Copper salicylate

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Structure of a hydrated copper(II) salicylate. Color code: red = O, blue = Cu, gray = C, white = H. CSD CIF ASALCU03.png
Structure of a hydrated copper(II) salicylate. Color code: red = O, blue = Cu, gray = C, white = H.

Copper salicylate describes a range of compounds containing copper(II) and salicylate. Many compounds are known. They are generally blue. Simple species include:

Many copper(II) salicylates are known with amines and N-hetrerocyclic ligands. None appear to have commercial applications.

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<span class="mw-page-title-main">Copper(II) nitrate</span> Chemical compound

Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu(NO3)2(H2O)x. The hydrates are blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 °C. Common hydrates are the hemipentahydrate and trihydrate.

<span class="mw-page-title-main">Copper(II) oxide</span> Chemical compound – an oxide of copper with formula CuO

Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds.

In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.

<span class="mw-page-title-main">Tetraamminecopper(II) sulfate</span> Chemical compound

Tetra ammine copper(II) sulphate is the salt with the formula [Cu(NH3)4]SO4·H2O. This dark blue to purple solid is a salt of the metal complex [Cu(NH3)4(H2O)]2+. It is closely related to Schweizer's reagent, which is used for the production of cellulose fibers in the production of rayon.

<span class="mw-page-title-main">Copper(II) acetate</span> Chemical compound

Copper(II) acetate, also referred to as cupric acetate, is the chemical compound with the formula Cu(OAc)2 where AcO is acetate (CH
3
CO
2
). The hydrated derivative, Cu2(OAc)4(H2O)2, which contains one molecule of water for each copper atom, is available commercially. Anhydrous copper(II) acetate is a dark green crystalline solid, whereas Cu2(OAc)4(H2O)2 is more bluish-green. Since ancient times, copper acetates of some form have been used as fungicides and green pigments. Today, copper acetates are used as reagents for the synthesis of various inorganic and organic compounds. Copper acetate, like all copper compounds, emits a blue-green glow in a flame.

<span class="mw-page-title-main">Copper benzoate</span> Chemical compound

Copper benzoate is the chemical compounds with the formula Cu(C6H5CO2)2(H2O)x. These coordination complexes are derived from the cupric ion and the conjugate base of benzoic acid. Many derivatives are known with diverse ancillary ligands. This compound has found some use as a source of blue light in fireworks.

Tutton's salts are a family of salts with the formula M2M'(SO4)2(H2O)6 (sulfates) or M2M'(SeO4)2(H2O)6 (selenates). These materials are double salts, which means that they contain two different cations, M+ and M'2+ crystallized in the same regular ionic lattice. The univalent cation can be potassium, rubidium, cesium, ammonium (NH4), deuterated ammonium (ND4) or thallium. Sodium or lithium ions are too small. The divalent cation can be magnesium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc or cadmium. In addition to sulfate and selenate, the divalent anion can be chromate (CrO42−), tetrafluoroberyllate (BeF42−), hydrogenphosphate (HPO42−) or monofluorophosphate (PO3F2−). Tutton's salts crystallize in the monoclinic space group P21/a. The robustness is the result of the complementary hydrogen-bonding between the tetrahedral anions and cations as well their interactions with the metal aquo complex [M(H2O)6]2+.

<span class="mw-page-title-main">Tetrakis(acetonitrile)copper(I) hexafluorophosphate</span> Chemical compound

Tetrakis(acetonitrile)copper(I) hexafluorophosphate is a salt with the formula [Cu(CH3CN)4]PF6. It is a colourless solid that is used in the synthesis of other copper complexes. The cation [Cu(CH3CN)4]+ is a well-known example of a transition metal nitrile complex.

<span class="mw-page-title-main">Copper(II) phosphate</span> Chemical compound

Copper(II) phosphate are inorganic compounds with the formula Cu3(PO4)2. They can be regarded as the cupric salts of phosphoric acid. Anhydrous copper(II) phosphate and a trihydrate are blue solids.

<span class="mw-page-title-main">Copper hydride</span> Chemical compound

Copper hydride is inorganic compound with the chemical formula CuHn where n ~ 0.95. It is a red solid, rarely isolated as a pure composition, that decomposes to the elements. Copper hydride is mainly produced as a reducing agent in organic synthesis and as a precursor to various catalysts.

The nitronickelates are a class of chemical compounds containing a nickel atom complexed by nitro groups, -NO2. Nickel can be in a +2 or +3 oxidation state. There can be five (pentanitronickelates), or six, (hexanitronickelates) nitro groups per nickel atom. They can be considered the double nitrites of nickel nitrite.

<span class="mw-page-title-main">Nickel oxyacid salts</span>

The Nickel oxyacid salts are a class of chemical compounds of nickel with an oxyacid. The compounds include a number of minerals and industrially important nickel compounds.

The nickel organic acid salts are organic acid salts of nickel. In many of these the ionised organic acid acts as a ligand.

<span class="mw-page-title-main">Transition metal pyridine complexes</span>

Transition metal pyridine complexes encompass many coordination complexes that contain pyridine as a ligand. Most examples are mixed-ligand complexes. Many variants of pyridine are also known to coordinate to metal ions, such as the methylpyridines, quinolines, and more complex rings.

<span class="mw-page-title-main">Transition metal chloride complex</span> Coordination complex

In chemistry, a transition metal chloride complex is a coordination complex that consists of a transition metal coordinated to one or more chloride ligand. The class of complexes is extensive.

<span class="mw-page-title-main">Transition metal dithiocarbamate complexes</span>

Transition metal dithiocarbamate complexes are coordination complexes containing one or more dithiocarbamate ligand, which are typically abbreviated R2dtc. Many complexes are known. Several homoleptic derivatives have the formula M(R2dtc)n where n = 2 and 3.

<span class="mw-page-title-main">Yttrium oxalate</span> Chemical compound

Yttrium oxalate is an inorganic compound, a salt of yttrium and oxalic acid with the chemical formula Y2(C2O4)3. The compound does not dissolve in water and forms crystalline hydrates—colorless crystals.

<span class="mw-page-title-main">Transition metal nitrate complex</span> Compound of nitrate ligands

A transition metal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the preparation of other compounds.

<span class="mw-page-title-main">Manganese lactate</span> Chemical compound

Manganese lactate is an organic chemical compound, a salt of manganese and lactic acid with the formula Mn(C3H5O3)2. The compound forms light pink crystals, soluble in water, forming crystalline hydrates.

Alexander Frank Wells, or A. F. Wells, was a British chemist and crystallographer. He is known for his work on structural inorganic chemistry, which includes the description and classification of structural motifs, such as the polyhedral coordination environments, in crystals obtained from X-ray crystallography. His work is summarized in a classic reference book, Structural inorganic chemistry, first appeared in 1945 and has since gone through five editions.

References

  1. Lutz, Martin; Kroon-Batenburg, Loes M. J. (2018). "Order-Disorder in Diaquobis(salicylato)copper(II) Revisited". Croatica Chemica Acta. 91 (2). doi: 10.5562/cca3362 . S2CID   59025247.
  2. Jagner, S.; Hazell, R. G.; Larsen, K. P. (1976). "The crystal structure of diaquabis(salicylato)copper(II), Cu[C6H4(OH)COO]2(H2O)2". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 32 (2): 548–554. Bibcode:1976AcCrB..32..548J. doi:10.1107/S0567740876003397.
  3. Hanic, F.; Michalov, J. (1960). "Die Kristallstruktur von Kupfersalicylat-Tetrahydrat Cu(OH.C6H4.COO)2.4H2O". Acta Crystallographica. 13 (4): 299–302. Bibcode:1960AcCry..13..299H. doi:10.1107/S0365110X60000753.
  4. V.V.Gorinchoy, Yu.A.Simonov, S.G.Shova, Y.N.Szafranski, K.I.Turta (2009). Zh.Strukt.Khim.(Russ.)(J.Struct.Chem.). 50: 1196.{{cite journal}}: Missing or empty |title= (help)CS1 maint: multiple names: authors list (link)