Coagulation (water treatment)

Last updated
Coagulation-flocculation process in a water treatment system The coagulation and filtration processes at a drinking water treatment plant. (14868618507).jpg
Coagulation-flocculation process in a water treatment system

In water treatment, coagulation and flocculation involve the addition of compounds that promote the clumping of fine floc into larger floc so that they can be more easily separated from the water. Coagulation is a chemical process that involves neutralization of charge whereas flocculation is a physical process and does not involve neutralization of charge. The coagulation-flocculation process can be used as a preliminary or intermediary step between other water or wastewater treatment processes like filtration and sedimentation. Iron and aluminium salts are the most widely used coagulants but salts of other metals such as titanium and zirconium have been found to be highly effective as well. [1] [2]

Contents

Factors

Coagulation is affected by the type of coagulant used, its dose and mass; pH and initial turbidity of the water that is being treated; and properties of the pollutants present. [1] [3] The effectiveness of the coagulation process is also affected by pretreatments like oxidation. [1] [4]

Mechanism

In a colloidal suspension, particles will settle very slowly or not at all because the colloidal particles carry surface electrical charges that mutually repel each other. This surface charge is most commonly evaluated in terms of zeta potential, the electrical potential at the slipping plane. To induce coagulation, a coagulant (typically a metallic salt) with the opposite charge is added to the water to overcome the repulsive charge and "destabilize" the suspension. For example, the colloidal particles are negatively charged and alum is added as a coagulant to create positively charged ions. Once the repulsive charges have been neutralized (since opposite charges attract), van der Waals force will cause the particles to cling together (agglomerate) and form micro floc.[ citation needed ]

Determining coagulant dose

Jar test

Jar test for coagulation Jar Test for Coagulation.jpg
Jar test for coagulation

The dose of the coagulant to be used can be determined via the jar test. [1] [5] The jar test involves exposing same volume samples of the water to be treated to different doses of the coagulant and then simultaneously mixing the samples at a constant rapid mixing time. [5] The microfloc formed after coagulation further undergoes flocculation and is allowed to settle. Then the turbidity of the samples is measured and the dose with the lowest turbidity can be said to be optimum.

Microscale dewatering tests

Despite its widespread use in the performance of so-called "dewatering experiments", the jar test is limited in its usefulness due to several disadvantages. For example, evaluating the performance of prospective coagulants or flocculants requires both significant volumes of water/wastewater samples (liters) and experimental time (hours). This limits the scope of the experiments which can be conducted, including the addition of replicates. [6] Furthermore, the analysis of jar test experiments produces results which are often only semi-quantitative. Coupled with the wide range of chemical coagulants and flocculants that exist, it has been remarked that determining the most appropriate dewatering agent as well as the optimal dose "is widely considered to be more of an ‘art’ rather than a ‘science’". [7] As such, dewatering performance tests such as the jar test lend themselves well to miniaturization. For example, the Microscale Flocculation Test developed by LaRue et al. reduces the scale of conventional jar tests down to the size of a standard multi-well microplate, which yields benefits stemming from the reduced sample volume and increased parallelization; this technique is also amenable to quantitative dewatering metrics, such as capillary suction time. [7]

Streaming current detector

An automated device for determining the coagulant dose is the Streaming Current Detector (SCD). The SCD measures the net surface charge of the particles and shows a streaming current value of 0 when the charges are neutralized (cationic coagulants neutralize the anionic colloids). At this value (0), the coagulant dose can be said to be optimum. [1]

Jar test: Mixing different doses of coagulant with samples of the water to be treated

Limitations

Coagulation itself results in the formation of floc but flocculation is required to help the floc further aggregate and settle. The coagulation-flocculation process itself removes only about 60%-70% of Natural Organic Matter (NOM) and thus, other processes like oxidation, filtration and sedimentation are necessary for complete raw water or wastewater treatment. [4] Coagulant aids (polymers that bridge the colloids together) are also often used to increase the efficiency of the process. [8]

See also

Related Research Articles

<span class="mw-page-title-main">Colloid</span> Mixture of an insoluble substance microscopically dispersed throughout another substance

A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend the definition to include substances like aerosols and gels. The term colloidal suspension refers unambiguously to the overall mixture. A colloid has a dispersed phase and a continuous phase. The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre.

<span class="mw-page-title-main">Water purification</span> Process of removing impurities from water

Water purification is the process of removing undesirable chemicals, biological contaminants, suspended solids, and gases from water. The goal is to produce water that is fit for specific purposes. Most water is purified and disinfected for human consumption, but water purification may also be carried out for a variety of other purposes, including medical, pharmacological, chemical, and industrial applications. The history of water purification includes a wide variety of methods. The methods used include physical processes such as filtration, sedimentation, and distillation; biological processes such as slow sand filters or biologically active carbon; chemical processes such as flocculation and chlorination; and the use of electromagnetic radiation such as ultraviolet light.

<span class="mw-page-title-main">Water treatment</span> Process that improves the quality of water

Water treatment is any process that improves the quality of water to make it appropriate for a specific end-use. The end use may be drinking, industrial water supply, irrigation, river flow maintenance, water recreation or many other uses, including being safely returned to the environment. Water treatment removes contaminants and undesirable components, or reduces their concentration so that the water becomes fit for its desired end-use. This treatment is crucial to human health and allows humans to benefit from both drinking and irrigation use.

<span class="mw-page-title-main">Turbidity</span> Cloudiness of a fluid

Turbidity is the cloudiness or haziness of a fluid caused by large numbers of individual particles that are generally invisible to the naked eye, similar to smoke in air. The measurement of turbidity is a key test of both water clarity and water quality.

<span class="mw-page-title-main">Flocculation</span> Process by which colloidal particles come out of suspension to precipitate as floc or flake

In colloidal chemistry, flocculation is a process by which colloidal particles come out of suspension to sediment in the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from precipitation in that, prior to flocculation, colloids are merely suspended, under the form of a stable dispersion and are not truly dissolved in solution.

<span class="mw-page-title-main">Sand filter</span> Water filtration device

Sand filters are used as a step in the water treatment process of water purification.

Electrocoagulation (EC) is a technique used for wastewater treatment, wash water treatment, industrially processed water, and medical treatment. Electrocoagulation has become a rapidly growing area of wastewater treatment due to its ability to remove contaminants that are generally more difficult to remove by filtration or chemical treatment systems, such as emulsified oil, total petroleum hydrocarbons, refractory organics, suspended solids, and heavy metals. There are many brands of electrocoagulation devices available and they can range in complexity from a simple anode and cathode to much more complex devices with control over electrode potentials, passivation, anode consumption, cell REDOX potentials as well as the introduction of ultrasonic sound, ultraviolet light and a range of gases and reactants to achieve so-called Advanced Oxidation Processes for refractory or recalcitrant organic substances.

Dissolved air flotation (DAF) is a water treatment process that clarifies wastewaters by the removal of suspended matter such as oil or solids. The removal is achieved by dissolving air in the water or wastewater under pressure and then releasing the air at atmospheric pressure in a flotation tank basin. The released air forms tiny bubbles which adhere to the suspended matter causing the suspended matter to float to the surface of the water where it may then be removed by a skimming device.

<span class="mw-page-title-main">Particle aggregation</span> Clumping of particles in suspension

Particle agglomeration refers to the formation of assemblages in a suspension and represents a mechanism leading to the functional destabilization of colloidal systems. During this process, particles dispersed in the liquid phase stick to each other, and spontaneously form irregular particle assemblages, flocs, or agglomerates. This phenomenon is also referred to as coagulation or flocculation and such a suspension is also called unstable. Particle agglomeration can be induced by adding salts or other chemicals referred to as coagulant or flocculant.

<span class="mw-page-title-main">Rapid sand filter</span>

The rapid sand filter or rapid gravity filter is a type of filter used in water purification and is commonly used in municipal drinking water facilities as part of a multiple-stage treatment system. These systems are complex and expensive to operate and maintain, and therefore less suitable for small communities and developing nations.

The physical process of sedimentation has applications in water treatment, whereby gravity acts to remove suspended solids from water. Solid particles entrained by the turbulence of moving water may be removed naturally by sedimentation in the still water of lakes and oceans. Settling basins are ponds constructed for the purpose of removing entrained solids by sedimentation. Clarifiers are tanks built with mechanical means for continuous removal of solids being deposited by sedimentation; however, clarification does not remove dissolved solids.

A lamella clarifier or inclined plate settler (IPS) is a type of clarifier designed to remove particulates from liquids.

<span class="mw-page-title-main">Clarifier</span> Settling tanks for continuous removal of solids being deposited by sedimentation

Clarifiers are settling tanks built with mechanical means for continuous removal of solids being deposited by sedimentation. A clarifier is generally used to remove solid particulates or suspended solids from liquid for clarification and/or thickening. Inside the clarifier, solid contaminants will settle down to the bottom of the tank where it is collected by a scraper mechanism. Concentrated impurities, discharged from the bottom of the tank, are known as sludge, while the particles that float to the surface of the liquid are called scum.

<span class="mw-page-title-main">PolyDADMAC</span> Chemical compound

Polydiallyldimethylammonium chloride, also commonly polyquaternium-6, is a homopolymer of diallyldimethylammonium chloride (DADMAC). The molecular weight of polyDADMAC is typically in the range of hundreds of thousands of grams per mole, and even up to a million for some products. PolyDADMAC is usually delivered as a liquid concentrate having a solids level in the range of 10 to 50%. It is a high charge density cationic polymer. The charge density makes it well suited for flocculation.

<span class="mw-page-title-main">Belt filter</span>

The belt filter is an industrial machine, used for solid/liquid separation processes, particularly the dewatering of sludges in the chemical industry, mining and water treatment. Belt filter presses are also used in the production of apple juice, cider and winemaking. The process of filtration is primarily obtained by passing a pair of filtering cloths and belts through a system of rollers. The system takes a sludge or slurry as a feed, and separates it into a filtrate and a solid cake.

Adsorption of polyelectrolytes on solid substrates is a surface phenomenon where long-chained polymer molecules with charged groups bind to a surface that is charged in the opposite polarity. On the molecular level, the polymers do not actually bond to the surface, but tend to "stick" to the surface via intermolecular forces and the charges created by the dissociation of various side groups of the polymer. Because the polymer molecules are so long, they have a large amount of surface area with which to contact the surface and thus do not desorb as small molecules are likely to do. This means that adsorbed layers of polyelectrolytes form a very durable coating. Due to this important characteristic of polyelectrolyte layers they are used extensively in industry as flocculants, for solubilization, as supersorbers, antistatic agents, as oil recovery aids, as gelling aids in nutrition, additives in concrete, or for blood compatibility enhancement to name a few.

Clarifying agents are used to remove suspended solids from liquids by inducing flocculation, causing the solids to form larger aggregates that can be easily removed after they either float to the surface or sink to the bottom of the containment vessel.

<span class="mw-page-title-main">SNF Floerger</span>

SNF is one of the largest manufacturers of polyacrylamides. These water-soluble polymers are used as flocculants and coagulants in solid/water separation to recycle water, rheology modifiers and friction reducers. These functionalities have many uses where water is used, in drinking water production, wastewater treatment, mining, paper, enhanced oil recovery, hydraulic fracturing, agriculture, textile and cosmetics.

A depletion force is an effective attractive force that arises between large colloidal particles that are suspended in a dilute solution of depletants, which are smaller solutes that are preferentially excluded from the vicinity of the large particles. One of the earliest reports of depletion forces that lead to particle coagulation is that of Bondy, who observed the separation or "creaming" of rubber latex upon addition of polymer depletant molecules to solution. More generally, depletants can include polymers, micelles, osmolytes, ink, mud, or paint dispersed in a continuous phase.

Chemical phosphorus removal is a wastewater treatment method, where phosphorus is removed using salts of aluminum, iron, or calcium. Phosphate forms precipitates with the metal ions and is removed together with the sludge in the separation unit.

References

  1. 1 2 3 4 5 Jiang, Jia-Qian (2015-05-01). "The role of coagulation in water treatment". Current Opinion in Chemical Engineering. 8: 36–44. doi:10.1016/j.coche.2015.01.008.
  2. Chekli, L.; Eripret, C.; Park, S. H.; Tabatabai, S. A. A.; Vronska, O.; Tamburic, B.; Kim, J. H.; Shon, H. K. (2017-03-24). "Coagulation performance and floc characteristics of polytitanium tetrachloride (PTC) compared with titanium tetrachloride (TiCl4) and ferric chloride (FeCl3) in algal turbid water". Separation and Purification Technology. 175: 99–106. doi:10.1016/j.seppur.2016.11.019. hdl: 10453/67246 .
  3. Ramavandi, Bahman (2014-08-01). "Treatment of water turbidity and bacteria by using a coagulant extracted from Plantago ovata". Water Resources and Industry. 6: 36–50. doi: 10.1016/j.wri.2014.07.001 .
  4. 1 2 Ayekoe, Chia Yvette Prisca; Robert, Didier; Lanciné, Droh Gone (2017-03-01). "Combination of coagulation-flocculation and heterogeneous photocatalysis for improving the removal of humic substances in real treated water from Agbô River (Ivory-Coast)". Catalysis Today. 281: 2–13. doi:10.1016/j.cattod.2016.09.024.
  5. 1 2 Aragonés-Beltrán, P.; Mendoza-Roca, J. A.; Bes-Piá, A.; García-Melón, M.; Parra-Ruiz, E. (2009-05-15). "Application of multicriteria decision analysis to jar-test results for chemicals selection in the physical–chemical treatment of textile wastewater". Journal of Hazardous Materials. 164 (1): 288–295. doi:10.1016/j.jhazmat.2008.08.046. PMID   18829168.
  6. Luring, M.; Pessoa Noyma, N.; de Magalhaes, L.; Miranda, M.; Mucci, M.; van Oosterhout, F.; Huszar, V.L.M.; Manzi Marinho, M. (June 2017). "Critical assessment of chitosan as coagulant to remove cyanobacteria". Harmful Algae. 66: 1–12. doi:10.1016/j.hal.2017.04.011. PMID   28602248.
  7. 1 2 LaRue, R.J.; Cobbledick, J.; Aubry, N.; Cranston, E.D.; Latulippe, D.R. (2016). "The microscale flocculation test (MFT)—A high-throughput technique for optimizing separation performance". Chemical Engineering Research & Design. 105: 85–93. doi:10.1016/j.cherd.2015.10.045. hdl: 11375/22240 .
  8. Oladoja, Nurudeen Abiola (2016-06-01). "Advances in the quest for substitute for synthetic organic polyelectrolytes as coagulant aid in water and wastewater treatment operations". Sustainable Chemistry and Pharmacy. 3: 47–58. doi:10.1016/j.scp.2016.04.001.