Hexachloropropene

Last updated
Hexachloropropene
Hexachloropropene.svg
Names
Preferred IUPAC name
1,1,2,3,3,3-Hexachloroprop-1-ene
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.015.965 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 217-560-9
PubChem CID
UNII
UN number 3382 3082
  • InChI=1S/C3Cl6/c4-1(2(5)6)3(7,8)9
    Key: VFDYKPARTDCDCU-UHFFFAOYSA-N
  • InChI=1/C3Cl6/c4-1(2(5)6)3(7,8)9
    Key: VFDYKPARTDCDCU-UHFFFAOYAH
  • C(=C(Cl)Cl)(C(Cl)(Cl)Cl)Cl
Properties
C3Cl6
Molar mass 248.75 g/mol
Appearancecolourless liquid [1]
Density 1.765 g/cm3 (at 25 °C)
Melting point −73 [1]  °C (−99 °F; 200 K)
Boiling point 209–210 [1]  °C (408–410 °F; 482–483 K)
0.25 g/L [1]
Solubility soluble in carbon tetrachloride, ethanol and diethyl ether [2]
Hazards
GHS labelling:
GHS-pictogram-skull.svg GHS-pictogram-exclam.svg
Danger
H315, H319, H330, H332, H335
P260, P261, P264, P271, P280, P284, P302+P352, P304+P312, P304+P340, P305+P351+P338, P310, P312, P320, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Hexachloropropene is a toxic compound of chlorine and carbon. Its linear formula is CCl3CCl=CCl2. [3]

Hexachloropropene can be produced by the elimination reaction of 1,1,1,2,2,3,3-heptachloropropane by potassium hydroxide in methanol solution. [4]

Hexachloropropene can be used to produce other compounds such as uranium tetrachloride, anhydrous niobium pentachloride and tungsten hexachloride. [5]

Related Research Articles

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<span class="mw-page-title-main">Acyl halide</span> Oxoacid compound with an –OH group replaced by a halogen

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<span class="mw-page-title-main">Hydrogen fluoride</span> Chemical compound

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Uranium hexachloride (UCl6) is an inorganic chemical compound of uranium in the +6 oxidation state. UCl6 is a metal halide composed of uranium and chlorine. It is a multi-luminescent dark green crystalline solid with a vapor pressure between 1-3 mmHg at 373.15 K. UCl6 is stable in a vacuum, dry air, nitrogen and helium at room temperature. It is soluble in carbon tetrachloride (CCl4). Compared to the other uranium halides, little is known about UCl6.

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Cobalt(III) chloride or cobaltic chloride is an unstable and elusive compound of cobalt and chlorine with formula CoCl
3
. In this compound, the cobalt atoms have a formal charge of +3.

Neodymium nitride or neodymium(III) nitride is a chemical compound of neodymium and nitrogen with the formula NdN in which neodymium exhibits the +3 oxidation state and nitrogen exhibits the -3 oxidation state. It is ferromagnetic, like gadolinium(III) nitride, terbium(III) nitride and dysprosium(III) nitride. Neodymium nitride is not usually stoichiometric, and it is very hard to create pure stoichiometric neodymium nitride.

References

  1. 1 2 3 4 Hexachlorpropen
  2. Gangolli, S.; Royal Society of Chemistry (1999). The dictionary of substances and their effects. Cambridge, UK. p. 607. ISBN   0-85404-803-0. OCLC   41660040.
  3. "Hexachloropropene96%". Sigma Aldrich. Retrieved Nov 27, 2013.
  4. Friedrich Boberg (1964-11-16). "Über 1.2-Dithia-cyclopentene, V. 4.5-Dichlor-1.2-dithia-cyclopentenon-(3)". Justus Liebigs Annalen der Chemie (in German). 679 (1): 109–118. doi:10.1002/jlac.19646790115 . Retrieved 2022-03-08.
  5. W. W. Porterfield and S. Y. Tyree, Jr. (1967), S. Young Tyree, Jr. (ed.), Anhydrous metal chlorides, McGraw-Hill Book Company, Inc., pp. 133–136