Heather C. Allen

Last updated

Heather C. Allen
Born1960
Alma mater University of California, Irvine
Awards Alexander von Humboldt Research Award
Scientific career
Fields Interfacial phenomena
Institutions Ohio State University
Website Allen Group

Heather Cecile Allen (born 1960) [1] is a research chemist, who leads the Allen Group at Ohio State University. Allen's research focuses on interfacial phenomena, particularly those involving water and air. Her work has broad application ranging from medicine to climate change. She also develops nonlinear optical spectroscopy and microscopy instruments for the examination of interfacial surfaces. [2]

Contents

Allen has published more than 140 journal papers, and is reported to have an H-index of 51 as of May 2023. [2] She has received a number of awards including the 2022 American Chemical Society Irving Langmuir Award in Chemical Physics, and in 2014 the Alexander von Humboldt Research Award. [3] Allen's work on the structure of water was mentioned in Science magazine's list of the top ten breakthroughs of 2004. [4] [5] [6] [7]

Education

Heather Allen enrolled at Saddleback College, a community college, as an adult student at age 28. Interested in environmental science, she won a Science Scholarship Foundation Fellowship, enabling her to transfer to the University of California, Irvine to earn a chemistry or chemical engineering degree. [8] She received her B.S. degree in chemistry from the University of California, Irvine in 1993, working as a research assistant with Frank Sherwood Rowland and Donald R. Blake. She received her Ph.D. in physical chemistry in 1997, working with John C. Hemminger and Barbara J. Finlayson-Pitts. The topic of her Ph.D. thesis was Fundamental surface processes in heterogeneous atmospheric chemistry: Applications to sea-salt (NaCl) and oxide particulate chemistry. [9] She received several awards and postdoctoral fellowships, and did postdoctoral work with Geraldine L. Richmond at the University of Oregon. [10]

Career

Heather Allen joined Ohio State University in 2000, as an assistant professor of environmental chemistry. [8] She went on to become a full professor in the department of chemistry and biochemistry and in the department of pathology. She leads the Allen Group at Ohio State University. [11] [12]

Interfacial phenomena

Her research focuses on fundamental interfacial phenomena, the molecular organization and orientation at interfaces between gases and liquids, gases and solids, and liquids and solids. [11] She is particularly interested in understanding the activities of ions and molecules in aqueous surface structures. Understanding molecular organization is essential to understanding the ways in which surfaces will react. [13] Her studies of chemical reaction mechanisms have examined water, lipids, and fatty acids, among others. [11] [14]

Her work has relevance to a wide variety of fields, from medicine to climate change. Medically, aqueous surface structures are particularly relevant in the understanding of cell membranes and skin surfaces, which function as gateways to the cell and the body. As a Beckman Young Investigator, Allen studied the biophysics of the lung as a barrier mediating oxygen and carbon dioxide transport, and the importance of pulmonary surfactants. [15] Air, lipids, and water are all involved at the surface of the lung. Molecules of the alveolar lining were found to be important in the efficiency with which the lung could function. [16]

Allen has also examined the development of biomembranes with particular application to the detection of cancer margins. [15] Her team is working on the development of infrared biomarkers and molecular level diagnostics for the use of cancer surgeons. [17]

Allen's studies of interfacial phenomena are also relevant to geophysics, geochemistry and climate. Her work includes studies of how ions and minerals interact at surfaces where they are involved in corrosion and the interactions of pollutants with soil. [8]

The effect of particles at surfaces is important in understanding the behavior of air and water at ocean surfaces, and the health of oceans. Recent research indicates that accumulated ions are present in the ocean's surface layers. Using highly accurate laser beams, researchers were able to see the structures formed by halogen ions, or halides, and surrounding molecules of water in the interfacial area. Halides such as iodide and bromide were found close to the surface, [5] a result which challenged "conventional wisdom" on the subject. [6] Chloride ions were found lower down. [5] [6] Iodide and bromide are unstable and tend to combine with other chemicals to form ozone. [5] This means that fog and ocean spray are more chemically reactive than was previously believed by scientists. Allen's results may cause atmospheric chemists to revise their models of ozone activity and climate change. [5] [6]

The behavior of atmospheric aerosols, particulate matter suspended in the atmosphere, is also related to climate change. [18] Heather Allen is part of a national multidisciplinary group of researchers involved in the Center for Aerosol Impacts on Climate and the Environment (CAICE) who study the effects of atmospheric aerosols. [19] Allen studies the surfaces of cloud systems and their electric fields, to better understand thunderstorms, lightning strikes and the effects of microdroplets on clouds and fogs. With Lisa Van Loon, she has examined the behavior of sulfuric acid and methanol, found as aerosols in the upper atmosphere. Together they can form methyl sulfate, a compound that attracts water droplets and supports cloud formation. While sulfuric acid can reflect light and heat, clouds tend to trap light and heat in the atmosphere. The interplay between sulfuric acid and atmospheric temperature change is therefore more complex than originally thought. [20]

“Aerosols are a major driver of climate change and have major impacts... their effect depends on their composition, size, surface properties, where they’re located in the environment—especially their inherent ability to scatter light, and clouds—all are variables.” Heather C. Allen [19]

Instrumentation

Heather Allen and the Allen Group are involved in the design of nonlinear optical spectroscopy and microscopy instruments for scientific research. These include vibrational sum frequency generation (VSFG) spectroscopy, [21] [22] and broad-bandwidth sum frequency generation (BBSFG) spectroscopy, used for investigating gas-liquid and solid interfaces. [23] [24] Laser technology uses ultra-fast femtosecond and picosecond laser pulses to examine molecular-level interfaces and observe the orientation and structure of the chemical species within the surface regime, the surface signature. [25] Other techniques used and studied include polarized Raman and infrared spectroscopy techniques, Brewster angle microscopy, and differential optical absorption spectroscopy. [26] [27] [28]

Awards

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References

  1. ↑ Directory of Graduate Research. American Chemical Society. 2001. p. 683. ISBN   9780841238176 . Retrieved December 16, 2015.
  2. 1 2 "Heather Cecile Allen" (PDF). Ohio State University. December 24, 2014.
  3. 1 2 "Professor Heather Allen Awarded Humboldt Research Prize". Ohio State University. December 4, 2014. Archived from the original on January 29, 2016.
  4. ↑ "Breakthrough of the Year: The Runners-Up". Science. 306 (5704): 2013–2017. December 17, 2004. doi:10.1126/science.306.5704.2013. PMID   15604368. S2CID   35832438.
  5. 1 2 3 4 5 Wagner, Holly (March 1, 2004). "Ocean's surface could have big impact on air quality, study says". Ohio State Research. Archived from the original on December 16, 2016. Retrieved December 18, 2015.
  6. 1 2 3 4 "Making a Splash >> Ions and interactions". National Science Foundation. Archived from the original on January 27, 2016. Retrieved December 17, 2015.
  7. ↑ Liu, Dingfang; Ma, Gang; Levering, Lori M.; Allen, Heather C. (February 19, 2004). "Vibrational spectroscopy of aqueous sodium halide solutions and air-liquid interfaces: Observation of increased interfacial depth" (PDF). The Journal of Physical Chemistry B. 108 (7): 2252–2260. doi:10.1021/jp036169r.
  8. 1 2 3 Wilkinson, Sophie L. (June 19, 2000). "Starting from scratch: new professors share their experiences". Chemical & Engineering News. 78 (25): 41–47. doi:10.1021/cen-v078n025.p041 . Retrieved December 16, 2015.
  9. ↑ American doctoral dissertations, 1996–1997. 1998. p. 153. OCLC   795384415.
  10. ↑ "Heather C. Allen". Chemistry Tree. Retrieved December 16, 2015.
  11. 1 2 3 "Heather Allen". The Ohio State University. Archived from the original on November 10, 2015. Retrieved December 16, 2015.
  12. ↑ "Allen Group". The Ohio State University. Archived from the original on August 17, 2011. Retrieved December 16, 2015.
  13. 1 2 "University Awards & Recognition". Ohio State University. Retrieved December 16, 2015.
  14. ↑ Ho, Mae-Wan (2012). Living rainbow H₂O. Singapore: World Scientific. pp. 161–166. ISBN   978-9814390897.
  15. 1 2 3 "Heather C. Allen – 2003". Novel Discoveries: Beckman Young Investigators, 1991–2009. Irvine, CA: Arnold and Mabel Beckman Foundation. 2011. p. 187.
  16. ↑ "Columbus Events Sept 18 – 25". Tania explores Columbus. September 24, 2013. Retrieved December 18, 2015.
  17. ↑ Chen, Zhaomin; Butke, Ryan; Miller, Barrie; Hitchcock, Charles L.; Allen, Heather C.; Povoski, Stephen P.; Martin, Edward W.; Coe, James V. (October 17, 2013). "Infrared Metrics for Fixation-Free Liver Tumor Detection". The Journal of Physical Chemistry B. 117 (41): 12442–12450. doi:10.1021/jp4073087. PMC   3875153 . PMID   24053455.
  18. ↑ Allen, Bob (July 31, 2015). "Atmospheric Aerosols: What Are They, and Why Are They So Important?". NASA.
  19. 1 2 "Ohio State Chemist's Work to Benefit From $20 Million NSF CAICE Grant". Ohio State University. September 16, 2013.
  20. ↑ Wagner, Holly (December 8, 2003). "Atmospheric compound is double-edged sword in climate change". Ohio State Research. Retrieved December 18, 2015.
  21. ↑ Jubb, Aaron M.; Hua, Wei; Allen, Heather C. (May 5, 2012). "Environmental Chemistry at Vapor/Water Interfaces: Insights from Vibrational Sum Frequency Generation Spectroscopy". Annual Review of Physical Chemistry. 63 (1): 107–130. Bibcode:2012ARPC...63..107J. doi:10.1146/annurev-physchem-032511-143811. PMID   22224702. S2CID   46142455.
  22. ↑ Ma, G; Allen, HC (2006). "New insights into lung surfactant monolayers using vibrational sum frequency generation spectroscopy". Photochemistry and Photobiology. 82 (6): 1517–29. doi:10.1562/2006-06-30-IR-958. PMID   16930094. S2CID   43903916.
  23. ↑ Hommel, EL; Ma, G; Allen, HC (November 2001). "Broadband vibrational sum frequency generation spectroscopy of a liquid surface". Analytical Sciences. 17 (11): 1325–9. doi:10.2116/analsci.17.1325. PMID   11759518. S2CID   22500496.
  24. ↑ Ma, Gang; Allen, Heather C. (June 2006). "DPPC Langmuir Monolayer at the Air−Water Interface: Probing the Tail and Head Groups by Vibrational Sum Frequency Generation Spectroscopy". Langmuir. 22 (12): 5341–5349. doi:10.1021/la0535227. PMID   16732662. S2CID   12630121.
  25. ↑ Hommel, EL; Allen, HC (January 2001). "Broadband sum frequency generation with two regenerative amplifiers: temporal overlap of femtosecond and picosecond light pulses". Analytical Sciences. 17 (1): 137–9. doi:10.2116/analsci.17.137. PMID   11993650. S2CID   41658795.
  26. ↑ Hommel, EL; Allen, HC (June 2003). "The air-liquid interface of benzene, toluene, m-xylene, and mesitylene: a sum frequency, Raman, and infrared spectroscopic study". The Analyst. 128 (6): 750–5. Bibcode:2003Ana...128..750H. doi:10.1039/b301032p. PMID   12866899. S2CID   9410214.
  27. ↑ Chen, Xiangke; Huang, Zishuai; Hua, Wei; Castada, Hardy; Allen, Heather C. (December 21, 2010). "Reorganization and Caging of DPPC, DPPE, DPPG, and DPPS Monolayers Caused by Dimethylsulfoxide Observed Using Brewster Angle Microscopy". Langmuir. 26 (24): 18902–18908. doi:10.1021/la102842a. PMID   21086993. S2CID   207720748.
  28. ↑ Beekman, Christopher Paul (2010). Differential Optical Absorption Spectroscopy of Trace Gas Species and Aerosols in the Upper Ohio River Valley (Ph.D. thesis). Ohio State University.
  29. ↑ "Award Abstract #0134131". National Sciences Foundation. Retrieved December 16, 2015.
  30. ↑ "Sloan Research Fellowships". Alfred P. Sloan Foundation. Retrieved December 16, 2015.
  31. ↑ "Camille Dreyfus Teacher-Scholar Awards Program" (PDF). Camille & Henry Dreyfus Foundation. Archived from the original (PDF) on July 5, 2016. Retrieved December 16, 2015.
  32. ↑ "2013 National Award Recipient Citations". ACS Chemistry for Life. Archived from the original on January 30, 2018. Retrieved December 16, 2015.
  33. ↑ "ACS 2013 National Award Winners". Chemical and Engineering News. 90 (34): 53–54. August 20, 2012. Retrieved December 16, 2015.
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