated. In acidic solution, bromites decompose to bromine.

An yttrium compound is a chemical compound containing yttrium. Among these compounds, yttrium generally has a +3 valence. The solubility properties of yttrium compounds are similar to those of the lanthanides. For example oxalates and carbonates are hardly soluble in water, but soluble in excess oxalate or carbonate solutions as complexes are formed. Sulfates and double sulfates are generally soluble. They resemble the "yttrium group" of heavy lanthanide elements.

References

  1. G. Chern; J. G. Skofronick; W. P. Brug; S. A. Safron (1989). "Surface phonon modes of the RbBr(001) crystal surface by inelastic He-atom scattering". Phys. Rev. B. 39 (17): 12838–12844. doi:10.1103/PhysRevB.39.12838. PMID   9948158.