Cotton effect

Last updated

The Cotton effect in physics, is the characteristic change in optical rotatory dispersion and/or circular dichroism in the vicinity of an absorption band of a substance. In a wavelength region where the light is absorbed, the absolute magnitude of the optical rotation at first varies rapidly with wavelength, crosses zero at absorption maxima and then again varies rapidly with wavelength but in the opposite direction. This phenomenon was discovered in 1895 by the French physicist Aimé Cotton (18691951).

The Cotton effect is called positive if the optical rotation first increases as the wavelength decreases (as first observed by Cotton), and negative if the rotation first decreases. [1] A protein structure such as a beta sheet shows a negative Cotton effect.

See also

Related Research Articles

In physics, attenuation is the gradual loss of flux intensity through a medium. For instance, dark glasses attenuate sunlight, lead attenuates X-rays, and water and air attenuate both light and sound at variable attenuation rates.

An electro–optic effect is a change in the optical properties of a material in response to an electric field that varies slowly compared with the frequency of light. The term encompasses a number of distinct phenomena, which can be subdivided into

<span class="mw-page-title-main">Optical isolator</span> Optical component allowing the transmission of light in only one direction

An optical isolator, or optical diode, is an optical component which allows the transmission of light in only one direction. It is typically used to prevent unwanted feedback into an optical oscillator, such as a laser cavity.

<span class="mw-page-title-main">Ultraviolet–visible spectroscopy</span> Range of spectroscopic analysis

Ultraviolet–visible spectrophotometry refers to absorption spectroscopy or reflectance spectroscopy in part of the ultraviolet and the full, adjacent visible regions of the electromagnetic spectrum. Being relatively inexpensive and easily implemented, this methodology is widely used in diverse applied and fundamental applications. The only requirement is that the sample absorb in the UV-Vis region, i.e. be a chromophore. Absorption spectroscopy is complementary to fluorescence spectroscopy. Parameters of interest, besides the wavelength of measurement, are absorbance (A) or transmittance (%T) or reflectance (%R), and its change with time.

Circular dichroism (CD) is dichroism involving circularly polarized light, i.e., the differential absorption of left- and right-handed light. Left-hand circular (LHC) and right-hand circular (RHC) polarized light represent two possible spin angular momentum states for a photon, and so circular dichroism is also referred to as dichroism for spin angular momentum. This phenomenon was discovered by Jean-Baptiste Biot, Augustin Fresnel, and Aimé Cotton in the first half of the 19th century. Circular dichroism and circular birefringence are manifestations of optical activity. It is exhibited in the absorption bands of optically active chiral molecules. CD spectroscopy has a wide range of applications in many different fields. Most notably, UV CD is used to investigate the secondary structure of proteins. UV/Vis CD is used to investigate charge-transfer transitions. Near-infrared CD is used to investigate geometric and electronic structure by probing metal d→d transitions. Vibrational circular dichroism, which uses light from the infrared energy region, is used for structural studies of small organic molecules, and most recently proteins and DNA.

<span class="mw-page-title-main">Dispersion (optics)</span> An effect of a material on light

Dispersion is the phenomenon in which the phase velocity of a wave depends on its frequency. Sometimes the term chromatic dispersion is used to refer to optics specifically, as opposed to wave propagation in general. A medium having this common property may be termed a dispersive medium.

Mode locking is a technique in optics by which a laser can be made to produce pulses of light of extremely short duration, on the order of picoseconds (10−12 s) or femtoseconds (10−15 s). A laser operated in this way is sometimes referred to as a femtosecond laser, for example, in modern refractive surgery. The basis of the technique is to induce a fixed phase relationship between the longitudinal modes of the laser's resonant cavity. Constructive interference between these modes can cause the laser light to be produced as a train of pulses. The laser is then said to be "phase-locked" or "mode-locked".

<span class="mw-page-title-main">Avalanche photodiode</span> Highly sensitive semiconductor electronic device

An avalanche photodiode (APD) is a highly sensitive type of photodiode, which in general are semiconductor diodes that convert light into electricity via interband excitation coupled with impact ionization. APDs use materials and a structure optimised for operating with high reverse bias, approaching the reverse breakdown voltage, such that charge carriers generated by the photoelectric effect are multiplied by an avalanche breakdown; thus they can be used to detect relatively small amounts of light.

<span class="mw-page-title-main">Absorption spectroscopy</span> Spectroscopic techniques that measure the absorption of radiation

Absorption spectroscopy is spectroscopy that involves techniques that measure the absorption of electromagnetic radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field. The intensity of the absorption varies as a function of frequency, and this variation is the absorption spectrum. Absorption spectroscopy is performed across the electromagnetic spectrum.

<span class="mw-page-title-main">Monochromator</span> Optical device which allows selection of a narrow band of wavelengths from a wider spectrum

A monochromator is an optical device that transmits a mechanically selectable narrow band of wavelengths of light or other radiation chosen from a wider range of wavelengths available at the input. The name is from Greek mono- 'single' chroma 'colour' and Latin -ator 'denoting an agent'.

The Faraday effect or Faraday rotation, sometimes referred to as the magneto-optic Faraday effect (MOFE), is a physical magneto-optical phenomenon. The Faraday effect causes a polarization rotation which is proportional to the projection of the magnetic field along the direction of the light propagation. Formally, it is a special case of gyroelectromagnetism obtained when the dielectric permittivity tensor is diagonal. This effect occurs in most optically transparent dielectric materials under the influence of magnetic fields.

<span class="mw-page-title-main">Raman scattering</span> Inelastic scattering of photons by matter

In chemistry and physics, Raman scattering or the Raman effect is the inelastic scattering of photons by matter, meaning that there is both an exchange of energy and a change in the light's direction. Typically this effect involves vibrational energy being gained by a molecule as incident photons from a visible laser are shifted to lower energy. This is called normal Stokes-Raman scattering.

<span class="mw-page-title-main">Optical filter</span> Filters which selectively transmit specific colors

An optical filter is a device that selectively transmits light of different wavelengths, usually implemented as a glass plane or plastic device in the optical path, which are either dyed in the bulk or have interference coatings. The optical properties of filters are completely described by their frequency response, which specifies how the magnitude and phase of each frequency component of an incoming signal is modified by the filter.

<span class="mw-page-title-main">Absorption (electromagnetic radiation)</span> Physical process by which matter takes up a photons energy and stores it

In physics, absorption of electromagnetic radiation is how matter takes up a photon's energy—and so transforms electromagnetic energy into internal energy of the absorber.

In optics, optical rotatory dispersion is the variation of the specific rotation of a medium with respect to the wavelength of light. Usually described by German physicist Paul Drude's empirical relation:

<span class="mw-page-title-main">Electromagnetic absorption by water</span>

The absorption of electromagnetic radiation by water depends on the state of the water.

<span class="mw-page-title-main">Aimé Cotton</span> French physicist

Aimé Auguste Cotton was a French physicist known for his studies of the interaction of light with chiral molecules. In the absorption bands of these molecules, he discovered large values of optical rotatory dispersion (ORD), or variation of optical rotation as a function of wavelength, as well as circular dichroism or differences of absorption between left and right circularly polarized light.

<span class="mw-page-title-main">Fluoride glass</span> Class of glasses based on fluorides rather than oxides

Fluoride glass is a class of non-oxide optical glasses composed of fluorides of various metals. They can contain heavy metals such as zirconium, or be combined with lighter elements like aluminium and beryllium. These heavier elements cause the glass to have a transparency range extended into the infrared wavelength.

Photoelectrochemical processes are processes in photoelectrochemistry; they usually involve transforming light into other forms of energy. These processes apply to photochemistry, optically pumped lasers, sensitized solar cells, luminescence, and photochromism.

In the study of heat transfer, Schwarzschild's equation is used to calculate radiative transfer through a medium in local thermodynamic equilibrium that both absorbs and emits radiation.

References

  1. Eliel, Ernest L.; Wilen, Samuel H.; Mander, Lewis N. (1994). Stereochemistry of Organic Compounds. Wiley. p. 1000. ISBN   0-471-01670-5.