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Gadolinium is a chemical element; it has symbol Gd and atomic number 64. Gadolinium is a silvery-white metal when oxidation is removed. It is a malleable and ductile rare-earth element. Gadolinium reacts with atmospheric oxygen or moisture slowly to form a black coating. Gadolinium below its Curie point of 20 °C (68 °F) is ferromagnetic, with an attraction to a magnetic field higher than that of nickel. Above this temperature it is the most paramagnetic element. It is found in nature only in an oxidized form. When separated, it usually has impurities of the other rare-earths because of their similar chemical properties.
Sir William Crookes was a British chemist and physicist who attended the Royal College of Chemistry, now part of Imperial College London, and worked on spectroscopy. He was a pioneer of vacuum tubes, inventing the Crookes tube which was made in 1875. This was a foundational discovery that eventually changed the whole of chemistry and physics.
Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. In simpler terms, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum.
Thallium is a chemical element; it has symbol Tl and atomic number 81. It is a gray post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Chemists William Crookes and Claude-Auguste Lamy discovered thallium independently in 1861, in residues of sulfuric acid production. Both used the newly developed method of flame spectroscopy, in which thallium produces a notable green spectral line. Thallium, from Greek θαλλός, thallós, meaning "green shoot" or "twig", was named by Crookes. It was isolated by both Lamy and Crookes in 1862; Lamy by electrolysis, and Crookes by precipitation and melting of the resultant powder. Crookes exhibited it as a powder precipitated by zinc at the international exhibition, which opened on 1 May that year.
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Paul-Émile Lecoq de Boisbaudran, also called François Lecoq de Boisbaudran, was a French chemist known for his discoveries of the chemical elements gallium, samarium and dysprosium. He developed methods for separation and purification of the rare earth elements and was one of the pioneers of the science of spectroscopy.
Martin Heinrich Klaproth was a German chemist. He trained and worked for much of his life as an apothecary, moving in later life to the university. His shop became the second-largest apothecary in Berlin, and the most productive artisanal chemical research center in Europe.
Jean Charles Galissard de Marignac was a Swiss chemist whose work with atomic weights suggested the possibility of isotopes and the packing fraction of nuclei. His study of the rare earth elements led to his discovery of ytterbium in 1878 and co-discovery of gadolinium in 1880.
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Johan Gadolin was a Finnish chemist, physicist and mineralogist. Gadolin discovered a "new earth" containing the first rare-earth compound yttrium, which was later determined to be a chemical element. He is also considered the founder of Finnish chemistry research, as the second holder of the Chair of Chemistry at the Royal Academy of Turku. Gadolin was ennobled for his achievements and awarded the Order of Saint Vladimir and the Order of Saint Anna.
Coronium, also called newtonium, was the name of a suggested chemical element, hypothesised in the 19th century. The name, inspired by the solar corona, was given by Gruenwald in 1887. A new atomic thin green line in the solar corona was then considered to be emitted by a new element unlike anything else seen under laboratory conditions. It was later determined to be emitted by iron (Fe13+), so highly ionized that it was at that time impossible to produce in a laboratory.
The history of chemistry represents a time span from ancient history to the present. By 1000 BC, civilizations used technologies that would eventually form the basis of the various branches of chemistry. Examples include the discovery of fire, extracting metals from ores, making pottery and glazes, fermenting beer and wine, extracting chemicals from plants for medicine and perfume, rendering fat into soap, making glass, and making alloys like bronze.
Eugène-Anatole Demarçay was a French chemist who designed an apparatus to produce a spark using an induction coil and used it to generate the spectra of rare earth elements which he examined using spectroscopy, thus detecting the element europium in 1896, and isolated it as the oxide europia in 1901. He helped Marie Curie to confirm the existence of another new element, radium, in 1898.
Georges Urbain was a French chemist, a professor of the Sorbonne, a member of the Institut de France, and director of the Institute of Chemistry in Paris. Much of his work focused on the rare earths, isolating and separating elements such as europium and gadolinium, and studying their spectra, their magnetic properties and their atomic masses. He discovered the element lutetium. He also studied the efflorescence of saline hydrates.
Carl Axel Arrhenius was an officer in the Swedish army as well as an amateur geologist and chemist. He is best known for his discovery of the mineral ytterbite in 1787.
Baron Jöns Jacob Berzelius was a Swedish chemist. Berzelius is considered, along with Robert Boyle, John Dalton, and Antoine Lavoisier, to be one of the founders of modern chemistry. Berzelius became a member of the Royal Swedish Academy of Sciences in 1808 and served from 1818 as its principal functionary. He is known in Sweden as the "Father of Swedish Chemistry". Berzelius Day is celebrated on 20 August in honour of him.
Austrium is the name of a new chemical element proposed by Eduard Linnemann in 1886. As a chemist at the German University in Prague he experimented with the mineral orthite. In the course of his works over several years he detected spectral lines at 4165 and 4030 Angstrom, respectively, which he was not able to ascribe to any then known element. These findings were published only after his death after due consideration on May 6, 1886, by the Academy of Sciences of Prague.
Larned (Larry) Brown Asprey was an American chemist noted for his work on actinide, lanthanide, rare-earth, and fluorine chemistry, and for his contributions to nuclear chemistry on the Manhattan Project and later at the Los Alamos National Laboratory.
References
- ↑ Elder, Eleanor S (1980). "Sir William Crookes, Victorium, and the Library of Congress". Journal of Chemical Education. 57 (6): 421. Bibcode:1980JChEd..57..421E. doi:10.1021/ed057p421.
- ↑ Fontani, Marco; Costa, Mariagrazia; Orna, Mary Virginia (2014). The Lost Elements: The Periodic Table's Shadow Side. Oxford University Press. pp. 202–203. ISBN 9780199383368.
- ↑ Brock, William Hodson (2008). William Crookes (1832-1919) and the Commercialization of Science. Ashgate Publishing. pp. 321–325. ISBN 9780754663225.
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