Coccinite

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Coccinite
Coccinite.jpg
Coccinite, from Backofen Mine, Rhineland-Palatinate, Germany
General
Category Halide mineral
Formula
(repeating unit)
HgI2
IMA symbol Cci [1]
Strunz classification 3.AB.10
Crystal system Tetragonal
Crystal class Ditetragonal dipyramidal (4/mmm)
H-M symbol: (4/m 2/m 2/m)
Space group P42/nmc
Unit cell a = 4.376 Å, c = 12.41 Å, Z = 2
Identification
ColourOrange-red
Cleavage Good on {001}
Mohs scale hardness2
Streak Orange
Diaphaneity Translucent
Specific gravity 3.17 (calculated)
Optical propertiesUniaxial (-)
Refractive index 2.684 (avg)
Birefringence 0.193
Other characteristicsVolatile at room temperature, toxic
References [2] [3] [4]

Coccinite is a rare mercury iodide mineral with chemical formula of HgI2, mercury(II) iodide. [5] [6] It was first discovered in Casas Viejas, Mexico; [7] it has also been reported from Broken Hill, New South Wales, and from a uranium mine in Thuringia and old mercury workings in the Rhineland-Palatinate in Germany. [2] At the Thuringia deposit the mineral occurs as a sublimation product resulting from fires associated with pyrite-bearing graptolitic slate. [6]

Contents

Discovery

The discovery was announced, by a man mentioned in Comptes rendus only as del Rio, [8] in the journal of the Mexico City School of Mining. The news spread through the reading that journal and direct letters of del Rio. In the subsequent years, the discovery was mentioned several times. One of the earliest notes of the discovery is a translation of a letter of del Rio to Freiesleben.[ citation needed ] In 1839, it was described as lemon coloured spots in the sandstone of Casas Vijecas. [9] This description was also given in a Spanish book printed in 1844. [10] In 1836, the communication of Yniestra to Arago about a discovery made by del Rio was published in Comptes rendus as a short paper. This publication recounts that a mineral sample was deposited at the school of mines by a Mr. Jose Casas Viejas from the Querétaro province, and that the mineral had a red-brown color. [8] In 1861, the book A Glossary of Mineralogy by Henry William Bristow stated that it had been found in Casas Viejas in Mexico as reddish brown particles on mercury selenide. [11] Shortly after, in 1862, a book about chemical technology named the Mexican region of Cavas Viejas as the only location where the mineral was found. [12]

Related Research Articles

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Cinnabar, or cinnabarite, is the bright scarlet to brick-red form of mercury(II) sulfide (HgS). It is the most common source ore for refining elemental mercury and is the historic source for the brilliant red or scarlet pigment termed vermilion and associated red mercury pigments.

<span class="mw-page-title-main">Victor Grignard</span> French chemist (1871–1935)

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<span class="mw-page-title-main">Andrés Manuel del Río</span>

Andrés Manuel del Río y Fernández was a Spanish–Mexican scientist, naturalist and engineer who discovered compounds of vanadium in 1801. He proposed that the element be given the name panchromium, or later, erythronium, but his discovery was not credited at the time, and his names were not used.

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<span class="mw-page-title-main">Mercury(II) iodide</span> Chemical compound

Mercury(II) iodide is a chemical compound with the molecular formula HgI2. It is typically produced synthetically but can also be found in nature as the extremely rare mineral coccinite. Unlike the related mercury(II) chloride it is hardly soluble in water (<100 ppm).

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Clearcreekite is a carbonate mineral, polymorphous with peterbaylissite. The chemical formula of clearcreekite is Hg1+3CO3(OH)∙2H2O. It has a pale greenish yellow color and streak with tabular subhedral crystals and good cleavage on {001}. It is transparent with vitreous luster and uneven fracture. Its density (calculated from the idealized formula) is 6.96 g/cm3. The mineral is monoclinic with the space group P2/c. Clearcreekite is an extremely rare mineral from the Clear Creek mercury mine, New Idria district, San Benito County, California. It was probably formed after the alteration of other mercury minerals such as cinnabar. The mineral is named after the locality where it was found.

<span class="mw-page-title-main">Coloradoite</span>

Coloradoite, also known as mercury telluride (HgTe), is a rare telluride ore associated with metallic deposit. Gold usually occurs within tellurides, such as coloradoite, as a high-finess native metal.

<span class="mw-page-title-main">Lulzacite</span>

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<span class="mw-page-title-main">Christite</span>

Christite is a mineral with the chemical formula TlHgAsS3. It is named after Dr. Charles L. Christ, a member of the U.S. Geological Survey. It usually comes in a crimson red or bright orange color. It has a density of 6.2 and has a rating between 1 and 2 on Mohs Hardness Scale. Christite has an adamantine luster and leaves behind an orange streak. Its crystal system is monoclinic with possible crystal classes of twofold symmetry, mirror plane symmetry, and twofold with a mirror plane. This means it can have radial symmetry, mirror plane symmetry, or mirror plane symmetry perpendicular to the two-fold axis. It is an anisotropic mineral, which means that it exhibits different properties when measured in different directions. In plane polarized light, its color is golden yellow. It is birefringent, which means that it has two distinct indices of refraction. This can be seen when one looks through the microscope with both polars crossed and sees the mineral change colors when it is rotated.

<span class="mw-page-title-main">Fettelite</span>

Fettelite, also known as sanguinite, is a mercury-sulfosalt mineral with the chemical formula Ag16HgAs4S15. The mineral was first described by Wang and Paniagua (1996) who named it after M. Fettel, a German field geologist who collected the first samples from Odenwald. It was first collected in the Nieder-Beerbach mine, 10 km south of Darmstadt, Odenwald, Germany. Its normal occurrence is in hydrothermal veins, which can cut gabbro-diorite intrusives. It is closely related to other rare minerals like dervillite, daomanite, vaughanite and criddleite which are also found in the same type locality as fettelite.

<span class="mw-page-title-main">Huntite</span> Carbonate mineral

Huntite is a carbonate mineral with the chemical formula Mg3Ca(CO3)4. Huntite crystallizes in the trigonal system and typically occurs as platy crystals and powdery masses. For most of recorded history its main use was as a white pigment. Today the most common industrial use of huntite is as a natural mixture with hydromagnesite as a flame retardant or fire retardant additive for polymers.

<span class="mw-page-title-main">Strashimirite</span>

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<span class="mw-page-title-main">Serandite</span> Mineral

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Daubréeite is a rare bismuth oxohalide mineral with formula BiO(OH,Cl). It is a creamy-white to yellow-brown, soft, earthy clay–like mineral which crystallizes in the tetragonal crystal system. It is a member of the matlockite group.

<span class="mw-page-title-main">Capgaronnite</span>

Capgaronnite is a mineral that forms small tufted aggregates or isolated crystals with a maximum width of 0.02mm and a maximum length of 0.1mm. This mineral is related to perroudite in chemical composition and crystal structure. Capgaronnite is associated with secondary minerals of Cu like olivenite, cyanotrichite, and tennantite.

<span class="mw-page-title-main">Edoylerite</span>

Edoylerite is a rare mercury containing mineral. Edoylerite was first discovered in 1961 by Edward H. Oyler, whom the mineral is named after, in a meter-sized boulder at the Clear Creek claim in San Benito County, California. The Clear Creek claim is located near the abandoned Clear Creek mercury mine. The material from the boulder underwent several analyses including, X-ray powder diffraction (XRD), a single crystal study, and a preliminary electron microprobe analysis (EMA). Using these analyses it was determined that this was a new mineral but the nature of the material at the time prevented further investigation. It was not until 1986, with the discovery of crystals large enough for a crystal structure determination and a sufficient quantity for a full mineralogical characterization, that the study was renewed. The new edoylerite crystals were found in the same area at the Clear Creek claim but were situated in an outcrop of silica-carbonate rock. This silica-carbonate rock was mineralized by cinnabar following the hydrothermal alteration of the serpentinite in the rock. Edoylerite is a primary alteration product of cinnabar. Though found with cinnabar, the crystals of edoylerite do not typically exceed 0.5mm in length. The ideal chemical formula for edoylerite is Hg32+Cr6+O4S2

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Coccinite on Mindat.org
  3. Coccinite data on Webmin
  4. Coccinite on Mineral Atlas
  5. Witzke, T. (1997). "New data on the mercury iodide mineral coccinite, HgI2". Neues Jahrbuch für Mineralogie - Monatshefte. 1997 (11): 505–510. doi:10.1127/njmm/1997/1997/505.
  6. 1 2 Jambor, John; Pertsev, Nicolai; Roberts, Andrew (1998). "New Mineral Names" (PDF). American Mineralogist. 83: 907–910.
  7. "Coccinite". Msrblog. 2018-02-14. Retrieved 2022-02-12.
  8. 1 2 "Une nouvelle combinaison naturelle de l'iode". Comptes rendus: 582–583. 1836.
  9. Britain), Society for the Diffusion of Useful Knowledge (Great (1839). The Penny cyclopædia of the Society for the Diffusion of Useful Knowledge.
  10. Domeyko, Ignacio (1844). Tratado de ensayes, tanto por la via seca como por la via humeda, de toda clase de minerales y pastas de cobre, plomo, plata, oro, mercurio, &c: con descripcion de los caracteres de los principales minerales y productos de las artes en America, y en particular en Chile.
  11. Bristow, Henry William (1861). A glossary of mineralogy. Longman, Green, Longman, and Roberts. p.  90. Casas Viejas.
  12. Richardson, Thomas (1863). Chemical technology; or, Chemistry in its applications to the arts & manufactures.