Arthur J. Spivack (born July 9, 1956 in Queens, New York), also known as "Art" or "Arturo", is an American geochemist. He is currently a professor at the University of Rhode Island Graduate School of Oceanography. [1]
Spivack's research interest is the geochemistry of the oceans, atmosphere, and crust. He developed the use of boron isotopes for determining the pH of ancient oceans. [2] This approach provides a principal basis for estimating atmospheric CO2 concentrations of the last several tens of million years. [3] He led the investigation of the 2015 Salty Brine Beach explosion. [4] He has also contributed to scientific understanding of geochemical fluxes in mid-ocean-ridge hydrothermal systems and subduction zones [5] and understanding of subseafloor life. [6]
Spivack received his bachelor's degree (1980) in chemistry from the Massachusetts Institute of Technology (MIT) and his Ph.D. in oceanography from MIT and Woods Hole Oceanographic Institution (1986).
The Archean Eon, in older sources sometimes called the Archaeozoic, is the second of the four geologic eons of Earth's history, preceded by the Hadean Eon and followed by the Proterozoic. The Archean represents the time period from 4,031 to 2,500 Mya. The Late Heavy Bombardment is hypothesized to overlap with the beginning of the Archean. The Huronian glaciation occurred at the end of the eon.
The Eoarchean is the first era of the Archean Eon of the geologic record. It spans 431 million years, from the end of the Hadean Eon 4031 Mya to the start of the Paleoarchean Era 3600 Mya. Some estimates place the beginnings of life on Earth in this era, while others place it earlier. Evidence of archaea and cyanobacteria date to 3500 Mya, comparatively shortly after the Eoarchean. At that time, the atmosphere was without oxygen and the pressure values ranged from 10 to 100 bar.
Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3), and dolomite rock (also known as dolostone), which is composed of mineral dolomite (CaMg(CO3)2). They are usually classified based on texture and grain size. Importantly, carbonate rocks can exist as metamorphic and igneous rocks, too. When recrystallized carbonate rocks are metamorphosed, marble is created. Rare igneous carbonate rocks even exist as intrusive carbonatites and, even rarer, there exists volcanic carbonate lava.
Charles David Keeling was an American scientist whose recording of carbon dioxide at the Mauna Loa Observatory confirmed Svante Arrhenius's proposition (1896) of the possibility of anthropogenic contribution to the greenhouse effect and global warming, by documenting the steadily rising carbon dioxide levels. The Keeling Curve measures the progressive buildup of carbon dioxide, a greenhouse gas, in the atmosphere.
The important sulfur cycle is a biogeochemical cycle in which the sulfur moves between rocks, waterways and living systems. It is important in geology as it affects many minerals and in life because sulfur is an essential element (CHNOPS), being a constituent of many proteins and cofactors, and sulfur compounds can be used as oxidants or reductants in microbial respiration. The global sulfur cycle involves the transformations of sulfur species through different oxidation states, which play an important role in both geological and biological processes. Steps of the sulfur cycle are:
The Great Oxidation Event (GOE) or Great Oxygenation Event, also called the Oxygen Catastrophe, Oxygen Revolution, Oxygen Crisis or Oxygen Holocaust, was a time interval during the Earth's Paleoproterozoic era when the Earth's atmosphere and shallow seas first experienced a rise in the concentration of free oxygen. This began approximately 2.460–2.426 Ga (billion years) ago during the Siderian period and ended approximately 2.060 Ga ago during the Rhyacian. Geological, isotopic and chemical evidence suggests that biologically produced molecular oxygen (dioxygen or O2) started to accumulate in the Archean prebiotic atmosphere due to microbial photosynthesis, and eventually changed it from a weakly reducing atmosphere practically devoid of oxygen into an oxidizing one containing abundant free oxygen, with oxygen levels being as high as 10% of modern atmospheric level by the end of the GOE.
Paleoceanography is the study of the history of the oceans in the geologic past with regard to circulation, chemistry, biology, geology and patterns of sedimentation and biological productivity. Paleoceanographic studies using environment models and different proxies enable the scientific community to assess the role of the oceanic processes in the global climate by the re-construction of past climate at various intervals. Paleoceanographic research is also intimately tied to paleoclimatology.
The origin of water on Earth is the subject of a body of research in the fields of planetary science, astronomy, and astrobiology. Earth is unique among the rocky planets in the Solar System in having oceans of liquid water on its surface. Liquid water, which is necessary for all known forms of life, continues to exist on the surface of Earth because the planet is at a far enough distance from the Sun that it does not lose its water, but not so far that low temperatures cause all water on the planet to freeze.
The Middle Miocene Climatic Transition (MMCT) was a relatively steady period of climatic cooling that occurred around the middle of the Miocene, roughly 14 million years ago (Ma), during the Langhian stage, and resulted in the growth of ice sheet volumes globally, and the reestablishment of the ice of the East Antarctic Ice Sheet (EAIS). The term Middle Miocene disruption, alternatively the Middle Miocene extinction or Middle Miocene extinction peak, refers to a wave of extinctions of terrestrial and aquatic life forms that occurred during this climatic interval. This period was preceded by the Middle Miocene Climatic Optimum (MMCO), a period of relative warmth from 18 to 14 Ma. Cooling that led to the Middle Miocene disruption is primarily attributed CO2 being pulled out of the Earth's atmosphere by organic material before becoming caught in different locations like the Monterey Formation. These may have been amplified by changes in oceanic and atmospheric circulation due to continental drift. Additionally, orbitally paced factors may also have played a role.
Harmon Craig was an American geochemist who worked briefly for the University of Chicago (1951-1955) before spending the majority of his career at Scripps Institution of Oceanography (1955-2003).
Earth science or geoscience includes all fields of natural science related to the planet Earth. This is a branch of science dealing with the physical, chemical, and biological complex constitutions and synergistic linkages of Earth's four spheres: the biosphere, hydrosphere/cryosphere, atmosphere, and geosphere. Earth science can be considered to be a branch of planetary science but with a much older history.
Marine chemistry, also known as ocean chemistry or chemical oceanography, is the study of the chemical composition and processes of the world’s oceans, including the interactions between seawater, the atmosphere, the seafloor, and marine organisms. This field encompasses a wide range of topics, such as the cycling of elements like carbon, nitrogen, and phosphorus, the behavior of trace metals, and the study of gases and nutrients in marine environments. Marine chemistry plays a crucial role in understanding global biogeochemical cycles, ocean circulation, and the effects of human activities, such as pollution and climate change, on oceanic systems. It is influenced by plate tectonics and seafloor spreading, turbidity, currents, sediments, pH levels, atmospheric constituents, metamorphic activity, and ecology.
The oceanic carbon cycle is composed of processes that exchange carbon between various pools within the ocean as well as between the atmosphere, Earth interior, and the seafloor. The carbon cycle is a result of many interacting forces across multiple time and space scales that circulates carbon around the planet, ensuring that carbon is available globally. The Oceanic carbon cycle is a central process to the global carbon cycle and contains both inorganic carbon and organic carbon. Part of the marine carbon cycle transforms carbon between non-living and living matter.
Ralph Franklin Keeling is a professor at Scripps Institution of Oceanography. He is the Principal Investigator for the Atmospheric Oxygen Research Group at Scripps and is the director of the Scripps CO2 Program, the measurement program behind the Keeling curve, which was started by his father Charles David Keeling in 1958. Ralph Keeling has developed precise instruments and techniques for the measurement of atmospheric oxygen and anthropogenic CO2 in the ocean, and for the analysis of land and ocean carbon sinks.
Euxinia or euxinic conditions occur when water is both anoxic and sulfidic. This means that there is no oxygen (O2) and a raised level of free hydrogen sulfide (H2S). Euxinic bodies of water are frequently strongly stratified; have an oxic, highly productive, thin surface layer; and have anoxic, sulfidic bottom water. The word "euxinia" is derived from the Greek name for the Black Sea (Εὔξεινος Πόντος (Euxeinos Pontos)) which translates to "hospitable sea". Euxinic deep water is a key component of the Canfield ocean, a model of oceans during part of the Proterozoic eon (a part specifically known as the Boring Billion) proposed by Donald Canfield, an American geologist, in 1998. There is still debate within the scientific community on both the duration and frequency of euxinic conditions in the ancient oceans. Euxinia is relatively rare in modern bodies of water, but does still happen in places like the Black Sea and certain fjords.
Steven D’Hondt is an American geomicrobiologist who studies microbial communities living beneath the seafloor. He is a professor of oceanography at the University of Rhode Island.
Carbonate-associated sulfates (CAS) are sulfate species found in association with carbonate minerals, either as inclusions, adsorbed phases, or in distorted sites within the carbonate mineral lattice. It is derived primarily from dissolved sulfate in the solution from which the carbonate precipitates. In the ocean, the source of this sulfate is a combination of riverine and atmospheric inputs, as well as the products of marine hydrothermal reactions and biomass remineralisation. CAS is a common component of most carbonate rocks, having concentrations in the parts per thousand within biogenic carbonates and parts per million within abiogenic carbonates. Through its abundance and sulfur isotope composition, it provides a valuable record of the global sulfur cycle across time and space.
The silica cycle is the biogeochemical cycle in which biogenic silica is transported between the Earth's systems. Silicon is considered a bioessential element and is one of the most abundant elements on Earth. The silica cycle has significant overlap with the carbon cycle and plays an important role in the sequestration of carbon through continental weathering, biogenic export and burial as oozes on geologic timescales.
Adina Paytan is a research professor at the Institute of Marine Sciences at the University of California, Santa Cruz. known for research into biogeochemical cycling in the present and the past. She has over 270 scientific publications in journals such as Science, Nature, Proceedings of the National Academy of Sciences, and Geophysical Research Letters.
Stanley Robert Hart is an American geologist, geochemist, leading international expert on mantle isotope geochemistry, and pioneer of chemical geodynamics.