In chemistry, the law of multiple proportions states that in compounds which contain two particular chemical elements, the amount of Element A per measure of Element B will differ across these compounds by ratios of small whole numbers. For instance, the ratio of the hydrogen content in methane and ethane per measure of carbon is 4:3 (CH4 vs C2H6). This law is also known as Dalton's Law, named after John Dalton, the chemist who first expressed it. The discovery of this pattern led Dalton to develop the modern theory of atoms, as it suggested that the elements combine with each other in multiples of a basic quantity.
The law of multiple proportions often does not apply when comparing very large molecules. For example, if one tried to demonstrate it using the hydrocarbonsdecane (chemical formula C10H22) and undecane (C11H24), one would find that 100grams of carbon could react with 18.46grams of hydrogen to produce decane or with 18.31grams of hydrogen to produce undecane, for a ratio of hydrogen masses of 121:120, which is hardly a ratio of "small" whole numbers.
History
In 1804, Dalton explained his atomic theory to his friend and fellow chemist Thomas Thomson, who published an explanation of Dalton's theory in his book A System of Chemistry in 1807. According to Thomson, Dalton's idea first occurred to him when experimenting with "olefiant gas" (ethylene) and "carburetted hydrogen gas" (methane). Dalton found that "carburetted hydrogen gas" contains twice as much hydrogen per measure of carbon as "olefiant gas", and concluded that a molecule of "olefiant gas" is one carbon atom and one hydrogen atom, and a molecule of "carburetted hydrogen gas" is one carbon atom and two hydrogen atoms.[1] In reality, an ethylene molecule has two carbon atoms and four hydrogen atoms (C2H4), and a methane molecule has one carbon atom and four hydrogen atoms (CH4). In this particular case, Dalton was mistaken about the formulas of these compounds, and it wasn't his only mistake. But in other cases, he got their formulas right. The following examples come from Dalton's own books A New System of Chemical Philosophy (in two volumes, 1808 and 1817):
Example 1 — tin oxides: Dalton identified two types of tin oxide. One is a grey powder that Dalton referred to as "the protoxide of tin", which is 88.1% tin and 11.9% oxygen. The other is a white powder which Dalton referred to as "the deutoxide of tin", which is 78.7% tin and 21.3% oxygen. Adjusting these figures, in the grey powder there is about 13.5g of oxygen for every 100g of tin, and in the white powder there is about 27g of oxygen for every 100g of tin. 13.5 and 27 form a ratio of 1:2. These compounds are known today as tin(II) oxide (SnO) and tin(IV) oxide (SnO2). In Dalton's terminology, a "protoxide" is a molecule containing a single oxygen atom, and a "deutoxide" molecule has two.[2][3] Tin oxides are actually crystals, they don't exist in molecular form.
Example 2 — iron oxides: Dalton identified two oxides of iron. There is one type of iron oxide that is a black powder which Dalton referred to as "the protoxide of iron", which is 78.1% iron and 21.9% oxygen. The other iron oxide is a red powder, which Dalton referred to as "the intermediate or red oxide of iron" which is 70.4% iron and 29.6% oxygen. Adjusting these figures, in the black powder there is about 28g of oxygen for every 100g of iron, and in the red powder there is about 42g of oxygen for every 100g of iron. 28 and 42 form a ratio of 2:3. These compounds are iron(II) oxide (Fe2O2)[lower-alpha 1] and iron(III) oxide (Fe2O3).[4][5] Dalton described the "intermediate oxide" as being "2 atoms protoxide and 1 of oxygen", which adds up to two atoms of iron and three of oxygen. That averages to one and a half atoms of oxygen for every iron atom, putting it midway between a "protoxide" and a "deutoxide".[6] As with tin oxides, iron oxides are crystals.
Example 3 — nitrogen oxides: Dalton was aware of three oxides of nitrogen: "nitrous oxide", "nitrous gas", and "nitric acid".[7] These compounds are known today as nitrous oxide, nitric oxide, and nitrogen dioxide respectively. "Nitrous oxide" is 63.3% nitrogen and 36.7% oxygen, which means it has 80 g of oxygen for every 140 g of nitrogen. "Nitrous gas" is 44.05% nitrogen and 55.95% oxygen, which means there are 160 g of oxygen for every 140 g of nitrogen. "Nitric acid" is 29.5% nitrogen and 70.5% oxygen, which means it has 320 g of oxygen for every 140 g of nitrogen. 80g, 160g, and 320g form a ratio of 1:2:4. The formulas for these compounds are N2O, NO, and NO2.[8][9]
The earliest definition of Dalton's observation appears in an 1807 chemistry encyclopedia:
...where two bodies combine in different proportions, if the quantity of one of them be assumed as a fixed number, the proportions of the other body that unite to it are in the simplest possible ratio to each other, being produced by multiplying the lowest proportion by a simple integral number as 2, 3, 4, &c. [...] in all cases the simple elements of bodies are disposed to unite atom to atom singly; or if either is in excess, it exceeds by a ratio to be expressed by some simple multiple of the number of its atoms.[10]
The first known writer to refer to this principle as the "doctrine of multiple proportions" was Jöns Jacob Berzelius in 1813.[11]
Dalton's atomic theory garnered widespread interest but not universal acceptance shortly after he published it because the law of multiple proportions by itself was not complete proof of the existence of atoms. Over the course of the 19th century, other discoveries in the fields of chemistry and physics would give atomic theory more credence, such that by the end of the 19th century it had found universal acceptance.
Footnotes
↑ Iron(II) oxide's formula is written here as "Fe2O2" rather than the more conventional "FeO" because this better illustrates the explanation.
↑ Thomas Thomson (1831). A History of Chemistry, Volume 2. p. 291
Joseph Louis Proust (1800). "Recherches sur l'étain"[Research on tin]. Journal de Physique, de Chimie, et d'Histoire Naturelle (in French). 51: 173–184.
Atoms are the basic particles of the chemical elements. An atom consists of a nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished from each other by the number of protons that are in their atoms. For example, any atom that contains 11 protons is sodium, and any atom that contains 29 protons is copper. Atoms with the same number of protons but a different number of neutrons are called isotopes of the same element.
Atomic theory is the scientific theory that matter is composed of particles called atoms. The definition of the word "atom" has changed over the years in response to scientific discoveries. Initially, it referred to a hypothetical concept of there being some fundamental particle of matter, too small to be seen by the naked eye, that could not be divided. Then the definition was refined to being the basic particles of the chemical elements, when chemists observed that elements seemed to combine with each other in ratios of small whole numbers. Then physicists discovered that these particles had an internal structure of their own and therefore perhaps did not deserve to be called "atoms", but renaming atoms would have been impractical by that point.
In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and plus (+) and minus (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name since it does not contain any words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae.
Diatomic molecules are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen or oxygen, then it is said to be homonuclear. Otherwise, if a diatomic molecule consists of two different atoms, such as carbon monoxide or nitric oxide, the molecule is said to be heteronuclear. The bond in a homonuclear diatomic molecule is non-polar.
The Haber process, also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. The German chemists Fritz Haber and Carl Bosch developed it in the first decade of the 20th century. The process converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using an iron metal catalyst under high temperatures and pressures. This reaction is slightly exothermic (i.e. it releases energy), meaning that the reaction is favoured at lower temperatures and higher pressures. It decreases entropy, complicating the process. Hydrogen is produced via steam reforming, followed by an iterative closed cycle to react hydrogen with nitrogen to produce ammonia.
In chemistry, the law of definite proportions, sometimes called Proust's law or the law of constant composition, states that a given chemical compound always contains its component elements in fixed ratio and does not depend on its source and method of preparation. For example, oxygen makes up about 8/9 of the mass of any sample of pure water, while hydrogen makes up the remaining 1/9 of the mass: the mass of two elements in a compound are always in the same ratio. Along with the law of multiple proportions, the law of definite proportions forms the basis of stoichiometry.
A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
Nitrogen is a chemical element; it has symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seventh in total abundance in the Milky Way and the Solar System. At standard temperature and pressure, two atoms of the element bond to form N2, a colorless and odorless diatomic gas. N2 forms about 78% of Earth's atmosphere, making it the most abundant uncombined element in air. Because of the volatility of nitrogen compounds, nitrogen is relatively rare in the solid parts of the Earth.
An oxide is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of Al2O3 that protects the foil from further oxidation.
John Dalton was an English chemist, physicist and meteorologist. He introduced the atomic theory into chemistry. He also researched colour blindness; as a result, the umbrella term for red-green congenital colour blindness disorders is Daltonism in several languages.
A period 2 element is one of the chemical elements in the second row of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behavior of the elements as their atomic number increases; a new row is started when chemical behavior begins to repeat, creating columns of elements with similar properties.
Nitric oxide is a colorless gas with the formula NO. It is one of the principal oxides of nitrogen. Nitric oxide is a free radical: it has an unpaired electron, which is sometimes denoted by a dot in its chemical formula. Nitric oxide is also a heteronuclear diatomic molecule, a class of molecules whose study spawned early modern theories of chemical bonding.
In chemistry, the amount of substance (symbol n) in a given sample of matter is defined as a ratio (n = N/NA) between the number of elementary entities (N) and the Avogadro constant (NA). The entities are usually molecules, atoms, or ions of a specified kind. The particular substance sampled may be specified using a subscript, e.g., the amount of sodium chloride (NaCl) would be denoted as nNaCl. The unit of amount of substance in the International System of Units is the mole (symbol: mol), a base unit. Since 2019, the value of the Avogadro constant NA is defined to be exactly 6.02214076×1023 mol−1. Sometimes, the amount of substance is referred to as the chemical amount or, informally, as the "number of moles" in a given sample of matter.
The history of chemistry represents a time span from ancient history to the present. By 1000 BC, civilizations used technologies that would eventually form the basis of the various branches of chemistry. Examples include the discovery of fire, extracting metals from ores, making pottery and glazes, fermenting beer and wine, extracting chemicals from plants for medicine and perfume, rendering fat into soap, making glass, and making alloys like bronze.
In chemistry, the valence or valency of an atom is a measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Valence is generally understood to be the number of chemical bonds that each atom of a given chemical element typically forms. Double bonds are considered to be two bonds, triple bonds to be three, quadruple bonds to be four, quintuple bonds to be five and sextuple bonds to be six. In most compounds, the valence of hydrogen is 1, of oxygen is 2, of nitrogen is 3, and of carbon is 4. Valence is not to be confused with the related concepts of the coordination number, the oxidation state, or the number of valence electrons for a given atom.
In chemistry, isotopologues are molecules that differ only in their isotopic composition. They have the same chemical formula and bonding arrangement of atoms, but at least one atom has a different number of neutrons than the parent.
In the history of chemistry, the chemical revolution, also called the first chemical revolution, was the reformulation of chemistry during the seventeenth and eighteenth centuries, which culminated in the law of conservation of mass and the oxygen theory of combustion.
A chemical substance is a unique form of matter with constant chemical composition and characteristic properties. Chemical substances may take the form of a single element or chemical compounds. If two or more chemical substances can be combined without reacting, they may form a chemical mixture. If a mixture is separated to isolate one chemical substance to a desired degree, the resulting substance is said to be chemically pure.
Factitious airs was a term used for synthetic gases which emerged around 1670 when Robert Boyle coined the term upon isolating what is now understood to be hydrogen. Factitious means "artificial, not natural", so the term means "man-made gases".
Nickel compounds are chemical compounds containing the element nickel which is a member of the group 10 of the periodic table. Most compounds in the group have an oxidation state of +2. Nickel is classified as a transition metal with nickel(II) having much chemical behaviour in common with iron(II) and cobalt(II). Many salts of nickel(II) are isomorphous with salts of magnesium due to the ionic radii of the cations being almost the same. Nickel forms many coordination complexes. Nickel tetracarbonyl was the first pure metal carbonyl produced, and is unusual in its volatility. Metalloproteins containing nickel are found in biological systems.
This page is based on this Wikipedia article Text is available under the CC BY-SA 4.0 license; additional terms may apply. Images, videos and audio are available under their respective licenses.
