Polyphenylene sulfide

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Polyphenylene sulfide Polyphenylene sulfide.svg
Polyphenylene sulfide
Space-filling model of a short section of a polyphenylene sulfide chain from the crystal structure Polyphenylene-sulfide-from-xtal-3D-sf.png
Space-filling model of a short section of a polyphenylene sulfide chain from the crystal structure

Polyphenylene sulfide (PPS) is an organic polymer consisting of aromatic rings linked by sulfides. Synthetic fiber and textiles derived from this polymer resist chemical and thermal attack. PPS is used in filter fabric for coal boilers, papermaking felts, electrical insulation, film capacitors, specialty membranes, gaskets, and packings. PPS is the precursor to a conductive polymer of the semi-flexible rod polymer family. The PPS, which is otherwise insulating, can be converted to the semiconducting form by oxidation or use of dopants. [2]

Contents

Polyphenylene sulfide is an engineering plastic, commonly used today as a high-performance thermoplastic. [3] PPS can be molded, extruded, or machined to tight tolerances. In its pure solid form, it may be opaque white to light tan in color. Maximum service temperature is 218 °C (424 °F). PPS has not been found to dissolve in any solvent at temperatures below approximately 200 °C (392 °F).[ citation needed ]

An easy way to identify the compound is by the metallic sound it makes when struck.

Manufacturers and trade names

PPS is marketed by different brand names by different manufacturers. The major industry players are China Lumena New Materials, Solvay, Kureha, HDC Polyall, Celanese, DIC Corporation, Toray Industries, Zhejiang NHU Special Materials, SABIC, and Tosoh. [4] Other manufacturers include Chengdu Letian Plastics, Lion Idemitsu Composites, and Initz (a joint venture of SK Chemicals and Teijin). [5]

The following are examples of brand names by manufacturer and PPS type:

Characteristics

PPS is one of the most important high temperature thermoplastic polymers because it exhibits a number of desirable properties. These properties include resistance to heat, acids, alkalies, mildew, bleaches, aging, sunlight, and abrasion. It absorbs only small amounts of solvents and resists dyeing.

Production

The Federal Trade Commission definition for sulfur fiber is "A manufactured fiber in which the fiber-forming substance is a long chain synthetic polysulfide in which at least 85% of the sulfide (–S–) linkages are attached directly to two (2) aromatic rings." The generic name for this synthetic fiber is Sulfar. [6]

The PPS (polyphenylene sulfide) polymer is formed by reaction of sodium sulfide with 1,4-dichlorobenzene:

n ClC6H4Cl + n Na2S → [C6H4S]n + 2n NaCl
Hill and Edmonds, developers of PPS Inventors Dr. H. Wayne Hill Jr. & Mr. James T. Edmonds.jpg
Hill and Edmonds, developers of PPS

The process for commercially producing this material was initially developed by Dr. H. Wayne Hill Jr. and James T. Edmonds at Phillips Petroleum. [7] N-Methyl-2-pyrrolidone (NMP) is used as the reaction solvent because it is stable at the high temperatures required for the synthesis and it dissolves both the sulfiding agent and the oligomeric intermediates.

Linear, high-molecular-weight PPS that is capable of being extruded into film or melt spun into fiber was invented by Robert W. Campbell. [8]

The first U.S. commercial sulfur fiber was produced in 1983 by Phillips Fibers Corporation, a subsidiary of Phillips 66. [2]

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<span class="mw-page-title-main">Fiber</span> Natural or synthetic substance made of long, thin filaments

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<span class="mw-page-title-main">Thermoplastic</span> Plastic that softens with heat and hardens on cooling

A thermoplastic, or thermosoftening plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling.

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<span class="mw-page-title-main">Engineering plastic</span> Plastics often used for making mechanical parts

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Poly(<i>p</i>-phenylene oxide) Chemical compound

Poly(p-phenylene oxide) (PPO), poly(p-phenylene ether) (PPE), poly(oxy-2,6-dimethyl-1,4-phenylene), often referred to simply as polyphenylene oxide, is a high-temperature thermoplastic with the general formula (C8H8O)n. It is rarely used in its pure form due to difficulties in processing. It is mainly used as blend with polystyrene, high impact styrene-butadiene copolymer or polyamide. PPO is a registered trademark of SABIC Innovative Plastics B.V. under which various polyphenylene ether resins are sold.

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High-performance plastics are plastics that meet higher requirements than standard or engineering plastics. They are more expensive and used in smaller amounts.

<span class="mw-page-title-main">Lumena</span>

China Lumena New Materials is a Chinese mining and manufacturing company primarily engaged in the production of polyphenylene sulfide (PPS), an industrial plastic. According to a market research report in 2016, the company is among the largest producers of PPS.

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References

  1. Tabor, B. J.; Magré, E. P.; Boon, J. (1971). "The crystal structure of poly-p-phenylene sulphide". Eur. Polym. J. 7 (8): 1127–1128. Bibcode:1971EurPJ...7.1127T. doi:10.1016/0014-3057(71)90145-5.
  2. 1 2 David Parker, Jan Bussink, Hendrik T. van de Grampel, Gary W. Wheatley, Ernst-Ulrich Dorf, Edgar Ostlinning, Klaus Reinking, "Polymers, High-Temperature" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH: Weinheim. doi : 10.1002/14356007.a21_449
  3. "Chevron Phillips Technical Library". Archived from the original on 2009-07-04. Retrieved 2009-07-22.
  4. "Polyphenylene Sulfide (PPS) Market Analysis by Application (Automotive, Electronics & Electrical, Industrial, Coatings) and Segment Forecasts to 2022".{{cite web}}: Missing or empty |url= (help)
  5. "Global Polyphenylene Sulfide (PPS) Market 2012-2022 - Research and Markets". Research and Markets. April 19, 2016.
  6. "eCFR :: 16 CFR 303.7 -- Generic names and definitions for manufactured fibers". Archived from the original on 2023-06-24.
  7. H Wayne Hill Jr., James T. Edmonds, to the Phillips Petroleum Company Research Center (Bartlesville, Oklahoma, US). Patent 3,354,129, 1963. issued November 21, 1967
  8. Robert W. Campbell to the Phillips Petroleum Company Research Center (Bartlesville, Oklahoma, US). Patent 3,919,177, 1974 issued November 11, 1975