Chlorocalcite

Last updated
Chlorocalcite
General
Category Halide mineral
Formula
(repeating unit)
KCaCl3
IMA symbol Ccal [1]
Strunz classification 3.AA.40
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Pnma (from synthetic crystals)
Unit cell a = 7.35 Å, b = 10.44 Å,
c = 7.25 Å; Z = 4
Identification
Formula mass 185.54 g/mol
ColorWhite, tinged violet
Crystal habit Prismatic or tabular cube-like crystals, pseudo cubic
Cleavage Perfect on {001}, good on {010} and {100}
Mohs scale hardness2.5-3
Diaphaneity Transparent to semi-transparent
Density 2.16 calculated
Optical propertiesBiaxial (–)
Refractive index ~1.52
Birefringence weak
Solubility In water
Other characteristicsDeliquescent
References [2] [3] [4] [5]

Chlorocalcite is a rare potassium calcium chloride evaporite mineral with formula: KCaCl3. It is found in active volcanic fumaroles.

It was first described in 1872 for an occurrence on Mount Vesuvius and given the name for its calcium content previous to discovering that it also contained potassium. [3] [4] It has also been reported from the Desdemona Mine, Peine, Lower Saxony, Germany. [3]

Related Research Articles

<span class="mw-page-title-main">Feldspar</span> Group of rock-forming minerals

Feldspar is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight.

<span class="mw-page-title-main">Plagioclase</span> Type of feldspar

Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi3O8 to CaAl2Si2O8), where sodium and calcium atoms can substitute for each other in the mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or "record-groove" effect.

<span class="mw-page-title-main">Carnotite</span> Radioactive mineral

Carnotite is a potassium uranium vanadate radioactive mineral with chemical formula K2(UO2)2(VO4)2·3H2O. The water content can vary and small amounts of calcium, barium, magnesium, iron, and sodium are often present.

<span class="mw-page-title-main">Nepheline</span> Silica-undersaturated aluminosilicate mineral

Nepheline, also called nephelite (from Ancient Greek νεφέλη (nephélē) 'cloud'), is a rock-forming mineral in the feldspathoid group – a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.

<span class="mw-page-title-main">Niter</span> Mineral form of potassium nitrate

Niter or nitre is the mineral form of potassium nitrate, KNO3. It is a soft, white, highly soluble mineral found primarily in arid climates or cave deposits.

<span class="mw-page-title-main">Anhydrite</span> Mineral, anhydrous calcium sulfate

Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium (baryte) and strontium (celestine) sulfates, as might be expected from the chemical formulas. Distinctly developed crystals are somewhat rare, the mineral usually presenting the form of cleavage masses. The Mohs hardness is 3.5, and the specific gravity is 2.9. The color is white, sometimes greyish, bluish, or purple. On the best developed of the three cleavages, the lustre is pearly; on other surfaces it is glassy. When exposed to water, anhydrite readily transforms to the more commonly occurring gypsum, (CaSO4·2H2O) by the absorption of water. This transformation is reversible, with gypsum or calcium sulfate hemihydrate forming anhydrite by heating to around 200 °C (400 °F) under normal atmospheric conditions. Anhydrite is commonly associated with calcite, halite, and sulfides such as galena, chalcopyrite, molybdenite, and pyrite in vein deposits.

<span class="mw-page-title-main">Chlorite group</span> Type of mineral

The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.

<span class="mw-page-title-main">Cummingtonite</span> Silicate mineral

Cummingtonite is a metamorphic amphibole with the chemical composition (Mg,Fe2+
)
2
(Mg,Fe2+
)
5
Si
8
O
22
(OH)
2
, magnesium iron silicate hydroxide.

<span class="mw-page-title-main">Heulandite</span>

Heulandite is the name of a series of tecto-silicate minerals of the zeolite group. Prior to 1997, heulandite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named:

<span class="mw-page-title-main">Sanidine</span>

Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system. Orthoclase is a monoclinic polymorph stable at lower temperatures. At yet lower temperatures, microcline, a triclinic polymorph of potassium feldspar, is stable.

<span class="mw-page-title-main">Laumontite</span>

Laumontite is a mineral, one of the zeolite group. Its molecular formula is Ca(AlSi2O6)2 · 4H2O, a hydrated calcium-aluminium silicate. Potassium or sodium may substitute for the calcium but only in very small amounts.

<span class="mw-page-title-main">Afghanite</span> Tectosilicate mineral

Afghanite, (Na,K)22Ca10[Si24Al24O96](SO4)6Cl6, is a hydrous sodium, calcium, potassium, sulfate, chloride, carbonate alumino-silicate mineral. Afghanite is a feldspathoid of the cancrinite group and typically occurs with sodalite group minerals. It forms blue to colorless, typically massive crystals in the trigonal crystal system. The lowering of the symmetry from typical (for cancrinite group) hexagonal one is due to ordering of Si and Al. It has a Mohs hardness of 5.5 to 6 and a specific gravity of 2.55 to 2.65. It has refractive index values of nω=1.523 and nε=1.529. It has one direction of perfect cleavage and exhibits conchoidal fracture. It fluoresces a bright orange.

<span class="mw-page-title-main">Celadonite</span>

Celadonite is a mica group mineral, a phyllosilicate of potassium, iron in both oxidation states, aluminium and hydroxide with formula K(Mg,Fe2+
)(Fe3+
,Al)[Si
4
O
10
](OH)
2
.

<span class="mw-page-title-main">Polyhalite</span> Sedimentary mineral

Polyhalite is an evaporite mineral, a hydrated sulfate of potassium, calcium and magnesium with formula: K2Ca2Mg(SO4)4·2H2O. Polyhalite crystallizes in the triclinic system, although crystals are very rare. The normal habit is massive to fibrous. It is typically colorless, white to gray, although it may be brick red due to iron oxide inclusions. It has a Mohs hardness of 3.5 and a specific gravity of 2.8. It is used as a fertilizer.

<span class="mw-page-title-main">Tinaksite</span>

Tinaksite (chemical formula K2Na(Ca,Mn2+)2TiO[Si7O18(OH)]) is a mineral found in northern Russia. Tinaksite can be grayish-white, yellowish, orange, or brown, and it is often found in charoite. Its name is derived from its composition: titanium (Ti), sodium (Na) potassium (K) and silicon (Si). The International Mineralogical Association first recognized tinaksite as a mineral in 1965.

<span class="mw-page-title-main">Syngenite</span>

Syngenite is an uncommon potassium calcium sulfate mineral with formula K2Ca(SO4)2·H2O. It forms as prismatic monoclinic crystals and as encrustations.

Mogovidite is a very rare mineral of the eudialyte group, with formula Na9(Ca,Na)6Ca6(Fe3+,Fe2+)2Zr3[]Si(Si9O27)2(Si3O9)2(CO3)(OH,H2O)4. The formula given is based on the original one but extended to show the presence of cyclic silicate groups. It is similar to feklichevite, differing from it in the presence of essential vacancies and carbonate group. Another specific feature is the dominance of ferric iron - a feature shared with other eudialyte-group members, including feklichevite, fengchengite, golyshevite and ikranite. Similarly to golyshevite, it is calcium-dominant, however on three sites: M(1), N(3) and N(4). It has a molecular mass of 3,066.24 gm.

<span class="mw-page-title-main">Canasite</span> Silicate mineral

Canasite is a mineral whose name is derived from its chemical composition of calcium (Ca), sodium (Na), and silicon (Si). It was approved in 1959 by IMA.

<span class="mw-page-title-main">Ganophyllite</span> Silicate mineral

Ganophyllite is a phyllosilicate mineral. It was named by Axel Hamberg in 1890 from the Greek words for leaf (φύλλον) and luster (γανωμα); the latter one was chosen due to the lustrous cleavages. The mineral was approved by the IMA in 1959, and it is a grandfathered mineral, meaning its name is still believed to refer to an existing species until this day. Tamaite is the calcium analogue, while eggletonite is the natrium analogue of said mineral.

<span class="mw-page-title-main">Bannisterite</span> Silicate mineral

Bannisterite is a mineral named in honor of mineralogist and x-ray crystallographer Dr. Frederick Allen Bannister (1901-1970). It is a calcium-dominant member of the ganophyllite group, and was previously identified as ganophyllite in 1936, but otherwise it is structurally related to the stilpnomelane group. It was approved by the IMA in 1967.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Mineralienatlas
  3. 1 2 3 Chlorocalcite on Mindat.org
  4. 1 2 Chlorocalcite on Webmineral
  5. Handbook of Mineralogy