Antiwear additive

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AW additives, or antiwear additives, are additives for lubricants to prevent metal-to-metal contact between parts of gears. [1]

Contents

EP additives are used in applications such as gearboxes, while AW additives are used with lighter loads such as bushings.

Details

Some popular AW additives are:

Some formulations use colloidal PTFE (Teflon), but its efficiency is controversial.

Many AW additives function as EP additives, for example organophosphates or sulfur compounds. The mechanism of function of TCP and ZDDP is explained in EP additives.

Under extreme pressure conditions, the performance of AW additives becomes insufficient and designated EP additives are required.

See also

Related Research Articles

A lubricant is a substance, usually organic, introduced to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, transporting foreign particles, or heating or cooling the surfaces. The property of reducing friction is known as lubricity.

Motor oil Lubricant used for lubrication of internal combustion engines

Motor oil, engine oil, or engine lubricant is any one of various substances that consist of base oils enhanced with various additives, particularly antiwear additives, detergents, dispersants, and, for multi-grade oils, viscosity index improvers. Motor oil is used for lubrication of internal combustion engines. The main function of motor oil is to reduce friction and wear on moving parts and to clean the engine from sludge and varnish (detergents). It also neutralizes acids that originate from fuel and from oxidation of the lubricant (detergents), improves sealing of piston rings, and cools the engine by carrying heat away from moving parts.

Hydraulic fluid

A hydraulic fluid or hydraulic liquid is the medium by which power is transferred in hydraulic machinery. Common hydraulic fluids are based on mineral oil or water. Examples of equipment that might use hydraulic fluids are excavators and backhoes, hydraulic brakes, power steering systems, transmissions, garbage trucks, aircraft flight control systems, lifts, and industrial machinery.

Cutting fluid

Cutting fluid is a type of coolant and lubricant designed specifically for metalworking processes, such as machining and stamping. There are various kinds of cutting fluids, which include oils, oil-water emulsions, pastes, gels, aerosols (mists), and air or other gases. Cutting fluids are made from petroleum distillates, animal fats, plant oils, water and air, or other raw ingredients. Depending on context and on which type of cutting fluid is being considered, it may be referred to as cutting fluid, cutting oil, cutting compound, coolant, or lubricant.

Synthetic oil

Synthetic oil is a lubricant consisting of chemical compounds that are artificially made. Synthetic lubricants can be manufactured using chemically modified petroleum components rather than whole crude oil, but can also be synthesized from other raw materials. The base material, however, is still overwhelmingly crude oil that is distilled and then modified physically and chemically. The actual synthesis process and composition of additives is generally a commercial trade secret and will vary among producers.

Timken OK Load is a standardized measurement that indicates the possible performance of extreme pressure (EP) additives in a lubricating grease or oil. The units of measurement are pounds-force or kilograms-force. This measurement is performed using a special test machine and standard block and ring test specimens.

Gear oil

Gear oil is a lubricant made specifically for transmissions, transfer cases, and differentials in automobiles, trucks, and other machinery. It is of a high viscosity and usually contains organosulfur compounds. Some modern automatic transaxles do not use a heavy oil at all but lubricate with the lower viscosity hydraulic fluid, which is available at pressure within the automatic transmission. Gear oils account for about 20% of the lubricant market.

A coolant is a substance, typically liquid or gas, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosion of the cooling system. Some applications also require the coolant to be an electrical insulator.

The viscosity index (VI) is an arbitrary, unit-less measure of a fluid's change in viscosity relative to temperature change. It is mostly used to characterize the viscosity-temperature behavior of lubricating oils. The lower the VI, the more the viscosity is affected by changes in temperature. The higher the VI, the more stable the viscosity remains over temperature fluctuations. The VI was originally measured on a scale from 0 to 100; however, advancements in lubrication science have led to the development of oils with much higher VIs.

Grease is a solid or semisolid lubricant formed as a dispersion of thickening agents in a liquid lubricant. Grease generally consists of a soap emulsified with mineral or vegetable oil.

Extreme pressure additive

Extreme pressure additives, or EP additives, are additives for lubricants with a role to decrease wear of the parts of the gears exposed to very high pressures. They are also added to cutting fluids for machining of metals.

Zinc dithiophosphate Lubricant additive

Zinc dialkyldithiophosphates are a family of coordination compounds developed in the 1940s that feature zinc bound to the anion of a dialkyldithiophosphoric acid. These uncharged compounds are not salts. They are soluble in nonpolar solvents, and the longer-chain derivatives easily dissolve in mineral and synthetic oils used as lubricants. They come under CAS number 68649-42-3. In aftermarket oil additives, the percentage of ZDDP ranges approximately between 2 and 15%. Zinc dithiophosphates have many names, including ZDDP, ZnDTP, and ZDP.

Phosphate coating is used on steel parts for corrosion resistance, lubrication, or as a foundation for subsequent coatings or painting. It serves as a conversion coating in which a dilute solution of phosphoric acid and phosphate salts is applied via spraying or immersion and chemically reacts with the surface of the part being coated to form a layer of insoluble, crystalline phosphates. Phosphate conversion coatings can also be used on aluminium, zinc, cadmium, silver and tin.

Friction modifiers are added to lubricants in order to reduce friction and wear in machine components. They are particularly important in the boundary lubrication regime, where they can prevent solid surfaces from coming into direct contact, substantially reducing friction and wear.

Shell Rotella T is a line of heavy duty engine lubrication products produced by Royal Dutch Shell. The line includes engine oils, gear oils and coolants. The oil carries both the American Petroleum Institute (API) diesel "C" rating as well as the API gasoline engine "S" rating. Ratings differ based on the oil. Rotella oils like T3 15w-40 meets both the API CJ-4 and SM specifications, and may be used in both gasoline and diesel engines. However, it is formulated specifically for vehicles without catalytic converters, containing phosphorus levels beyond the 600-800ppm range. Therefore, Rotella is not recommended for gasoline vehicles with catalytic converters due to the higher risk of damaging these emission controls. Newer formulations of Rotella T6 however are API SM rated as safe for pre-2011 gasoline vehicles.

Oil additives are chemical compounds that improve the lubricant performance of base oil. The manufacturer of many different oils can utilize the same base stock for each formulation and can choose different additives for each specific application. Additives comprise up to 5% by weight of some oils.

Dry lubricants or solid lubricants are materials that, despite being in the solid phase, are able to reduce friction between two surfaces sliding against each other without the need for a liquid oil medium.

Automotive oil recycling

Automotive oil recycling involves the recycling of used oils and the creation of new products from the recycled oils, and includes the recycling of motor oil and hydraulic oil. Oil recycling also benefits the environment: increased opportunities for consumers to recycle oil lessens the likelihood of used oil being dumped on lands and in waterways. For example, one gallon of motor oil dumped into waterways has the potential to pollute one million gallons of water.

Marvel Mystery Oil

Marvel Mystery Oil is an automotive product of the American Marvel Oil Company, founded by Burt Pierce in 1923. It is used as a fuel additive, oil additive, corrosion inhibitor, penetrating oil, and transmission leak stopper and seal relubricator.

References

  1. Rudnick, Leslie R. (2009-04-20). Lubricant Additives: Chemistry and Applications, Second Edition. CRC Press. ISBN   9781420059656.
  2. Fuels and Lubricants Handbook. ASTM International.