Crystalloluminescence

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Crystalloluminescence is the effect of luminescence produced during crystallization. The phenomenon was first reported in the 1800s from the rapid crystallization of potassium sulfate from an aqueous solution. [1]

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Crystal Solid material forming a crystal lattice

A crystal or crystalline solid is a solid material whose constituents are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification.

Honey Sweet food made by bees mostly using nectar from flowers

Honey is a sweet, viscous food substance made by honey bees and some other bees. Bees produce honey from the sugary secretions of plants or from secretions of other insects, by regurgitation, enzymatic activity, and water evaporation. Honey bees store honey in wax structures called honeycombs, whereas stingless bees store honey in pots made of wax and resin. The variety of honey produced by honey bees is the best-known, due to its worldwide commercial production and human consumption. Honey is collected from wild bee colonies, or from hives of domesticated bees, a practice known as beekeeping or apiculture.

Magma Hot semifluid material found beneath the surface of Earth

Magma is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and gas bubbles.

Molasses Viscous by-product of the refining of sugarcane, grapes, or sugar beets into sugar

Molasses or black treacle is a viscous substance resulting from refining sugarcane or sugar beets into sugar. Molasses varies by the amount of sugar, method of extraction, and age of plant. Sugarcane molasses is primarily used for sweetening and flavoring foods in the United States, Canada, and elsewhere. Molasses is a defining component of fine commercial brown sugar. It is also one of the primary ingredients used for distilling rum.

Luminescence Spontaneous emission of light by a substance

Luminescence is spontaneous emission of light by a substance not resulting from heat; or "cold light".

Supersaturation occurs with a chemical solution when the concentration of a solute exceeds the concentration specified by the value equilibrium solubility. Most commonly the term is applied to a solution of a solid in a liquid. A supersaturated solution is in a metastable state; it may be brought to equilibrium by forcing the excess of solute to separate from the solution. The term can also be applied to a mixture of gases.

Syrup Thick, viscous solution of sugar in water

In cooking, a syrup is a condiment that is a thick, viscous liquid consisting primarily of a solution of sugar in water, containing a large amount of dissolved sugars but showing little tendency to deposit crystals. Its consistency is similar to that of molasses. The viscosity arises from the multiple hydrogen bonds between the dissolved sugar, which has many hydroxyl (OH) groups.

Fudge Type of sugar candy

Fudge is a type of sugar candy that is made by mixing sugar, butter and milk, heating it to the soft-ball stage at 240 °F (115 °C), and then beating the mixture while it cools so that it acquires a smooth, creamy consistency. In texture, this crystalline candy falls in between fondant icing and hard caramels.

Fractionation a separation process

Fractionation is a separation process in which a certain quantity of a mixture is divided during a phase transition, into a number of smaller quantities (fractions) in which the composition varies according to a gradient. Fractions are collected based on differences in a specific property of the individual components. A common trait in fractionations is the need to find an optimum between the amount of fractions collected and the desired purity in each fraction. Fractionation makes it possible to isolate more than two components in a mixture in a single run. This property sets it apart from other separation techniques.

Crystallization Process by which a solid with a highly organised atomic or molecular structure forms

Crystallization or crystallisation is the process by which a solid forms, where the atoms or molecules are highly organized into a structure known as a crystal. Some of the ways by which crystals form are precipitating from a solution, freezing, or more rarely deposition directly from a gas. Attributes of the resulting crystal depend largely on factors such as temperature, air pressure, and in the case of liquid crystals, time of fluid evaporation.

AgInSbTe, or silver-indium-antimony-tellurium, is a phase change material from the group of chalcogenide glasses, used in rewritable optical discs and phase-change memory applications. It is a quaternary compound of silver, indium, antimony, and tellurium.

In geology, igneous differentiation, or magmatic differentiation, is an umbrella term for the various processes by which magmas undergo bulk chemical change during the partial melting process, cooling, emplacement, or eruption. The sequence of magmas produced by igneous differentiation is known as a magma series.

Fractional crystallization (geology) One of the main processes of magmatic differentiation

Fractional crystallization, or crystal fractionation, is one of the most important geochemical and physical processes operating within crust and mantle of a rocky planetary body, such as the Earth. It is important in the formation of igneous rocks because it is one of the main processes of magmatic differentiation. Fractional crystallization is also important in the formation of sedimentary evaporite rocks.

Liquidus

The liquidus temperature, TL or Tliq, specifies the temperature above which a material is completely liquid, and the maximum temperature at which crystals can co-exist with the melt in thermodynamic equilibrium. It is mostly used for impure substances (mixtures) such as glasses, alloys and rocks.

Merensky Reef Layer of igneous rock in the Bushveld igneous complex, South Africa

The Merensky Reef is a layer of igneous rock in the Bushveld Igneous Complex (BIC) in the North West, Limpopo, Gauteng and Mpumalanga provinces of South Africa which together with an underlying layer, the Upper Group 2 Reef (UG2), contains most of the world's known reserves of platinum group metals (PGMs) or platinum group elements (PGEs)—platinum, palladium, rhodium, ruthenium, iridium and osmium. The Reef is 46 cm thick and bounded by thin chromite seams or stringers. The composition consists predominantly of cumulate rocks, including leuconorite, anorthosite, chromitite, and melanorite.

Igneous petrology is the study of igneous rocks—those that are formed from magma. As a branch of geology, igneous petrology is closely related to volcanology, tectonophysics, and petrology in general. The modern study of igneous rocks utilizes a number of techniques, some of them developed in the fields of chemistry, physics, or other earth sciences. Petrography, crystallography, and isotopic studies are common methods used in igneous petrology.

Recrystallization (chemistry) Separation and purification process of crystalline solids

In chemistry, recrystallization is a technique used to purify chemicals. By dissolving both impurities and a compound in an appropriate solvent, either the desired compound or impurities can be removed from the solution, leaving the other behind. It is named for the crystals often formed when the compound precipitates out. Alternatively, recrystallization can refer to the natural growth of larger ice crystals at the expense of smaller ones.

Crystallization of polymers is a process associated with partial alignment of their molecular chains. These chains fold together and form ordered regions called lamellae, which compose larger spheroidal structures named spherulites. Polymers can crystallize upon cooling from melting, mechanical stretching or solvent evaporation. Crystallization affects optical, mechanical, thermal and chemical properties of the polymer. The degree of crystallinity is estimated by different analytical methods and it typically ranges between 10 and 80%, with crystallized polymers often called "semi-crystalline". The properties of semi-crystalline polymers are determined not only by the degree of crystallinity, but also by the size and orientation of the molecular chains.

H. Douglas Keith

Harvey Douglas Keith was a physicist and one of the primary polymer researchers over the latter half of the 20th century.

References

  1. Light emission during growth and destruction of crystals. Crystalloluminescence and triboluminescence, Jeffrey I. Zink, and B. P. Chandra; J. Phys. Chem., 1982, 86 (1), pp 5–7