Chameleon coating

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Chameleon coating, also known as nano composite tribological coating, is an adaptive adhesive that uses nanotechnology to adjust to environmental fluctuations to make living conditions more suitable to the object that the coat has been applied to.

Contents

Purpose

The purpose of chameleon coating is to provide optimal performance of material in any environment. The idea is that when a sudden change in the environment occurs the particular nano coating will change its chemical properties to better suit itself in the environment in order to avoid wear due to friction and abrasion. Chameleon coating is supposed to resolve the issues with fluid hydraulics where atmospheric pressure changes under different environments. The chemical properties of fluid hydraulics alter under different atmospheric pressure because liquids and gases expand and condense under different pressures. Thus the goal of chameleon coating is to provide the same lubrication in machines from fluids such as oil but without the drawbacks of the coating or lubrication deteriorating under variable environments. [1] [2] [3]

Development

The beginning of chameleon coating was not always nanoscaled until recent developments in nanoengineering. Before the use of nano films (coatings), the films used to provide the beneficiary aspects of the coating would break down easier and faster due to consistent wear and tear. The use of the nano thin films helped control dislocating formation of the film and helped reduce the shear rate (rate at which the film deteriorated) due to abrasion and wear several folds over. The term “chameleon coating” was used in analogy to the actual coating of a chameleon where the coat of a chameleon is able to adapt to its environment as a defense mechanism to avoid predators and increase its chances of survival. The use of diamond-like carbon for short is generally one of the nano films used to inhibit abrasion. A possible nano film that could be used to counteract temperature changes are the pure metals Ag (silver) and Au (gold). Silver and gold can withstand high temperatures and remain soft, which is desirable for coating properties. Using a lattice matrix (a template for the coating using the basket weave design), nano engineers are able to utilize properties of the diamond-like carbons and pure metals to make chameleon coatings more adaptable at even more varied environments. [3]

Applications

The most common application for chameleon coating is in aerospace technology, where the environment is always changing due to changes in altitude. On the earth the air is humid, and temperature varies only slightly in comparison to other environments like space. The use of oil for reduced friction and wear, and lubrication applies to those ambient conditions only found on earth. When the frontier changes from atmosphere to orbit, temperatures can range from -150 °C to nearly 200 °C [4] many of these lubrications break down at accelerated rates and thus become useless. Space satellites are under such conditions where liquid lubrication is useless as many liquid lubricants become prone to volatilization due to extremely low pressures - from nearly 100 kPa at launch, to 10 nPa in orbit. [5] With the help of chameleon coating, the life expectancy of satellites range from 15 to about 30 years. [2] Chameleon coatings are also often used on hypersonic and reusable launch vehicles that require lubrication in ambient atmosphere, vacuum (space), and during re-entry (high temperature). A typical multilayer coating may use a molybdenum disulfide or diamond-like carbon for low friction at ambient conditions. A layer of teflon may be used for vacuum service along with a silver or gold containing layer for high temperature lubricity.

Related Research Articles

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Polytetrafluoroethylene Synthetic polymer

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Fluid bearings are bearings in which the load is supported by a thin layer of rapidly moving pressurized liquid or gas between the bearing surfaces. Since there is no contact between the moving parts, there is no sliding friction, allowing fluid bearings to have lower friction, wear and vibration than many other types of bearings. Thus, it is possible for some fluid bearings to have near-zero wear if operated correctly.

Cutting fluid

Cutting fluid is a type of coolant and lubricant designed specifically for metalworking processes, such as machining and stamping. There are various kinds of cutting fluids, which include oils, oil-water emulsions, pastes, gels, aerosols (mists), and air or other gases. Cutting fluids are made from petroleum distillates, animal fats, plant oils, water and air, or other raw ingredients. Depending on context and on which type of cutting fluid is being considered, it may be referred to as cutting fluid, cutting oil, cutting compound, coolant, or lubricant.

Lubrication The presence of a material to reduce friction between two surfaces.

Lubrication is the process or technique of using a lubricant to reduce friction and wear and tear in a contact between two surfaces. The study of lubrication is a discipline in the field of tribology.

Wear Damaging, gradual removal or deformation of material at solid surfaces

Wear is the damaging, gradual removal or deformation of material at solid surfaces. Causes of wear can be mechanical or chemical. The study of wear and related processes is referred to as tribology.

Tribology is the science and engineering of interacting surfaces in relative motion. It includes the study and application of the principles of friction, lubrication, and wear. Tribology is highly interdisciplinary. It draws on many academic fields, including physics, chemistry, materials science, mathematics, biology, and engineering. People who work in the field of tribology are referred to as tribologists.

Galling A form of wear caused by adhesion between sliding surfaces

Galling is a form of wear caused by adhesion between sliding surfaces. When a material galls, some of it is pulled with the contacting surface, especially if there is a large amount of force compressing the surfaces together. Galling is caused by a combination of friction and adhesion between the surfaces, followed by slipping and tearing of crystal structure beneath the surface. This will generally leave some material stuck or even friction welded to the adjacent surface, whereas the galled material may appear gouged with balled-up or torn lumps of material stuck to its surface.

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A piston ring is a metallic split ring that is attached to the outer diameter of a piston in an internal combustion engine or steam engine.

Tribometer An instrument that measures tribological quantities

A tribometer is an instrument that measures tribological quantities, such as coefficient of friction, friction force, and wear volume, between two surfaces in contact. It was invented by the 18th century Dutch scientist Musschenbroek

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Polyphenyl ether

Phenyl ether polymers are a class of polymers that contain a phenoxy or a thiophenoxy group as the repeating group in ether linkages. Commercial phenyl ether polymers belong to two chemical classes: polyphenyl ethers (PPEs) and polyphenylene oxides (PPOs). The phenoxy groups in the former class of polymers do not contain any substituents whereas those in the latter class contain 2 to 4 alkyl groups on the phenyl ring. The structure of an oxygen-containing PPE is provided in Figure 1 and that of a 2, 6-xylenol derived PPO is shown in Figure 2. Either class can have the oxygen atoms attached at various positions around the rings.

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Dry lubricants or solid lubricants are materials that, despite being in the solid phase, are able to reduce friction between two surfaces sliding against each other without the need for a liquid oil medium.

Tribocorrosion Material degradation due to corrosion and wear.

Tribocorrosion is a material degradation process due to the combined effect of corrosion and wear. The name tribocorrosion expresses the underlying disciplines of tribology and corrosion. Tribology is concerned with the study of friction, lubrication and wear and corrosion is concerned with the chemical and electrochemical interactions between a material, normally a metal, and its environment. As a field of research tribocorrosion is relatively new, but tribocorrosion phenomena have been around ever since machines and installations are being used.

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Space tribology is a discipline in the field of tribology which deals with tribological systems for spacecraft applications. Research in the field aims to design reliable tribological systems that can withstand the harsh environment of space.

Extreme tribology

Extreme tribology refers to tribological situations under extreme operating conditions which can be related to high loads and/or temperatures, or severe environments. Also, they may be related to high transitory contact conditions, or to situations with near-impossible monitoring and maintenance opportunities. In general, extreme conditions can typically be categorized as involving abnormally high or excessive exposure to e.g. cold, heat, pressure, vacuum, voltage, corrosive chemicals, vibration, or dust. The extreme conditions should include any device or system requiring a lubricant operating under any of the following conditions:

References

  1. Muratore and Voevodin, C and A.A (2009). "Chameleon Coatings: Adaptive Surfaces to Reduce Friction and Wear in Extreme Environments". Annual Review of Materials Research . 39: 297–324. doi:10.1146/annurev-matsci-082908-145259.
  2. 1 2 Voevodin and Zabinski, A.A J.S (2005). "Nanocomposite and Nanostructured tribological materials for space applications". Composites Science and Technology. 65 (5): 741–748. doi:10.1016/j.compscitech.2004.10.008.
  3. 1 2 Voevodin, A.A. "Nanocomposite tribological coatings with "chameleon" surface adaptation". Archived from the original on 2013-04-14.
  4. Steve Price, Dr. Tony Phillips, Gil Knier. "Staying Cool on the ISS". NASA.CS1 maint: multiple names: authors list (link)
  5. Krick, B.A. & Sawyer (19 September 2010). "Space Tribometers: Design for Exposed Experiments on Orbit". Tribology Letters. 41: 303–311. doi:10.1007/s11249-010-9689-y.