Aluminized steel

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Aluminized steel Aluminized Steel.jpg
Aluminized steel

Aluminized steel is steel that has been plated with aluminium or aluminium-silicon alloy) The steel workpiece is immersed in molten aluminum to produce a tight metallic bond between the steel and coating. The product has a unique combination of properties possessed neither by steel nor by aluminium alone, analogous to hot-dip galvanizing. Aluminized steel is more resistant to corrosion than bare steel [1] while retaining properties of steel, at temperature lower than the melting point of aluminum, 800 °C (1,470 °F). Common applications include heat exchangers in residential furnaces, commercial rooftop HVAC units, automotive mufflers, ovens, kitchen ranges, water heaters, fireplaces, barbecue burners, and baking pans. Aluminized steel transfers heat more effectively than bare steel. It serves where galvanized steel might have been used historically, without galvanized steel's drawbacks.

Contents

Characteristics vary depending on the aluminum alloy used.

Types

Type 1
Hot-dip coated with a thin layer of aluminium-silicon alloy. 5% to 11% added silicon promotes better adherence. It is intended principally for heat resisting applications and also for uses where corrosion resistance and heat are required. Possible end uses are mufflers, furnaces, ovens, ranges, heaters, water heaters, fireplaces, and baking pans. Aluminized steel can withstand 550 °C (1,022 °F) with almost no change in the base material. But due to silicon content it develops black spot. Aluminized steel has slowly started to convert bakery trays which were previously made by galvanized or galvalume steel as it does not contain lead which is poisonous. Type 1 is also commonly found in industrial products.
Type 2
Hot-dip coated with commercially pure aluminum. It is intended principally for applications requiring atmospheric corrosion resistance. Type 2 may ultimately be manufactured into corrugated roofing and siding, grain bins, drying ovens, and air-conditioner condenser housings.

Properties

Structure of aluminized steel under a) light microscope and b) scanning electron microscope (SEM): 1) oxidative layer 2) aluminized layer 3) substrate Structure of Aluminized Steel.png
Structure of aluminized steel under a) light microscope and b) scanning electron microscope (SEM): 1) oxidative layer 2) aluminized layer 3) substrate
Weight gain of metal samples, oxidative time: 1) no aluminized layer 2) aluminized layer Aluminized Steel Oxidation over TIme.png
Weight gain of metal samples, oxidative time: 1) no aluminized layer 2) aluminized layer

The basic structure of aluminized steel is a thin aluminium oxide layer outside, then an intermetallic layer that is a mix of aluminium, silicon, and steel, and finally a steel core. [2]

Both Type 1 and Type 2 show excellent high reflectivity characteristics. At temperatures up to 842 °C (1,548 °F), aluminized steel reflects up to 80% of heat projected onto it. [3] Aluminized steel has the ability to maintain its strength at temperatures up to 677 °C (1,251 °F). Although stainless steel is the stronger of the two, aluminized steel has a greater electrostatic surface, and can therefore reflect heat better.

Aluminized steel is highly resistant to corrosion because of the thin layers of aluminium and silicon, which keep the underlying steel from oxidizing. These thin layers also keep pit corrosion from occurring, especially during exposure to salts that affect most other metals. However, despite the good corrosion resistance of aluminized steel, if the aluminium layer is disrupted and the steel is exposed, then the steel may oxidize and corrosion may occur.

Consumption

In North America nearly 700,000 tons of aluminized steel are consumed annually. [4] Some of the common products made from aluminized steel include water heaters, ranges, furnaces, space heaters and grills.

Processing

Aluminized steel can be made using a variety of processes, cladding, hot dipping, galvanic coating, metallizing, and calorizing, but the most effective process is hot dipping. The process of hot dipping starts by cleaning the steel, then placing the steel in a bath of Al-11%Si at a temperature of 988K and shaken, then pulled out and air dried. [5] The aluminium diffuses into the steel, creating an intermetallic layer above the steel base layer, but below the outside aluminum coating. The aluminium coating is oxidized to help protect the inner steel from corrosion and further aluminium diffusion. [6] The silicon is added to the aluminium bath to create a thinner layer of aluminium on the steel. The hot dipping process is cheaper and more effective to produce aluminized steel than any other process. [7]

Uses

Automotive muffler and exhaust system made of aluminized steel Car Parts.png
Automotive muffler and exhaust system made of aluminized steel

Aluminized steel was developed for providing more structural durability and a high yield strength in highly corrosive environments. It maintains the strength of high-alloy steel, but is cheaper to produce than high-alloy steels and thus is a preferred material for manufacturing automobile and motorcycle exhaust gas systems. [7]

Al-Si coatings are used to protect boron steel when hot pressing.

See also

Related Research Articles

<span class="mw-page-title-main">Galvanization</span> Process of coating steel or iron with zinc to prevent rusting

Galvanization or galvanizing is the process of applying a protective zinc coating to steel or iron, to prevent rusting. The most common method is hot-dip galvanizing, in which the parts are submerged in a bath of hot, molten zinc.

<span class="mw-page-title-main">Rust</span> Type of iron oxide

Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture. Rust consists of hydrous iron(III) oxides (Fe2O3·nH2O) and iron(III) oxide-hydroxide (FeO(OH), Fe(OH)3), and is typically associated with the corrosion of refined iron.

<span class="mw-page-title-main">Stainless steel</span> Steel alloy resistant to corrosion

Stainless steel is an alloy of iron that is resistant to rusting and corrosion. It contains at least 11% chromium and may contain elements such as carbon, other nonmetals and metals to obtain other desired properties. Stainless steel's resistance to corrosion results from the chromium, which forms a passive film that can protect the material and self-heal in the presence of oxygen.

<span class="mw-page-title-main">Corrosion</span> Gradual destruction of materials by chemical reaction with its environment

Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.

Passivation, in physical chemistry and engineering, refers to coating a material so it becomes "passive", that is, less readily affected or corroded by the environment. Passivation involves creation of an outer layer of shield material that is applied as a microcoating, created by chemical reaction with the base material, or allowed to build by spontaneous oxidation in the air. As a technique, passivation is the use of a light coat of a protective material, such as metal oxide, to create a shield against corrosion. Passivation of silicon is used during fabrication of microelectronic devices. In electrochemical treatment of water, passivation reduces the effectiveness of the treatment by increasing the circuit resistance, and active measures are typically used to overcome this effect, the most common being polarity reversal, which results in limited rejection of the fouling layer.

<span class="mw-page-title-main">Hot-dip galvanization</span> Process of coating iron or steel with molten zinc

Hot-dip galvanization is a form of galvanization. It is the process of coating iron and steel with zinc, which alloys with the surface of the base metal when immersing the metal in a bath of molten zinc at a temperature of around 450 °C (842 °F). When exposed to the atmosphere, the pure zinc (Zn) reacts with oxygen (O2) to form zinc oxide (ZnO), which further reacts with carbon dioxide (CO2) to form zinc carbonate (ZnCO3), a usually dull grey, fairly strong material that protects the steel underneath from further corrosion in many circumstances. Galvanized steel is widely used in applications where corrosion resistance is needed without the cost of stainless steel, and is considered superior in terms of cost and life-cycle. It can be identified by the crystallization patterning on the surface (often called a "spangle").

<span class="mw-page-title-main">Cookware and bakeware</span> Food preparation containers

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<span class="mw-page-title-main">Brazing</span> High-temperature soldering; metal-joining technique by high-temperature molten metal filling

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<span class="mw-page-title-main">Anodizing</span> Metal treatment process

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<span class="mw-page-title-main">Heating element</span> Device that converts electricity into heat

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<span class="mw-page-title-main">Superalloy</span> Alloy with higher durability than normal metals

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<span class="mw-page-title-main">Plasma electrolytic oxidation</span>

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<span class="mw-page-title-main">Aluminium alloy</span> Alloy in which aluminium is the predominant metal

An aluminium alloy is an alloy in which aluminium (Al) is the predominant metal. The typical alloying elements are copper, magnesium, manganese, silicon, tin, nickel and zinc. There are two principal classifications, namely casting alloys and wrought alloys, both of which are further subdivided into the categories heat-treatable and non-heat-treatable. About 85% of aluminium is used for wrought products, for example rolled plate, foils and extrusions. Cast aluminium alloys yield cost-effective products due to the low melting point, although they generally have lower tensile strengths than wrought alloys. The most important cast aluminium alloy system is Al–Si, where the high levels of silicon (4–13%) contribute to give good casting characteristics. Aluminium alloys are widely used in engineering structures and components where light weight or corrosion resistance is required.

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<span class="mw-page-title-main">Aluminium-conductor steel-reinforced cable</span> Type of overhead power line conductor

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References

  1. ""Aluminized steel Offers Attractive Physical Characteristics For Use In Industrial Duct Construction". Sheet Metal and Air Conditioning Contractors' National Association. Retrieved 26 Feb 2011". Archived from the original on 2011-02-20. Retrieved 2011-02-26.
  2. Kee-Hyun, Kim. Van-Daele, Benny. Van-Tendeloo, Gusfaaf. and Jong-Kyu, Yoon. (2006). "Observations of Intermetallic Compound Formation of Hot Dip Aluminized steel". Materials Science Forum, 519-21(2), 1871-75.
  3. Atlas Steel - Aluminized steel
  4. "Block Steel Aluminized Steel Specialists". Archived from the original on 2010-09-30. Retrieved 2011-11-29.
  5. Rajendran, R. Venkataswamy, S. Jaikrishna, U. Gowrishankar, N. and Rajadurai, A. (2006). "Effect of Process Parameters in Hot Dip Aluminizing of Medium Carbon Steel".
  6. Deqing, Wang. and Ziyuan, Shi. (2003) "Formation of Al2O3 Layer on Steel". Journal of Materials Science Letters, 22(14), 1003-1006.
  7. 1 2 Wang, Chaur. Jeng. Badaruddin, Mohd.. (2010) "The dependence of high temperature resistance of aluminized steel exposed to water-vapour oxidation". Surface and Coatings Technology, 205(5), 1200-1205.