Portlandite

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Portlandite
Portlandite, Ettringite - Mineralogisches Museum Bonn.jpg
Portlandite and ettringite
General
Category Oxide mineral
Formula
(repeating unit)
Ca(OH)2
IMA symbol Por [1]
Strunz classification 4.FE.05
Dana classification06.02.01.04
Brucite group
Crystal system Trigonal
Crystal class Hexagonal scalenohedral (3m)
H-M symbol: (3 2/m)
Space group P3m1
Unit cell a = 3.589 Å, c = 4.911 Å; Z = 1
Identification
ColorColorless, white to greenish white
Crystal habit Hexagonal plates; commonly fibrous, powdery, massive.
Cleavage Perfect on {0001}
Tenacity Sectile with flexible cleavage plates
Mohs scale hardness2
Luster Pearly on cleavages
Diaphaneity Transparent
Specific gravity 2.23
Optical propertiesUniaxial (−)
Refractive index nω = 1.574 nε = 1.547
Birefringence δ = 0.027
Solubility Soluble in water producing an alkaline solution
Alters toAlters to CaCO3 on exposure to CO2 bearing waters
References [2] [3] [4] [5] [6]

Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2).

Occurrence

Portlandite occurs in a variety of environments. At the type location in Northern Ireland it occurs as an alteration of calc–silicate rocks by contact metamorphism of larnitespurrite. It occurs as fumarole deposits in the Vesuvius area. In Jebel Awq, Oman, it occurs as precipitates from an alkaline spring emanating from ultramafic bedrock. In the Chelyabinsk coal basin of Russia it is produced by combustion of coal seams and similarly by spontaneous combustion of bitumen in the Hatrurim Formation of the Negev desert in Israel and the Maqarin area, Jordan. [3] It also occurs in the manganese mining area of Kuruman, Cape Province, South Africa in the Kalahari Desert where it occurs as large crystals and masses. [4] [3]

It occurs in association with afwillite, calcite, larnite, spurrite, halite, brownmillerite, hydrocalumite, mayenite and ettringite. [3]

It was first described in 1933 for an occurrence at Scawt Hill, Larne, County Antrim, Northern Ireland. It was named portlandite because the chemical calcium hydroxide is a common hydrolysis product of Portland cement. [4] [3]

Related Research Articles

<span class="mw-page-title-main">Prehnite</span> Inosilicate of calcium and aluminium

Prehnite is an inosilicate of calcium and aluminium with the formula: Ca2Al(AlSi3O10)(OH)2 with limited Fe3+ substitutes for aluminium in the structure. Prehnite crystallizes in the orthorhombic crystal system, and most often forms as stalactitic, botryoidal, reniform or globular aggregates, with only just the crests of small crystals showing any faces, which are almost always curved or composite. Very rarely will it form distinct, well-individualized crystals showing a square-like cross-section, including those found at the Jeffrey Mine in Asbestos, Quebec, Canada. Prehnite is brittle with an uneven fracture and a vitreous to pearly luster. Its hardness is 6.5, its specific gravity is 2.80–2.95 and its color varies from light green to yellow, but also colorless, blue, pink or white. In April 2000, rare orange prehnite was discovered in the Kalahari Manganese Fields, South Africa. Prehnite is mostly translucent, and rarely transparent.

<span class="mw-page-title-main">Calcium hydroxide</span> Inorganic compound of formula Ca(OH)2

Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca(OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed with water. It has many names including hydrated lime, caustic lime, builders' lime, slaked lime, cal, and pickling lime. Calcium hydroxide is used in many applications, including food preparation, where it has been identified as E number E526. Limewater, also called milk of lime, is the common name for a saturated solution of calcium hydroxide.

<span class="mw-page-title-main">Manganite</span>

Manganite is a mineral composed of manganese oxide-hydroxide, MnO(OH), crystallizing in the monoclinic system (pseudo-orthorhombic). Crystals of manganite are prismatic and deeply striated parallel to their length; they are often grouped together in bundles. The color is dark steel-grey to iron-black, and the luster brilliant and submetallic. The streak is dark reddish brown. The hardness is 4, and the specific gravity is 4.3. There is a perfect cleavage parallel to the brachypinacoid, and less-perfect cleavage parallel to the prism faces. Twinned crystals are not infrequent.

<span class="mw-page-title-main">Atacamite</span> Halide evaporite mineral

Atacamite is a copper halide mineral: a copper(II) chloride hydroxide with formula Cu2Cl(OH)3. It was first described for deposits in the Atacama Desert of Chile in 1802 by Dmitri de Gallitzin. The Atacama Desert is also the namesake of the mineral.

<span class="mw-page-title-main">Powellite</span>

Powellite is a calcium molybdate mineral with formula CaMoO4. Powellite crystallizes with tetragonal – dipyramidal crystal structure as transparent adamantine blue, greenish-brown, yellow-to-grey typically anhedral forms. It exhibits distinct cleavage, and has a brittle-to-conchoidal fracture. It has a Mohs hardness of 3.5 to 4 and a specific gravity of 4.25. It forms a solid solution series with scheelite (calcium tungstate, CaWO4). It has refractive index values of nω=1.974 and nε=1.984.

<span class="mw-page-title-main">Afwillite</span> Nesosilicate alteration mineral also sometimes found in hydrated cement paste

Afwillite is a calcium hydroxide nesosilicate mineral with formula Ca3(SiO3OH)2·2H2O. It occurs as glassy, colorless to white prismatic monoclinic crystals. Its Mohs scale hardness is between 3 and 4. It occurs as an alteration mineral in contact metamorphism of limestone. It occurs in association with apophyllite, natrolite, thaumasite, merwinite, spurrite, gehlenite, ettringite, portlandite, hillebrandite, foshagite, brucite and calcite.

<span class="mw-page-title-main">Brownmillerite</span> Rare calcium aluminium oxide mineral

Brownmillerite is a rare oxide mineral with chemical formula Ca2(Al,Fe)2O5. It is named for Lorrin Thomas Brownmiller (1902–1990), chief chemist of the Alpha Portland Cement Company, Easton, Pennsylvania.

<span class="mw-page-title-main">Bentorite</span> Rare chromium-rich ettringite, or Cr-AFt

Bentorite is a mineral with the chemical formula Ca6(Cr,Al)2(SO4)3(OH)12·26H2O. It is colored violet to light violet. Its crystals are hexagonal to dihexagonal dipyramidal. It is transparent and has vitreous luster. It has perfect cleavage. It is not radioactive. Bentorite is rated 2 on the Mohs scale.

<span class="mw-page-title-main">Botryogen</span>

Botryogen is a hydrous magnesium sulfate mineral with formula: MgFe3+(SO4)2(OH)·7H2O. It is also known as quetenite.

<span class="mw-page-title-main">Ettringite</span> Hydrous calcium sulfo-aluminate

Ettringite is a hydrous calcium aluminium sulfate mineral with formula: Ca6Al2(SO4)3(OH)12·26H2O. It is a colorless to yellow mineral crystallizing in the trigonal system. The prismatic crystals are typically colorless, turning white on partial dehydration. It is part of the ettringite-group which includes other sulfates such as thaumasite and bentorite.

Belite is an industrial mineral important in Portland cement manufacture. Its main constituent is dicalcium silicate, Ca2SiO4, sometimes formulated as 2 CaO · SiO2 (C2S in cement chemist notation).

<span class="mw-page-title-main">Thaumasite</span> Complex calcium silicate hydrate mineral

Thaumasite is a calcium silicate mineral, containing Si atoms in unusual octahedral configuration, with chemical formula Ca3Si(OH)6(CO3)(SO4)·12H2O, also sometimes more simply written as CaSiO3·CaCO3·CaSO4·15H2O.

<span class="mw-page-title-main">Spurrite</span> Nesosilicate mineral

Spurrite is a white, yellow or light blue mineral with monoclinic crystals. Its chemical formula is Ca5(SiO4)2CO3.

<span class="mw-page-title-main">Meyerhofferite</span>

Meyerhofferite is a hydrated borate mineral of calcium, with the chemical formula Ca2B6O6(OH)10·2H2O, CaB3O3(OH)5·H2O or Ca2(H3B3O7)2·4H2O. It occurs principally as an alteration product of inyoite, another borate mineral.

<span class="mw-page-title-main">Chlormayenite</span> Mayenite supergroup, mayenite mineral

Chlormayenite (after Mayen, Germany), Ca12Al14O32[☐4Cl2], is a rare calcium aluminium oxide mineral of cubic symmetry.

<span class="mw-page-title-main">Tinaksite</span>

Tinaksite (chemical formula K2Na(Ca,Mn2+)2TiO[Si7O18(OH)]) is a mineral found in northern Russia. Tinaksite can be grayish-white, yellowish, orange, or brown, and it is often found in charoite. Its name is derived from its composition: titanium (Ti), sodium (Na) potassium (K) and silicon (Si). The International Mineralogical Association first recognized tinaksite as a mineral in 1965.

<span class="mw-page-title-main">Grossite</span>

Grossite is a calcium aluminium oxide mineral with formula CaAl4O7. It is a colorless to white vitreous mineral which crystallizes in the monoclinic crystal system.

Larnite is a calcium silicate mineral with the formula Ca2SiO4. It is the calcium member of the olivine group of minerals.

<span class="mw-page-title-main">Znucalite</span>

Znucalite or CaZn11(UO2)(CO3)3(OH)20·4(H2O) is a rare, radioactive, white to pale cream colored uranium-containing carbonate mineral, hydrated calcium zinc uranyl carbonate hydroxide. Znucalite crystallizes in the orthorhombic system, often forming aggregates or crusts, and is found as a rare secondary species in carbonate-hosted (meaning it is mined from carbonate containing formations such as limestone) polymetallic veins, and nearby oxidizing uranium veins; on dump material and coating mine walls, apparently of post-mine origin. It fluoresces yellow-green under UV light.

<span class="mw-page-title-main">Scawtite</span>

Scawtite is a hydrous calcium silicate mineral with carbonate, formula: Ca7(Si3O9)2CO3·2H2O. It crystallizes in the monoclinic crystal system as thin plates or flat prisms.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Mineralienatlas - Fossilienatlas". www.mineralienatlas.de.
  3. 1 2 3 4 5 "Handbook of Mineralogy" (PDF).
  4. 1 2 3 "Portlandite: Mineral information, data and localities". www.mindat.org.
  5. "Portlandite Mineral Data". www.webmineral.com.
  6. Pallache, Charles; Berman, Harry; Frondel, Clifford (1944). The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana (7 ed.). Wiley. pp. 641–642. ISBN   9780471192398.