Potassium phthalimide

Last updated
Potassium phthalimide
Phthalimide Potassium V.1.svg
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.012.770
PubChem CID
UNII
Properties
C8H4KNO2
Molar mass 185.221 g/mol
AppearanceLight yellow solid
Melting point > 300 °C (572 °F; 573 K)
Soluble in water
Hazards
NFPA 704 (fire diamond)
Flammability code 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilHealth code 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformReactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no codePotassium phthalimide
1
2
0
Related compounds
Related compounds
Phthalimide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Potassium phthalimide is a chemical compound of formula C8H4KNO2. It is the potassium salt of phthalimide, and usually presents as fluffy, very pale yellow crystals. It can be prepared by adding a hot solution of phthalimide in ethanol to a solution of potassium hydroxide in ethanol; the desired product precipitates. [1]

This compound is a commercially available reagent used in the Gabriel synthesis of amines.

Gabriel Synthesis Scheme.png

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Ethanol is a chemical compound, a simple alcohol with the chemical formula C
2
H
6
O
. Its formula can be also written as CH
3
CH
2
OH or C
2
H
5
OH, and is often abbreviated as EtOH. Ethanol is a volatile, flammable, colorless liquid with a slight characteristic odor. It is a psychoactive substance and is the principal active ingredient found in alcoholic drinks.

Solution A homogeneous mixture which assumes the phase of the solvent

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Pyruvic acid (CH3COCOOH) is the simplest of the alpha-keto acids, with a carboxylic acid and a ketone functional group. Pyruvate, the conjugate base, CH3COCOO, is a key intermediate in several metabolic pathways throughout the cell.

Hygroscopy Phenomenon of attracting and holding water molecules

Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance's molecules, adsorbing substances can become physically changed, e.g., changing in volume, boiling point, viscosity or some other physical characteristic or property of the substance.

Potassium hydroxide chemical compound

Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.

Precipitation (chemistry) Chemical process

Precipitation defined as the creation of a solid from a solution. When the reaction occurs in a liquid solution, the solid formed is called the 'precipitate'. The chemical that causes the solid to form is called the 'precipitant'. Without sufficient force of gravity (settling) to bring the solid particles together, the precipitate remains in suspension. After sedimentation, especially when using a centrifuge to press it into a compact mass, the precipitate may be referred to as a 'pellet'. Precipitation can be used as a medium. The precipitate-free liquid remaining above the solid is called the 'supernate' or 'supernatant'. Powders derived from precipitation have also historically been known as 'flowers'. When the solid appears in the form of cellulose fibers which have been through chemical processing, the process is often referred to as regeneration.

Phthalic anhydride chemical compound

Phthalic anhydride is the organic compound with the formula :-C6H4(CO)2O. It is the anhydride of phthalic acid. Phthalic anhydride is a principal commercial form of phthalic acid. It was the first anhydride of a dicarboxylic acid to be used commercially. This white solid is an important industrial chemical, especially for the large-scale production of plasticizers for plastics. In 2000, the worldwide production volume was estimated to be about 3 million tonnes per year.

Imide class of chemical compounds

In organic chemistry, an imide is a functional group consisting of two acyl groups bound to nitrogen. The compounds are structurally related to acid anhydrides, although imides are more resistant toward hydrolysis. In terms of commercial applications, imides are best known as components of high-strength polymers, called polyimides.

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Potassium sulfate chemical compound

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Potassium dichromate chemical compound

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2
Cr
2
O
7
, is a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications. As with all hexavalent chromium compounds, it is acutely and chronically harmful to health. It is a crystalline ionic solid with a very bright, red-orange color. The salt is popular in the laboratory because it is not deliquescent, in contrast to the more industrially relevant salt sodium dichromate.

The Gabriel synthesis is a chemical reaction that transforms primary alkyl halides into primary amines. Traditionally, the reaction uses potassium phthalimide. The reaction is named after the German chemist Siegmund Gabriel.

Potassium acetate chemical compound

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Phthalimide Organic Compound

Phthalimide is the organic compound with the formula C6H4(CO)2NH. It is the imide derivative of phthalic anhydride. It is a sublimable white solid that is slightly soluble in water but more so upon addition of base. It is used as a precursor to other organic compounds as a masked source of ammonia.

Potassium nonahydridorhenate chemical compound

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9
anion is a rare example of a coordination complex bearing only hydride ligands.

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Hydroxy alpha sanshool chemical compound

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Sodium ferrioxalate chemical compound

Sodium ferrioxalate is a chemical compound with the formula Na
3
Fe(C
2
O
4
)
3
. It is also called sodium oxalatoferrate or sodium trisoxalatoferrate.

Georges-Simon Serullas was a professor of pharmacy notable for being the first to publish a work on Iodoform, an early antiseptic and disinfectant.

References

  1. P. L. Salzberg and J. V. Supniewski (1941). "β-Bromoethylphthalimide". Organic Syntheses .; Collective Volume, 1, p. 119