Borate sulfide

Borate sulfides are chemical mixed anion compounds that contain any kind of borate and sulfide ions. They are distinct from thioborates in which sulfur atoms replace oxygen in borates. There are also analogous borate selenides, with selenium ions instead of sulfur.

List

name	chem	mw	crystal system	space group	unit cell	volume	density	comments	references
	Zn4B6O12S			I43m				NLO 1.9 × KDP	[1]
cadmium sulfur boracite	Cd3B7O13S2		cubic	F43c					[2]
	La6Nb2MgSB8O26		trigonal	P3	a=8.2137 c =8.8601			clear	[3]
	Ce6Nb2MgSB8O26		trigonal	P3	a=8.1672 c=8.8093			clear	[3]
	Pr6Nb2MgSB8O26		trigonal	P3	a=8.1362 c=8.7716			yellowish green	[3]
	Nd6Nb2MgSB8O26		trigonal	P3	a=8.1135 c=8.7469			clear	[3]
EBOS	Eu2B5O9S	534.03	orthorhombic	Pnn2	a=11.2909 b=11.3742 c=6.4440 Z=4	827.57	4.286	black	[4]
EBOSI	Eu4.5(B5O9)2SI	1238.88	orthorhombic	Pnn2	a=11.529 b=11.550 c=6.5070 Z=2	866.5	4.748	yellow-green band gap 1.98 eV	[4]
EMSBO	Eu9MgS2B20O41	2328.27	Hexagonal	P63/m	a=8.2708 c=24.919 Z=2	1476.3	5.238	brown	[5]
	Eu6Ta2MgSB8O26	1832.51	trigonal	P3	a=8.0431 c=8.6486 Z=1	484.53	6.280		[6]
	Sm3S3BO3	606.04	triclinic	P1	a=4.0173 b=7.647 c=11.241  α=91.339  β=91.275 γ=90.349 Z=2	345.14	5.832	green; band gap 2.5 eV	[7]
	Gd3S3BO3	626.74	triclinic	P1	a=3.9725 b=7.5945 c=11.182 α=91.402 β=91.093 γ=90.206 Z=2	337.30	6.173	pale yellow; band gap 2.65 eV	[8]

References

1. Zhou, Wenfeng; Yao, Wen-Dong; Tang, Ru-Ling; Xue, Huaiguo; Guo, Sheng-Ping (2021-06-25). "Second-order nonlinear optical and photoelectric properties of Zn4B6O12S". Journal of Alloys and Compounds. 867: 158879. doi: 10.1016/j.jallcom.2021.158879 . ISSN   0925-8388. S2CID   233544941.
2. Gould, R O; Nelmes, R J; Gould, S E B (1981-12-10). "Structural studies of boracites. VII. Cadmium sulphur boracite at room temperature" . Journal of Physics C: Solid State Physics. 14 (34): 5259–5267. Bibcode:1981JPhC...14.5259G. doi:10.1088/0022-3719/14/34/008. ISSN   0022-3719.
3. Tang, Ru-Ling; Wei, Yu-Long; Chi, Yang; Shi, Zhi-Hui; Liu, Wenlong; Guo, Sheng-Ping (2022-06-13). "Cation Regulation to Investigate the Chalcogenide Borate RE 6 Nb 2 MgSB 8 O 26 (RE = La–Nd) Family" . Inorganic Chemistry. 61 (23): 8653–8661. doi:10.1021/acs.inorgchem.2c00033. ISSN   0020-1669. PMID   35622004. S2CID   249095609.
4. Chi, Yang; Xue, Huai-Guo; Guo, Sheng-Ping (2020-01-21). "Designing Sulfide Borate as a Novel Type of Second-Order Nonlinear-Optical Material" . Inorganic Chemistry. 59 (2): 1547–1555. doi:10.1021/acs.inorgchem.9b03426. ISSN   0020-1669. PMID   31909601. S2CID   210043683.
5. Chi, Yang; Xu, Jing; Xue, Huai-Guo; Zhang, Yueping; Chen, Xiaolong; Whangbo, Myung-Hwan; Guo, Sheng-Ping; Deng, Shuiquan (2019-06-19). "Triple-Kagomé-Layer Slabs of Mixed-Valence Rare-Earth Ions Exhibiting Quantum Spin Liquid Behaviors: Synthesis and Characterization of Eu9MgS2B20O41" . Journal of the American Chemical Society. 141 (24): 9533–9536. doi:10.1021/jacs.9b04627. ISSN   0002-7863. PMID   31184141. S2CID   184485492.
6. Shi, Zhi-Hui; Chi, Yang; Yang, Mei; Liu, Wenlong; Guo, Sheng-Ping (2020-03-16). "A Series of Chalcogenide Borates RE6Ta2MgQB8O26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B4O10 Cluster" . Inorganic Chemistry. 59 (6): 3532–3536. doi:10.1021/acs.inorgchem.0c00086. ISSN   0020-1669. PMID   32090554. S2CID   211263182.
7. Guo, Sheng-Ping; Chi, Yang; Xue, Huai-Guo (2015-12-07). "Sm 3 S 3 BO 3 : The First Sulfide Borate without S–O and B–S Bonds" . Inorganic Chemistry. 54 (23): 11052–11054. doi:10.1021/acs.inorgchem.5b01930. ISSN   0020-1669. PMID   26558599.
8. Chi, Yang; Guo, Sheng-Ping; Kong, Hong-Jian; Xue, Huai-Guo (2016-08-01). "Crystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE3S3BO3 (RE = Sm, Gd)" . New Journal of Chemistry. 40 (8): 6720–6727. doi:10.1039/C6NJ00549G. ISSN   1369-9261.