Alan S. Goldman

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Alan S. Goldman is an American chemist and Distinguished Professor of Chemistry at Rutgers University. [1] Goldman's research area is homogeneous catalysis with emphasis on C-H activation. [2]

Iridium pincer complex for alkane dehydrogenation. GoldmanPincer.svg
Iridium pincer complex for alkane dehydrogenation.

Recognition

Goldman has been recognized by numerous awards. He was awarded the ACS Catalysis Lectureship for the Advancement of Catalytic Science in 2018. [4] He received the ACS Award in Organometallic Chemistry in 2019 [5] and the Sir Geoffrey Wilkinson Award from the Royal Society of Chemistry (UK) in 2020. [6] In 2021, he was elected as a Fellow of the American Association for the Advancement of Science. [7]

Related Research Articles

In chemistry, dehydrogenation is a chemical reaction that involves the removal of hydrogen, usually from an organic molecule. It is the reverse of hydrogenation. Dehydrogenation is important, both as a useful reaction and a serious problem. At its simplest, it's a useful way of converting alkanes, which are relatively inert and thus low-valued, to olefins, which are reactive and thus more valuable. Alkenes are precursors to aldehydes, alcohols, polymers, and aromatics. As a problematic reaction, the fouling and inactivation of many catalysts arises via coking, which is the dehydrogenative polymerization of organic substrates.

<span class="mw-page-title-main">Transition metal pincer complex</span>

In chemistry, a transition metal pincer complex is a type of coordination complex with a pincer ligand. Pincer ligands are chelating agents that binds tightly to three adjacent coplanar sites in a meridional configuration. The inflexibility of the pincer-metal interaction confers high thermal stability to the resulting complexes. This stability is in part ascribed to the constrained geometry of the pincer, which inhibits cyclometallation of the organic substituents on the donor sites at each end. In the absence of this effect, cyclometallation is often a significant deactivation process for complexes, in particular limiting their ability to effect C-H bond activation. The organic substituents also define a hydrophobic pocket around the reactive coordination site. Stoichiometric and catalytic applications of pincer complexes have been studied at an accelerating pace since the mid-1970s. Most pincer ligands contain phosphines. Reactions of metal-pincer complexes are localized at three sites perpendicular to the plane of the pincer ligand, although in some cases one arm is hemi-labile and an additional coordination site is generated transiently. Early examples of pincer ligands were anionic with a carbanion as the central donor site and flanking phosphine donors; these compounds are referred to as PCP pincers.

Alkane metathesis is a class of chemical reaction in which an alkane is rearranged to give a longer or shorter alkane product. It is similar to olefin metathesis, except that olefin metathesis cleaves and recreates a carbon-carbon double bond, but alkane metathesis operates on a carbon-carbon single bond.

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References

  1. "Goldman, Alan". chem.rutgers.edu. Retrieved 21 November 2018.
  2. Choi, Jongwook; MacArthur, Amy H. Roy; Brookhart, Maurice; Goldman, Alan S. (2011). "Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes". Chemical Reviews. 111 (3): 1761–1779. doi:10.1021/cr1003503.
  3. Gordon, Benjamin M.; Lease, Nicholas; Emge, Thomas J.; Hasanayn, Faraj; Goldman, Alan S. (2022). "Reactivity of Iridium Complexes of a Triphosphorus-Pincer Ligand Based on a Secondary Phosphine. Catalytic Alkane Dehydrogenation and the Origin of Extremely High Activity". Journal of the American Chemical Society. 144 (9): 4133–4146. doi:10.1021/jacs.1c13309. OSTI   1866620.
  4. "Professor Alan Goldman Interview". pubs.acs.org. Retrieved 21 November 2018.
  5. Meerovich, Amy. "Congratulations Alan Goldman!". chem.rutgers.edu. Retrieved 21 November 2018.
  6. "Royal Society of Chemistry 2020 prize and award winners". rsc.org. Retrieved 5 September 2020.
  7. "2021 AAAS Fellows". aaas.org. Retrieved 24 May 2022.