Avicennite

Last updated
Avicennite
General
Category Mineral
Formula
(repeating unit)
Tl2O3
Strunz classification 4.CB.10
Dana classification 04.03.08.01
Crystal system Cubic
Crystal class Diploidal (m3)
H-M symbol: (2/m 3)
Space group Ia3
Identification
ColorGrayish black with brownish black tint
Mohs scale hardness2 [1]
Density 8.9 [2]

Avicennite (thallium(III) oxide) is an oxide mineral. It was discovered around the Dzhuzumli village, Samarqand, Uzbekistan. [2] It is named after Avicenna, a Persian doctor and polymath. [3]

See also

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<span class="mw-page-title-main">Thallium(III) oxide</span> Chemical compound

Thallium(III) oxide, also known as thallic oxide, is a chemical compound of thallium and oxygen. It occurs in nature as the rare mineral avicennite. Its structure is related to that of Mn2O3 which has a bixbyite like structure. Tl2O3 is metallic with high conductivity and is a degenerate n-type semiconductor which may have potential use in solar cells. A method of producing Tl2O3 by MOCVD is known. Any practical use of thallium(III) oxide will always have to take account of thallium's poisonous nature. Contact with moisture and acids may form poisonous thallium compounds.

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Yttriaite-(Y) is an exceedingly rare mineral, a natural form of yttrium oxide, Y2O3. In terms of chemistry it is yttrium-analogue of kangite, arsenolite, avicennite and senarmontite (isometric minerals). Other minerals with the general formula A2O3 include corundum, bismite, bixbyite, eskolaite, hematite, karelianite, sphaerobismoite, tistarite, and valentinite. Yttriaite-(Y) forms tiny inclusions in native tungsten.

Chrysothallite is a rare thallium-bearing chloride mineral with the formula K6Cu6Tl3+Cl17(OH)4•H2O. Chrysothallite is unique in being only the second mineral with essential trivalent thallium, a feature shared with natural thallium(III) oxide, avicennite. Another examples of natural thallium chlorides are steropesite, Tl3BiCl6, and lafossaite, TlCl. Chrysothallite is one of numerous fumarolic minerals discovered among fumarolic sites of the Tolbachik volcano, Kamchatka, Russia The mineral is named in allusion to its colour and thallium content.

References

  1. "Avicennite Mineral Data".
  2. 1 2 Mindat - Avicennite
  3. Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (eds.). "Avicennite". Handbook of Mineralogy (PDF). Chantilly, VA, USA: Mineralogical Society of America. Retrieved 13 March 2022.