CR-39

Last updated
Poly(allyl diglycol carbonate)
PADC neu.svg
Polymer structure
Names
Other names
2,5,8,10-Tetraoxatridec-12-enoic acid, 9-oxo-, 2-propen-1-yl ester, homopolymer
Identifiers
AbbreviationsPADC
Properties
Density 1.31
1.498
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Diallyl diglycol carbonate
ADC.svg
Monomer structure
Names
IUPAC name
2-(2-prop-2-enoxycarbonyloxyethoxy)ethyl prop-2-enyl carbonate
Other names
allyl diglycol carbonate (ADC); diethyleneglycol bis allylcarbonate
Identifiers
PubChem CID
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
A piece of CR-39 manufactured for radiation detection Circular CR-39.jpg
A piece of CR-39 manufactured for radiation detection

Poly(allyl diglycol carbonate) (PADC) is a plastic commonly used in the manufacture of eyeglass lenses alongside the material PMMA (polymethyl methacrylate). The monomer is allyl diglycol carbonate (ADC). The term CR-39 technically refers to the ADC monomer, but is more commonly used to refer to the finished plastic.

Contents

The abbreviation stands for "Columbia Resin #39", which was the 39th formula of a thermosetting plastic developed by the Columbia Resins project in 1940. [1]

The first commercial use of CR-39 monomer (ADC) was to help create glass-reinforced plastic fuel tanks for the B-17 bomber aircraft in World War II, reducing the weight and increasing the range of the bomber. After the war, the Armorlite Lens Company in California is credited with manufacturing the first CR-39 eyeglass lenses in 1947. CR-39 plastic has an index of refraction of 1.498 and an Abbe number of 58. CR-39 is now a trade-marked product of PPG Industries. [2]

An alternative use includes a purified version that is used to measure neutron radiation, a type of ionizing radiation, in neutron dosimetry.

Although CR-39 is a type of polycarbonate, it should not be confused with the general term "polycarbonate", a tough homopolymer usually made from bisphenol A. [3]

Synthesis

CR-39 is made by polymerization of ADC in presence of diisopropyl peroxydicarbonate (IPP) initiator. The presence of the allyl groups allows the polymer to form cross-links; thus, it is a thermoset resin. The polymerization schedule of ADC monomers using IPP is generally 20 hours long with a maximum temperature of 95 °C. The elevated temperatures can be supplied using a water bath or a forced air oven.

Benzoyl peroxide (BPO) is an alternative organic peroxide that may be used to polymerize ADC. Pure benzoyl peroxide is crystalline and less volatile than diisopropyl peroxydicarbonate. Using BPO results in a polymer that has a higher yellowness index, and the peroxide takes longer to dissolve into ADC at room temperature than IPP.

Applications

Optics

CR-39 is transparent in the visible spectrum and is almost completely opaque in the ultraviolet range. [4] It has high abrasion resistance, in fact the highest abrasion/scratch resistance of any uncoated optical plastic. CR-39 is about half the weight of glass with an index of refraction only slightly lower than that of crown glass, and its high Abbe number yields low chromatic aberration, altogether making it an advantageous material for eyeglasses and sunglasses. A wide range of colors can be achieved by dyeing of the surface or the bulk of the material. CR-39 is also resistant to most solvents and other chemicals, gamma radiation, aging, and to material fatigue. It can withstand the small hot sparks from welding, something glass cannot do. It can be used continuously in temperatures up to 100 °C and up to one hour at 130 °C.[ citation needed ]

Radiation detection

Microscopic image of deuteron tracks in CR-39 Tracks in CR-39.jpg
Microscopic image of deuteron tracks in CR-39

In the radiation detection application, CR-39 is used as a solid-state nuclear track detector (SSNTD) to detect the presence of ionising radiation. Energetic particles colliding with the polymer structure leave a trail of broken chemical bonds within the CR-39. When immersed in a concentrated alkali solution (typically sodium hydroxide) hydroxide ions attack and break the polymer structure, etching away the bulk of the plastic at a nominally fixed rate. However, along the paths of damage left by charged particle interaction the concentration of radiation damage allows the chemical agent to attack the polymer more rapidly than it does in the bulk, revealing the paths of the charged particle ion tracks. The resulting etched plastic therefore contains a permanent record of not only the location of the radiation on the plastic but also gives spectroscopic information about the source. Principally used for the detection of alpha radiation emitting radionuclides (especially radon gas), the radiation-sensitivity properties of CR-39 are also used for proton and neutron dosimetry and historically cosmic ray investigations.

The ability of CR-39 to record the location of a radiation source, even at extremely low concentrations is exploited in autoradiography studies with alpha particles, [5] and for (comparatively cheap) detection of alpha-emitters like uranium. [6] Typically, a thin section of a biological material is fixed against CR-39 and kept frozen for a timescale of months to years in an environment that is shielded as much as possible from possible radiological contaminants. Before etching, photographs are taken of the biological sample with the affixed CR-39 detector, with care taken to ensure that prescribed location marks on the detector are noted. After the etching process, automated or manual 'scanning' of the CR-39 is used to physically locate the ionising radiation recorded, which can then be mapped to the position of the radionuclide within the biological sample. There is no other non-destructive method for accurately identifying the location of trace quantities of radionuclides in biological samples at such low emission levels.

See also

Related Research Articles

<span class="mw-page-title-main">Geiger counter</span> Instrument used for measuring ionizing radiation

A Geiger counter is an electronic instrument used for detecting and measuring ionizing radiation. It is widely used in applications such as radiation dosimetry, radiological protection, experimental physics and the nuclear industry.

<span class="mw-page-title-main">Neutron activation analysis</span> Method used for determining the concentrations of elements in many materials

Neutron activation analysis (NAA) is a nuclear process used for determining the concentrations of elements in many materials. NAA allows discrete sampling of elements as it disregards the chemical form of a sample, and focuses solely on atomic nuclei. The method is based on neutron activation and thus requires a neutron source. The sample is bombarded with neutrons, causing its constituent elements to form radioactive isotopes. The radioactive emissions and radioactive decay paths for each element have long been studied and determined. Using this information, it is possible to study spectra of the emissions of the radioactive sample, and determine the concentrations of the various elements within it. A particular advantage of this technique is that it does not destroy the sample, and thus has been used for the analysis of works of art and historical artifacts. NAA can also be used to determine the activity of a radioactive sample.

A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferred to one of its electrons to release it as a conversion electron; or used to create and emit a new particle (alpha particle or beta particle) from the nucleus. During those processes, the radionuclide is said to undergo radioactive decay. These emissions are considered ionizing radiation because they are energetic enough to liberate an electron from another atom. The radioactive decay can produce a stable nuclide or will sometimes produce a new unstable radionuclide which may undergo further decay. Radioactive decay is a random process at the level of single atoms: it is impossible to predict when one particular atom will decay. However, for a collection of atoms of a single nuclide the decay rate, and thus the half-life (t1/2) for that collection, can be calculated from their measured decay constants. The range of the half-lives of radioactive atoms has no known limits and spans a time range of over 55 orders of magnitude.

<span class="mw-page-title-main">Petrochemical</span> Chemical product derived from petroleum

Petrochemicals are the chemical products obtained from petroleum by refining. Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or renewable sources such as maize, palm fruit or sugar cane.

<span class="mw-page-title-main">Thermoplastic</span> Plastic that softens with heat and hardens on cooling

A thermoplastic, or thermosoftening plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling.

Radiation dosimetry in the fields of health physics and radiation protection is the measurement, calculation and assessment of the ionizing radiation dose absorbed by an object, usually the human body. This applies both internally, due to ingested or inhaled radioactive substances, or externally due to irradiation by sources of radiation.

<span class="mw-page-title-main">Polycarbonate</span> Family of polymers

Polycarbonates (PC) are a group of thermoplastic polymers containing carbonate groups in their chemical structures. Polycarbonates used in engineering are strong, tough materials, and some grades are optically transparent. They are easily worked, molded, and thermoformed. Because of these properties, polycarbonates find many applications. Polycarbonates do not have a unique resin identification code (RIC) and are identified as "Other", 7 on the RIC list. Products made from polycarbonate can contain the precursor monomer bisphenol A (BPA).

<span class="mw-page-title-main">Polyvinyl fluoride</span> Chemical compound

Polyvinyl fluoride (PVF) or –(CH2CHF)n– is a polymer material mainly used in the flammability-lowering coatings of airplane interiors and photovoltaic module backsheets. It is also used in raincoats and metal sheeting. Polyvinyl fluoride is a thermoplastic fluoropolymer with a repeating vinyl fluoride unit, and it is structurally very similar to polyvinyl chloride.

The ionization chamber is the simplest type of gaseous ionisation detector, and is widely used for the detection and measurement of many types of ionizing radiation, including X-rays, gamma rays, alpha particles and beta particles. Conventionally, the term "ionization chamber" refers exclusively to those detectors which collect all the charges created by direct ionization within the gas through the application of an electric field. It uses the discrete charges created by each interaction between the incident radiation and the gas to produce an output in the form of a small direct current. This means individual ionising events cannot be measured, so the energy of different types of radiation cannot be differentiated, but it gives a very good measurement of overall ionising effect.

<span class="mw-page-title-main">Solid-state nuclear track detector</span> Radiation detection method for analyzing nuclear particles

A solid-state nuclear track detector or SSNTD is a sample of a solid material exposed to nuclear radiation, etched in a corrosive chemical, and examined microscopically. When the nuclear particles pass through the material they leave trails of molecular damage, and these damaged regions are etched faster than the bulk material, generating holes called tracks.

<span class="mw-page-title-main">Neutron activation</span> Induction of radioactivity by neutron radiation

Neutron activation is the process in which neutron radiation induces radioactivity in materials, and occurs when atomic nuclei capture free neutrons, becoming heavier and entering excited states. The excited nucleus decays immediately by emitting gamma rays, or particles such as beta particles, alpha particles, fission products, and neutrons. Thus, the process of neutron capture, even after any intermediate decay, often results in the formation of an unstable activation product. Such radioactive nuclei can exhibit half-lives ranging from small fractions of a second to many years.

<span class="mw-page-title-main">Hot particle</span> Nuclear risk to human health

A hot particle is a microscopic piece of radioactive material that can become lodged in living tissue and deliver a concentrated dose of radiation to a small area. A generally accepted theory proposes that hot particles within the body are vastly more dangerous than external emitters delivering the same dose of radiation in a diffused manner. Other researchers claim that there is little or no difference in risk between internal and external emitters, maintaining that individuals will likely continue to accumulate radiation dose from internal sources even after being removed from the original hazard and properly decontaminated, regardless of the relative danger from an internally sourced radiation dose compared to an equivalent externally sourced radiation dose.

<span class="mw-page-title-main">Neutron detection</span>

Neutron detection is the effective detection of neutrons entering a well-positioned detector. There are two key aspects to effective neutron detection: hardware and software. Detection hardware refers to the kind of neutron detector used and to the electronics used in the detection setup. Further, the hardware setup also defines key experimental parameters, such as source-detector distance, solid angle and detector shielding. Detection software consists of analysis tools that perform tasks such as graphical analysis to measure the number and energies of neutrons striking the detector.

In health physics, whole-body counting refers to the measurement of radioactivity within the human body. The technique is primarily applicable to radioactive material that emits gamma rays. Alpha particle decays can also be detected indirectly by their coincident gamma radiation. In certain circumstances, beta emitters can be measured, but with degraded sensitivity. The instrument used is normally referred to as a whole body counter.

<span class="mw-page-title-main">Radiation monitoring</span> Measurement of radiation doses or contamination

Radiation monitoring involves the measurement of radiation dose or radionuclide contamination for reasons related to the assessment or control of exposure to radiation or radioactive substances, and the interpretation of the results.

<span class="mw-page-title-main">Alpha particle</span> Ionizing radiation particle of two protons and two neutrons

Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produced in other ways. Alpha particles are named after the first letter in the Greek alphabet, α. The symbol for the alpha particle is α or α2+. Because they are identical to helium nuclei, they are also sometimes written as He2+
or 4
2
He2+
indicating a helium ion with a +2 charge. Once the ion gains electrons from its environment, the alpha particle becomes a normal helium atom 4
2
He
.

Radioanalytical chemistry focuses on the analysis of sample for their radionuclide content. Various methods are employed to purify and identify the radioelement of interest through chemical methods and sample measurement techniques.

<span class="mw-page-title-main">Radionuclide identification device</span>

A radionuclide identification device is a small, lightweight, portable gamma-ray spectrometer used for the detection and identification of radioactive substances. As RIIDs are portable, they are suitable for medical and industrial applications, fieldwork, geological surveys, first-line responders in Homeland Security, and Environmental Monitoring and Radiological Mapping along with other industries that necessitate the identification of radioactive substances..

Columbia-Southern Chemical Corporation was a subsidiary of Pittsburgh Plate Glass Company. It produced heavy industrial chemicals for industry and agriculture, including: anhydrous ammonia, caustic soda, chlorine, titanium tetrachloride, and soda ash.

<span class="mw-page-title-main">Diallyl carbonate</span> Acrylating agent

Diallyl carbonate (DAC) is a colorless liquid with a pungent odor. Its structure contains allyl groups and a functional carbonate group. The presence of double bonds in the allyl groups makes it reactive in various chemical processes. This compound plays a key role in the production of polymers, including polycarbonates and polyurethanes. Diallyl carbonate is soluble in ethanol, methanol, toluene, and chloroform. Diallyl carbonate reacts with amines, alcohols, and thiols.

References

  1. "Optical Products". Corporateportal.ppg.com. Archived from the original on 2009-06-13. Retrieved 2012-09-15.
  2. "Optical Products". Corporateportal.ppg.com. Archived from the original on 2006-04-19. Retrieved 2012-09-15.
  3. "A Field study" (PDF). Dtic.mil. Archived (PDF) from the original on October 2, 2012. Retrieved 2012-09-16.
  4. "OptiCampus.com - Spectral Transmittance Charts". opticampus.opti.vision. Retrieved 2019-03-09.
  5. A quantitative method for determining the biodistribution of alpha radionuclides using whole-body cryosectioning and alpha-track autoradiography Archived 2013-10-14 at the Wayback Machine Cebrián, D., Morcillo, M.A.; Radiation Dosimetry, CIEMAT Avd. Complutense 22; 28040-Madrid Spain.
  6. Busby Busby Chris and Williams Dai, Further Evidence of Enriched Uranium in guided weapons employed by the Israeli Military in Lebanon in July 2006: Ambulance Air Filter Analysis Archived 2012-12-24 at the Wayback Machine Green Audit Research Note 7/2006 Nov 3rd 2006.