Dielectric elastomers

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Working principle of dielectric elastomer actuators. An elastomeric film is coated on both sides with electrodes. The electrodes are connected to a circuit. By applying a voltage
U
{\displaystyle U}
the electrostatic pressure
p
e
l
{\displaystyle p_{el}}
acts. Due to the mechanical compression the elastomer film contracts in the thickness direction and expands in the film plane directions. The elastomer film moves back to its original position when it is short-circuited. Dielectric elastomers.gif
Working principle of dielectric elastomer actuators. An elastomeric film is coated on both sides with electrodes. The electrodes are connected to a circuit. By applying a voltage the electrostatic pressure acts. Due to the mechanical compression the elastomer film contracts in the thickness direction and expands in the film plane directions. The elastomer film moves back to its original position when it is short-circuited.

Dielectric elastomers (DEs) are smart material systems that produce large strains and are promising for Soft robotics, Artificial muscle, etc. They belong to the group of electroactive polymers (EAP). DE actuators (DEA) transform electric energy into mechanical work and vice versa. Thus, they can be used as both actuators, sensors, and energy-harvesting devices. They have high elastic energy density and fast response due to being lightweight, highly stretchable, and operating under the electrostatic principle. They have been investigated since the late 1990s. Many prototype applications exist. Every year, conferences are held in the US [1] and Europe. [2]

Contents

Working principles

A DEA is a compliant capacitor (see image), where a passive elastomer film is sandwiched between two compliant electrodes. When a voltage is applied, the electrostatic pressure arising from the Coulomb forces acts between the electrodes. The electrodes squeeze the elastomer film. The equivalent electromechanical pressure is twice the electrostatic pressure and is given by:

where is the vacuum permittivity, is the dielectric constant of the polymer and is the thickness of the elastomer film in the current state (during deformation). Usually, strains of DEA are in the order of 10–35%, maximum values reach 300% (the acrylic elastomer VHB 4910, commercially available from 3M, which also supports a high elastic energy density and a high electrical breakdown strength.)

Ionic

Replacing the electrodes with soft hydrogels allows ionic transport to replace electron transport. Aqueous ionic hydrogels can deliver potentials of multiple kilovolts, despite the onset of electrolysis at below 1.5 V. [3] [4]

The difference between the capacitance of the double layer and the dielectric leads to a potential across the dielectric that can be millions of times greater than that across the double layer. Potentials in the kilovolt range can be realized without electrochemically degrading the hydrogel. [3] [4]

Deformations are well controlled, reversible, and capable of high-frequency operation. The resulting devices can be perfectly transparent. High-frequency actuation is possible. Switching speeds are limited only by mechanical inertia. The hydrogel's stiffness can be thousands of times smaller than the dielectric's, allowing actuation without mechanical constraint across a range of nearly 100% at millisecond speeds. They can be biocompatible. [3] [4]

Remaining issues include drying of the hydrogels, ionic build-up, hysteresis, and electrical shorting. [3] [4]

Early experiments in semiconductor device research relied on ionic conductors to investigate field modulation of contact potentials in silicon and to enable the first solid-state amplifiers. Work since 2000 has established the utility of electrolyte gate electrodes. Ionic gels can also serve as elements of high-performance, stretchable graphene transistors. [4]

Materials

Films of carbon powder or grease loaded with carbon black were early choices as electrodes for the DEAs. Such materials have poor reliability and are not available with established manufacturing techniques. Improved characteristics can be achieved with liquid metal, sheets of graphene, coatings of carbon nanotubes, surface-implanted layers of metallic nanoclusters and corrugated or patterned metal films. [4] [5]

These options offer limited mechanical properties, sheet resistances, switching times and easy integration. Silicones and acrylic elastomers are other alternatives.

The requirements for an elastomer material are:

Mechanically prestretching the elastomer film offers the possibility of enhancing the electrical breakdown strength. Further reasons for prestretching include:

The elastomers show a visco-hyperelastic behavior. Models that describe large strains and viscoelasticity are required for the calculation of such actuators.

Materials used in research include graphite powder, silicone oil / graphite mixtures, gold electrodes. The electrode should be conductive and compliant. Compliance is important so that the elastomer is not constrained mechanically when elongated. [4]

Films of polyacrylamide hydrogels formed with salt water can be laminated onto the dielectric surfaces, replacing electrodes. [4]

DEs based on silicone (PDMS) and natural rubber are promising research fields. [6] Properties such as fast response times and efficiency are superior using natural rubber based DEs compared to VHB (acrylic elastomer) based DEs for strains under 15%. [7]

Instabilities in Dielectric elastomers

Dielectric elastomer actuators are to be designed so as to avoid the phenomenon of dielectric breakdown in their whole course of motion. In addition to the dielectric breakdown, DEAs are susceptible to another failure mode, referred to as the electromechanical instability, which arises due to nonlinear interaction between the electrostatic and the mechanical restoring forces. In several cases, the electromechanical instability precedes the dielectric breakdown. The instability parameters (critical voltage and the corresponding maximum stretch) are dependent on several factors, such as the level of prestretch, temperature, and the deformation dependent permittivity. Additionally, they also depend on the voltage waveform used to drive the actuator. [8]

Configurations

Configurations include:

Applications

Dielectric elastomers offer multiple potential applications with the potential to replace many electromagnetic actuators, pneumatics and piezo actuators. A list of potential applications include:

Related Research Articles

<span class="mw-page-title-main">Dielectric</span> Electrically insulating substance able to be polarised by an applied electric field

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<span class="mw-page-title-main">Capacitance</span> Ability of a body to store an electrical charge

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<span class="mw-page-title-main">Hydrogel</span> Soft water-rich polymer gel

A hydrogel is a biphasic material, a mixture of porous, permeable solids and at least 10% by weight or volume of interstitial fluid composed completely or mainly by water. In hydrogels the porous permeable solid is a water insoluble three dimensional network of natural or synthetic polymers and a fluid, having absorbed a large amount of water or biological fluids. These properties underpin several applications, especially in the biomedical area. Many hydrogels are synthetic, but some are derived from nature. The term 'hydrogel' was coined in 1894.

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<span class="mw-page-title-main">Electrorheological fluid</span>

Electrorheological (ER) fluids are suspensions of extremely fine non-conducting but electrically active particles in an electrically insulating fluid. The apparent viscosity of these fluids changes reversibly by an order of up to 100,000 in response to an electric field. For example, a typical ER fluid can go from the consistency of a liquid to that of a gel, and back, with response times on the order of milliseconds. The effect is sometimes called the Winslow effect after its discoverer, the American inventor Willis Winslow, who obtained a US patent on the effect in 1947 and wrote an article published in 1949.

<span class="mw-page-title-main">Electroactive polymer</span>

An electroactive polymer (EAP) is a polymer that exhibits a change in size or shape when stimulated by an electric field. The most common applications of this type of material are in actuators and sensors. A typical characteristic property of an EAP is that they will undergo a large amount of deformation while sustaining large forces.

<span class="mw-page-title-main">Comb drive</span>

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<span class="mw-page-title-main">Capacitor types</span> Manufacturing styles of an electronic device

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<span class="mw-page-title-main">Capacitor</span> Passive two-terminal electronic component that stores electrical energy in an electric field

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<span class="mw-page-title-main">Ionic polymer–metal composites</span>

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<span class="mw-page-title-main">Ferroelectric polymer</span> Group of crystalline polar polymers that are also ferroelectric

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Mohsen (MO) Shahinpoor is an Iranian American engineer, scientist, and academician. He is a professor and Director at the University of Maine College of Engineering, Department of Mechanical Engineering. He is also a professor in the Graduate School of Biomedical Science and Engineering at the University of Maine.

References

  1. "Conference Detail for Electroactive Polymer Actuators and Devices (EAPAD) XV". Spie.org. 14 March 2013. Retrieved 1 December 2013.(registration required)
  2. European conference
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Further reading