White metal

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The white metals are a series of often decorative bright metal alloys used as a base for plated silverware, ornaments or novelties, as well as any of several lead-based or tin-based alloys used for things like bearings, jewellery, miniature figures, fusible plugs, some medals and metal type. [1] The term is also used in the antiques trade for an item suspected of being silver, but not hallmarked.

Contents

A white metal alloy may include antimony, tin, lead, cadmium, bismuth, and zinc (some of which are quite toxic). Not all of these metals are found in all white metal alloys. Metals are mixed to achieve a desired goal or need. As an example, a base metal for jewellery needs to be castable, polishable, have good flow characteristics, have the ability to cast fine detail without an excessive amount of porosity and cast at between 230 and 300  °C (446 and 572  °F ). [1]

Silver

In compliance with British law, the British fine art trade uses the term "white metal" in auction catalogues to describe foreign silver items which do not carry British Assay Office hallmarks, but which are nonetheless understood to be silver and are priced accordingly.

Tin-lead and tin-copper alloys

Bars and ingots of Babbitt metal Pigs and Bars of Babbitt.jpg
Bars and ingots of Babbitt metal

Tin-lead and tin-copper alloys such as Babbitt metal [2] have a low melting point, which is ideal for use as solder, but these alloys also have ideal characteristics for plain bearings. Most importantly for bearings, the material should be hard and wear-resistant and have a low coefficient of friction. It must also be shock-resistant, tough and sufficiently ductile to allow for slight misalignment prior to running-in.

Pure metals are soft, tough and ductile with a high coefficient of friction. Intermetallic compounds are hard and wear-resistant but brittle. By themselves, these do not make ideal bearing materials.

Alloys consist of small particles of a hard compound embedded in the tough, ductile background of a solid solution. In service the latter can wear away slightly, leaving the hard compound to carry the load. This wear also provides channels to allow in lubricant (oils). All bearing metals contain antimony (Sb), which forms hard cubic crystals.

 % Sn  % Sb  % Cu  % Pb Applications
933.53.5Light and medium internal combustion engine big-end bearings
8610.53.5Light and medium internal combustion engine main bearings
80113.06.0General-purpose heavy bearings (lead increases plasticity)
601028.51.5Heavy-duty marine engine bearings, electrical machines
40101.548.5Low-cost, general-purpose, medium-duty bearings

See also

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<span class="mw-page-title-main">Alloy</span> Mixture or metallic solid solution composed of two or more elements

An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity, and luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength.

<span class="mw-page-title-main">Bronze</span> Alloy of copper and tin

Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals and sometimes non-metals, such as phosphorus, or metalloids such as arsenic or silicon. These additions produce a range of alloys that may be harder than copper alone, or have other useful properties, such as strength, ductility, or machinability.

<span class="mw-page-title-main">Metal</span> Type of material

A metal is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile and malleable. These properties are the result of the metallic bond between the atoms or molecules of the metal.

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<span class="mw-page-title-main">Type metal</span> Metal alloys used in traditional typefounding and hot metal typesetting

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Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderability, to harden, to improve wearability, to reduce friction, to improve paint adhesion, to alter conductivity, to improve IR reflectivity, for radiation shielding, and for other purposes. Jewelry typically uses plating to give a silver or gold finish.

<span class="mw-page-title-main">Intermetallic</span> Type of metallic alloy

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References

  1. 1 2 "White Metals". Belmont Metals. 17 April 2019. Retrieved April 18, 2021.
  2. USpatent 1252,Isaac Babbitt,"Mode of making boxes for axles and gudgeons",issued 17 Jul 1839.